File name: Pandora157s1_MexicoCity-Vallejo_20200404_L2Fit_fout2c6d20191023p1-8.txt File generation date: 20240926T190617.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20200404_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20200404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1173 305.2579 305.3985 305.5391 305.6797 305.8202 305.9608 306.1013 306.2418 306.3823 306.5228 306.6633 306.8037 306.9442 307.0847 307.2251 307.3655 307.5059 307.6463 307.7867 307.9271 308.0674 308.2078 308.3481 308.4884 308.6288 308.7691 308.9093 309.0496 309.1899 309.3301 309.4704 309.6106 309.7508 309.8910 310.0312 310.1714 310.3116 310.4517 310.5919 310.7320 310.8721 311.0122 311.1523 311.2924 311.4325 311.5726 311.7126 311.8526 311.9927 312.1327 312.2727 312.4127 312.5527 312.6926 312.8326 312.9725 313.1124 313.2524 313.3923 313.5322 313.6720 313.8119 313.9518 314.0916 314.2314 314.3713 314.5111 314.6509 314.7906 314.9304 315.0702 315.2099 315.3497 315.4894 315.6291 315.7688 315.9085 316.0481 316.1878 316.3275 316.4671 316.6067 316.7463 316.8859 317.0255 317.1651 317.3047 317.4442 317.5838 317.7233 317.8628 318.0023 318.1418 318.2813 318.4208 318.5602 318.6997 318.8391 318.9785 319.1179 319.2573 319.3967 319.5361 319.6754 319.8148 319.9541 320.0934 320.2328 320.3721 320.5113 320.6506 320.7899 320.9291 321.0684 321.2076 321.3468 321.4860 321.6252 321.7644 321.9035 322.0427 322.1818 322.3210 322.4601 322.5992 322.7383 322.8774 323.0164 323.1555 323.2945 323.4336 323.5726 323.7116 323.8506 323.9896 324.1285 324.2675 324.4064 324.5454 324.6843 324.8232 324.9621 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200404T133003.6Z 7399.562541 323 1 5.10 2 76.10 88.47 132.47 316.73 0.00 1 0.00 1 0 25 1.545e-01 1.194e-02 1.728e-01 9.608e-03 4.613831e-01 5.074038e-03 4.808232e-03 -6.000000e+00 9.243966e-02 227.50 -2.00 3.11 -2.00 319.62 0.00e+00 3.065390e-03 1.467155e-03 6.806557e-04 -6.000000e+00 4.064354e-03 280.70 -2.00 20.00 -2.00 318.97 0.00e+00 4.073 0.000 302.00 328.00 3 3.8076e+00 1.4416e-02 3.7739e-02 -6.0000e+00 2.2940e-01 5.5457e-02 1.6942e-02 2.1284e-02 -6.0000e+00 2.4898e-01 -6.7447e-02 1.3181e-02 1.1067e-02 -6.0000e+00 1.4824e-01 2.1359e-02 6.8227e-03 4.1483e-03 -6.0000e+00 6.1892e-02 2.9243e-04 -6.2156e-04 3.0434e-04 5.1938e-05 -6.0000e+00 4.7647e-03 -6.8859e-03 0.0000e+00 12 9 9 12 1 1 999.00 19.15 0.42 -0.00689 -0.01156 2 6 1 8 0 1645.300 21.48 15.00 19.15 26.27 21.0 780.72 -24905 691 -48160 -74560 -13341 47916 88214 26267 -75802 44401 -9879 31121 -38487 15887 13515 -14022 -426 5659 8039 -22638 2404 1587 -14362 -9435 4719 5939 -9085 2232 -3537 -5547 948 -2949 7376 -6929 -10330 -8789 4963 -14390 774 7691 -1046 -622 533 -571 -3753 227 2477 2404 2345 -561 7084 1031 10925 -23 1531 3412 2385 1381 -1375 2499 4847 3905 4937 3336 -1015 4561 -371 -3575 3287 767 -725 -2012 -2315 -1599 159 -348 -1978 -2446 581 75 -1976 -1175 -3493 -169 180 119 -2105 220 -763 -680 -1416 804 692 1211 2198 207 488 -306 -255 -859 816 -391 975 293 -952 -1176 -1417 -945 509 789 211 175 128 557 215 950 1068 147 38 -394 -1121 299 417 1005 -223 143 862 1971 179 359 -886 109 -1080 82 -553 -328 439 68 -180 128 -113 114 -308 -542 13 -1495 -2837 -263 525 827 426 -3573 689 -275 653 -1891 557 576 -875 -26 344 504 -1968 169 114 -1238 -823 382 489 -854 184 -307 -521 94 -342 845 -928 -1400 -1207 660 -2698 149 1571 -254 -159 140 -155 -1052 63 670 658 658 -169 2137 357 3723 -9 622 1400 993 582 -586 1029 2042 1796 2452 1789 -570 2383 -198 -1994 1872 487 -501 -1443 -1658 -1089 100 -201 -1099 -1370 345 50 -1498 -966 -3119 -154 173 119 -2228 235 -815 -703 -1400 734 608 1075 2084 218 566 -386 -336 -1127 1011 -459 1090 337 -1154 -1490 -1867 -1295 730 1197 339 287 207 869 321 1371 1543 221 60 -638 -1828 478 649 1519 -330 204 1202 2794 271 581 -1521 192 -1969 153 -1085 -663 899 142 -372 261 -224 219 -585 SS 20200404T133622.1Z 7399.566923 326 1 50.21 2 74.61 88.98 133.44 318.17 0.00 1 0.00 1 0 25 4.469e-02 5.510e-03 1.848e-02 1.409e-03 4.200695e-01 7.443926e-04 4.352519e-03 -6.000000e+00 2.673824e-02 227.50 -2.00 3.11 -2.00 319.70 0.00e+00 1.488922e-03 2.184765e-04 1.977471e-04 -6.000000e+00 1.175783e-03 280.70 -2.00 20.00 -2.00 319.04 0.00e+00 3.702 0.000 302.00 328.00 3 2.6113e+00 2.1255e-03 3.4355e-02 -6.0000e+00 6.6355e-02 9.4824e-03 2.5048e-03 1.9567e-02 -6.0000e+00 7.2021e-02 -1.5256e-02 1.9312e-03 9.6597e-03 -6.0000e+00 4.2880e-02 -2.6925e-03 9.9471e-04 3.1813e-03 -6.0000e+00 1.7900e-02 1.3603e-03 -3.8460e-04 4.5735e-05 3.8709e-05 -6.0000e+00 1.3784e-03 -5.8294e-03 0.0000e+00 10 0 0 10 0 0 76.05 19.15 0.31 -0.00583 -0.00872 129 27 1 8 0 386.150 21.48 15.00 19.15 26.84 20.9 780.78 -4483 -22959 -7685 -18796 -11080 -10963 -19918 -2318 -17230 -11089 -9078 -13773 -9425 -8588 -3233 -7768 3646 -4340 4238 -834 1483 -1581 -689 -626 -893 455 -5135 -1502 -2491 -53 239 -675 635 -1909 -2138 -3649 -2072 -1382 -378 -2334 -1901 -1407 -1422 -200 -464 1154 -366 633 -432 1139 1234 1005 1854 968 917 346 493 -31 467 943 1452 1434 1669 1088 316 978 910 1190 1456 999 362 -197 281 -189 521 55 439 -87 196 -312 -1063 -1344 -1769 -1280 -1092 -690 -361 -230 198 108 778 765 984 897 1045 344 447 10 -334 -731 -631 -201 323 308 -1058 -1090 -686 -605 191 219 172 -245 -67 116 439 816 778 404 -171 -598 -649 -199 -94 178 550 388 814 1072 732 120 8 -309 62 294 -60 -4 -48 -43 -200 -156 -280 -215 42 -88 -596 -174 -452 -231 -229 -495 -54 -516 -329 -277 -490 -381 -413 -173 -488 222 -305 289 -62 110 -123 -55 -54 -82 42 -501 -137 -226 -5 25 -79 80 -250 -274 -486 -303 -238 -77 -508 -452 -352 -368 -52 -122 301 -97 167 -117 318 372 330 648 362 357 140 201 -13 187 378 605 650 827 578 170 502 451 600 800 616 243 -137 193 -124 313 30 224 -44 109 -197 -768 -1080 -1538 -1176 -1068 -715 -392 -254 216 113 758 690 841 775 976 363 528 11 -425 -922 -815 -238 365 356 -1315 -1436 -869 -810 272 337 281 -411 -109 180 637 1130 1080 587 -264 -968 -1062 -318 -146 265 779 575 1167 1571 1064 191 14 -550 114 566 -122 -8 -98 -88 -413 -313 -585 -431 83 SS 20200404T134636.1Z 7399.574029 329 1 50.28 2 72.20 89.83 134.96 320.64 0.00 1 0.00 1 0 25 2.213e-02 5.534e-03 5.650e-03 6.825e-04 3.690764e-01 3.565059e-04 3.822563e-03 -6.000000e+00 1.324194e-02 227.50 -2.00 3.11 -2.00 319.11 0.00e+00 1.142638e-03 8.598112e-05 1.252615e-04 -6.000000e+00 5.822778e-04 280.70 -2.00 20.00 -2.00 318.41 0.00e+00 3.229 0.000 302.00 328.00 3 1.8140e+00 9.8530e-04 2.9939e-02 -6.0000e+00 3.2862e-02 1.4112e-03 1.1365e-03 1.6915e-02 -6.0000e+00 3.5668e-02 -1.3534e-02 8.0257e-04 8.3408e-03 -6.0000e+00 2.1236e-02 -2.1637e-03 4.1415e-04 2.5971e-03 -6.0000e+00 8.8652e-03 4.6065e-03 -2.6681e-04 2.2175e-05 3.1340e-05 -6.0000e+00 6.8262e-04 -6.0938e-03 0.0000e+00 10 0 0 10 0 0 55.95 19.15 0.32 -0.00609 -0.00810 347 72 1 8 0 143.210 21.48 15.00 19.15 28.30 20.9 780.97 -6042 -7017 -6490 -6393 -8876 -4982 -5954 -6935 -6703 -7600 -7397 -4845 -4941 -3269 -2374 -1368 -595 -1176 1079 -158 643 -566 711 -581 -882 -1345 -2234 -1852 -1286 450 294 1344 1027 -1775 -1664 -1335 -1153 -1437 -1026 -1796 -1480 -1000 -933 -393 -140 -320 -134 -80 44 718 1352 1098 1265 1177 635 955 456 224 769 703 1626 1508 1460 945 196 302 528 828 1665 810 72 -46 174 -176 -23 -13 309 377 355 -513 -1056 -1452 -1830 -1259 -1074 -821 -530 -78 -8 66 576 675 892 1098 950 618 399 169 -394 -783 -616 -469 376 365 -692 -1054 -755 -600 -31 130 -1 -145 -64 161 422 670 935 437 -1 -393 -590 -403 51 246 535 465 760 1132 715 119 -51 -239 -31 266 70 -96 -40 -146 -259 -281 -196 -141 20 -214 -272 -253 -234 -311 -167 -219 -289 -305 -365 -368 -257 -306 -235 -196 -124 -57 -121 114 -17 72 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