File name: Pandora157s1_MexicoCity-Vallejo_20200130_L2Fit_fwvt1c6d20191023p1-8.txt File generation date: 20240926T182043.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v4d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20200130_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20200130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 1646 1796 Nominal wavelengths inside fitting window [nm]: 492.0156 492.1362 492.2568 492.3773 492.4979 492.6184 492.7389 492.8594 492.9798 493.1003 493.2207 493.3411 493.4615 493.5819 493.7023 493.8226 493.9430 494.0633 494.1836 494.3039 494.4241 494.5444 494.6646 494.7848 494.9050 495.0252 495.1454 495.2655 495.3856 495.5058 495.6259 495.7459 495.8660 495.9861 496.1061 496.2261 496.3461 496.4661 496.5860 496.7060 496.8259 496.9458 497.0657 497.1856 497.3055 497.4253 497.5452 497.6650 497.7848 497.9045 498.0243 498.1440 498.2638 498.3835 498.5032 498.6229 498.7425 498.8622 498.9818 499.1014 499.2210 499.3406 499.4601 499.5797 499.6992 499.8187 499.9382 500.0577 500.1771 500.2965 500.4160 500.5354 500.6548 500.7741 500.8935 501.0128 501.1321 501.2514 501.3707 501.4900 501.6092 501.7285 501.8477 501.9669 502.0861 502.2052 502.3244 502.4435 502.5626 502.6817 502.8008 502.9198 503.0389 503.1579 503.2769 503.3959 503.5149 503.6338 503.7528 503.8717 503.9906 504.1095 504.2283 504.3472 504.4660 504.5848 504.7036 504.8224 504.9412 505.0599 505.1787 505.2974 505.4161 505.5347 505.6534 505.7720 505.8907 506.0093 506.1278 506.2464 506.3650 506.4835 506.6020 506.7205 506.8390 506.9575 507.0759 507.1943 507.3128 507.4311 507.5495 507.6679 507.7862 507.9045 508.0228 508.1411 508.2594 508.3777 508.4959 508.6141 508.7323 508.8505 508.9686 509.0868 509.2049 509.3230 509.4411 509.5592 509.6772 509.7953 509.9133 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200130T133048.8Z 7334.563065 452 1 5.61 2 86.66 110.11 137.50 67.37 0.00 1 0.00 1 0 15 3.136e-03 3.124e-03 3.164e-04 3.160e-04 7.737515e+03 2.023800e+01 5.363051e+02 -6.000000e+00 1.684195e+02 279.52 -2.00 20.00 -2.00 505.32 0.00e+00 8.796009e-03 8.588372e-06 4.822609e-04 -6.000000e+00 8.652142e-05 279.52 -2.00 20.00 -2.00 500.65 0.00e+00 7.300905e-01 6.162216e-03 8.868467e-02 -6.000000e+00 6.138008e-02 223.62 -2.00 3.11 -2.00 502.21 0.00e+00 12.899 0.010 489.00 513.00 1 2.0157e+00 4.7083e-04 1.9638e-02 -6.0000e+00 4.6953e-03 -5.3066e-03 1.2072e-04 1.6699e-03 -6.0000e+00 1.2278e-03 5.2568e-02 4.9571e-04 2.8620e-05 1.6783e-04 -6.0000e+00 2.9666e-04 -3.8732e-03 1.3301e-05 12 1 1 12 1 1 13.91 18.00 1.45 -0.00387 -0.00043 77 56 1 7 0 69.770 20.67 15.00 18.00 22.00 34.60 23.5 779.84 -489 -479 -398 -112 430 539 604 606 488 546 364 44 -30 -148 -279 -265 -100 -24 -146 144 329 127 357 249 179 226 375 61 -126 50 -418 -573 -240 -238 -246 91 324 48 1 16 -68 -39 109 179 211 230 309 282 123 -250 -311 -608 -678 -488 -535 -373 -172 31 40 259 231 201 286 309 191 145 174 -16 -347 -300 -162 -337 -227 -111 -353 -268 -50 -94 -330 -348 -280 -518 -354 -139 -290 -322 -257 -170 -117 -112 -23 224 58 2 240 324 187 11 -358 -456 -568 -422 -380 -430 -642 -419 -308 -222 12 -33 -141 -8 204 258 480 794 797 469 335 421 222 228 453 410 148 328 227 182 417 281 -228 -20 73 -137 22 206 -171 -168 172 214 102 189 197 150 157 -49 -267 -339 -284 -343 -255 -457 -452 -378 -108 427 536 612 621 491 554 363 43 -30 -144 -270 -255 -97 -24 -145 145 332 128 361 248 180 230 380 62 -125 49 -409 -557 -231 -236 -249 91 325 49 1 16 -69 -39 110 185 217 239 322 292 127 -253 -313 -609 -668 -480 -527 -380 -176 32 41 267 239 209 299 325 201 151 178 -17 -353 -301 -161 -339 -225 -111 -358 -272 -50 -92 -327 -342 -274 -509 -349 -138 -284 -317 -254 -167 -114 -111 -22 220 58 2 240 324 183 11 -340 -431 -528 -390 -357 -409 -624 -415 -305 -217 12 -32 -139 -8 206 259 486 810 820 480 345 431 224 230 451 407 148 332 231 183 426 282 -230 -21 73 -135 22 205 -170 -168 174 218 103 193 202 155 163 -51 -274 -341 -283 -343 -255 SQ 20200130T134022.2Z 7334.569701 455 1 50.32 2 84.55 110.97 135.47 68.95 0.00 1 0.00 1 0 15 2.868e-03 2.861e-03 3.630e-04 3.624e-04 5.989294e+03 2.277287e+01 4.130966e+02 -6.000000e+00 1.540697e+02 279.52 -2.00 20.00 -2.00 505.32 0.00e+00 7.281225e-03 9.815419e-06 3.989972e-04 -6.000000e+00 7.914319e-05 279.52 -2.00 20.00 -2.00 500.61 0.00e+00 5.669380e-01 7.075370e-03 7.312848e-02 -6.000000e+00 5.613937e-02 223.62 -2.00 3.11 -2.00 502.17 0.00e+00 9.254 0.004 489.00 513.00 1 4.6890e+00 5.4010e-04 1.5125e-02 -6.0000e+00 4.2946e-03 -1.2300e-02 1.3910e-04 1.3121e-03 -6.0000e+00 1.1227e-03 5.6078e-03 2.3865e-04 3.3255e-05 1.3700e-04 -6.0000e+00 2.7140e-04 4.4592e-03 -2.1593e-05 10 0 0 10 0 0 98.78 18.00 1.52 0.00446 0.00611 115 24 1 7 0 433.690 20.67 15.00 18.00 22.91 34.10 22.9 779.85 -511 -428 -345 -87 386 507 555 549 412 458 258 -7 -51 -126 -283 -234 -116 -34 -238 106 285 58 257 234 169 356 369 37 -108 178 -444 -411 -129 -128 -280 92 195 57 7 -24 -83 -67 132 188 267 246 247 274 25 -147 -210 -489 -587 -318 -395 -408 -301 -44 100 168 236 148 229 251 123 208 115 70 -321 -232 -208 -278 -213 -84 -340 -280 -71 -73 -256 -388 -224 -491 -387 -156 -284 -218 -272 -108 -167 -89 -106 220 62 -66 223 266 74 56 -360 -371 -461 -399 -296 -337 -584 -345 -345 -201 20 -61 -142 26 242 215 374 718 793 570 413 431 232 227 467 341 69 281 146 153 371 195 -254 -80 109 -255 -43 131 -104 -100 115 299 82 255 177 66 118 -54 -292 -390 -202 -275 -240 -484 -408 -326 -85 387 521 558 559 421 461 256 -7 -51 -124 -277 -228 -114 -34 -236 107 287 59 259 237 173 365 380 38 -109 173 -421 -403 -123 -126 -286 95 202 58 7 -24 -84 -68 131 190 275 257 258 284 26 -148 -214 -487 -575 -311 -394 -406 -309 -46 105 176 247 155 243 267 130 218 119 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