File name: Pandora157s1_MexicoCity-Vallejo_20200902_L2Fit_fout2c6d20191023p1-8.txt File generation date: 20240926T204621.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20200902_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20200902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1173 305.2579 305.3985 305.5391 305.6797 305.8202 305.9608 306.1013 306.2418 306.3823 306.5228 306.6633 306.8037 306.9442 307.0847 307.2251 307.3655 307.5059 307.6463 307.7867 307.9271 308.0674 308.2078 308.3481 308.4884 308.6288 308.7691 308.9093 309.0496 309.1899 309.3301 309.4704 309.6106 309.7508 309.8910 310.0312 310.1714 310.3116 310.4517 310.5919 310.7320 310.8721 311.0122 311.1523 311.2924 311.4325 311.5726 311.7126 311.8526 311.9927 312.1327 312.2727 312.4127 312.5527 312.6926 312.8326 312.9725 313.1124 313.2524 313.3923 313.5322 313.6720 313.8119 313.9518 314.0916 314.2314 314.3713 314.5111 314.6509 314.7906 314.9304 315.0702 315.2099 315.3497 315.4894 315.6291 315.7688 315.9085 316.0481 316.1878 316.3275 316.4671 316.6067 316.7463 316.8859 317.0255 317.1651 317.3047 317.4442 317.5838 317.7233 317.8628 318.0023 318.1418 318.2813 318.4208 318.5602 318.6997 318.8391 318.9785 319.1179 319.2573 319.3967 319.5361 319.6754 319.8148 319.9541 320.0934 320.2328 320.3721 320.5113 320.6506 320.7899 320.9291 321.0684 321.2076 321.3468 321.4860 321.6252 321.7644 321.9035 322.0427 322.1818 322.3210 322.4601 322.5992 322.7383 322.8774 323.0164 323.1555 323.2945 323.4336 323.5726 323.7116 323.8506 323.9896 324.1285 324.2675 324.4064 324.5454 324.6843 324.8232 324.9621 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200902T131416.8Z 7550.551583 232 1 49.58 2 78.52 85.89 98.34 261.21 0.00 1 0.00 1 0 25 2.643e-01 7.591e-03 1.846e-01 4.486e-03 5.690733e-01 2.467514e-03 5.765431e-03 -6.000000e+00 1.577477e-01 226.33 -2.00 3.11 -2.00 320.86 0.00e+00 2.481845e-03 1.069542e-03 3.849269e-04 -6.000000e+00 7.052268e-03 282.68 -2.00 20.00 -2.00 320.26 0.00e+00 4.866 0.001 302.00 328.00 3 3.2871e+00 7.9501e-03 4.5660e-02 -6.0000e+00 3.9016e-01 3.9264e-02 1.0345e-02 2.6874e-02 -6.0000e+00 4.2347e-01 -4.7303e-02 9.7521e-03 1.3909e-02 -6.0000e+00 2.5263e-01 4.6331e-03 4.7583e-03 4.8570e-03 -6.0000e+00 1.0687e-01 2.4503e-04 -1.1184e-03 1.4458e-04 6.2517e-05 -6.0000e+00 8.1814e-03 -2.2536e-02 0.0000e+00 11 9 0 11 8 0 99.50 19.09 0.52 -0.02254 -0.03094 37 8 1 8 0 1339.600 21.48 15.00 19.09 26.27 24.7 782.98 900000 -128897 -72825 -76991 28932 -21215 -86036 -89720 -89934 -77596 -78849 139341 -34111 -51822 -630 -6482 7245 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-1584 -828 -954 -687 -138 -458 -638 -231 -222 765 262 63 1740 90 1050 244 332 -181 -878 -857 219 107 -1267 -1680 -832 -1036 12 201 42 -199 -164 801 827 1198 635 1362 -780 -1166 -543 -210 1031 -211 655 629 1453 976 834 458 -386 -756 -475 927 -283 -1087 -252 841 -1460 -428 -143 339 633 SS 20200902T132005.2Z 7550.555615 235 1 50.33 2 77.16 86.36 99.64 261.67 0.00 1 0.00 1 0 25 1.050e-01 5.745e-03 2.680e-02 1.083e-03 5.100704e-01 5.822211e-04 5.271772e-03 -6.000000e+00 6.268369e-02 226.33 -2.00 3.11 -2.00 320.31 0.00e+00 2.701654e-03 2.120481e-04 2.763901e-04 -6.000000e+00 2.783734e-03 282.68 -2.00 20.00 -2.00 319.66 0.00e+00 4.384 0.000 302.00 328.00 3 1.4558e+00 1.7609e-03 4.1077e-02 -6.0000e+00 1.5505e-01 2.5896e-02 2.1619e-03 2.4122e-02 -6.0000e+00 1.6822e-01 -3.4862e-02 1.8586e-03 1.2134e-02 -6.0000e+00 1.0037e-01 1.2903e-03 9.3966e-04 4.6952e-03 -6.0000e+00 4.2215e-02 2.3322e-03 -7.1478e-04 3.4814e-05 5.6320e-05 -6.0000e+00 3.2358e-03 -2.4459e-02 0.0000e+00 10 0 0 10 0 0 54.94 19.09 0.32 -0.02446 -0.02983 288 60 1 8 0 172.490 21.48 15.00 19.09 26.83 24.5 783.59 -25473 -46304 -21857 -50670 -10505 -45705 -33842 -36018 -34843 -22071 -35858 -4903 -22066 -4997 -15322 -1871 -8866 -5594 -1409 -8347 -2697 -7346 -2010 -8216 -3693 -6205 -6338 -7096 -9539 692 -6459 1490 -1892 -1768 -5230 -1854 -2637 -4126 -1235 -3788 -813 -2198 -427 -782 819 144 -112 1786 49 2211 1234 2044 1302 1539 1484 1083 947 -750 1016 6 1344 1420 2029 1487 755 1385 506 1939 1886 1667 561 448 184 -43 189 -561 365 -591 314 -621 -598 -1422 -1928 -1354 -1044 -606 -781 -78 -265 464 648 739 1028 1017 1244 310 616 150 -285 -622 -473 -436 207 478 -1037 -1291 -1007 -549 -188 271 160 -114 84 152 519 612 924 321 -7 -518 -790 -344 -70 417 409 523 649 1281 780 135 40 -209 -53 152 -20 -206 -119 -71 -261 -234 -146 28 145 -253 -641 -247 -739 -97 -594 -422 -517 -548 -326 -648 -74 -478 -113 -465 -57 -323 -215 -55 -369 -115 -334 -90 -422 -194 -348 -357 -394 -542 38 -431 106 -155 -150 -454 -158 -250 -470 -164 -603 -140 -410 -82 -154 161 29 -23 364 10 489 300 492 343 432 438 333 297 -238 312 2 428 493 776 621 327 582 209 807 858 852 316 263 107 -24 97 -263 158 -259 149 -341 -377 -1013 -1500 -1116 -914 -561 -762 -78 -263 440 576 611 808 810 1076 306 688 172 -352 -771 -552 -509 225 524 -1221 -1616 -1326 -700 -258 405 258 -191 140 243 779 878 1317 477 -11 -854 -1317 -559 -110 626 590 723 951 1751 1163 222 72 -394 -105 315 -41 -439 -262 -159 -583 -510 -303 59 302 SS 20200902T132545.1Z 7550.559549 238 1 50.15 2 75.82 86.81 100.91 262.12 0.00 1 0.00 1 0 25 6.163e-02 5.453e-03 1.579e-02 8.354e-04 4.694087e-01 4.479978e-04 4.899405e-03 -6.000000e+00 3.679287e-02 226.33 -2.00 3.11 -2.00 319.96 0.00e+00 2.171256e-03 1.447734e-04 2.818148e-04 -6.000000e+00 1.633947e-03 282.68 -2.00 20.00 -2.00 319.30 0.00e+00 3.998 0.000 302.00 328.00 3 1.3487e+00 1.3110e-03 3.7559e-02 -6.0000e+00 9.1009e-02 1.4906e-02 1.5760e-03 2.2122e-02 -6.0000e+00 9.8739e-02 -2.2408e-02 1.2873e-03 1.0980e-02 -6.0000e+00 5.8915e-02 -2.8598e-03 6.5959e-04 4.0298e-03 -6.0000e+00 2.4778e-02 3.6243e-03 -6.6093e-04 2.6869e-05 4.7530e-05 -6.0000e+00 1.8993e-03 -2.4434e-02 0.0000e+00 10 0 0 10 0 0 11.26 19.09 0.33 -0.02443 -0.02940 395 82 1 8 0 125.660 21.48 15.00 19.09 27.57 24.5 783.29 -21354 -2121 -21434 -17656 -17998 -26843 -20265 -27292 -17544 -21742 -15547 -16242 -9598 -9224 -2587 -2937 -5073 -266 -3919 -28 -2205 -1612 386 -1672 -2117 -6097 -2780 -6940 -1455 -2245 180 739 -49 -917 -2764 -2361 -3511 -899 -1532 -2070 -1973 -1898 -969 -1397 195 -277 483 -87 501 1003 1652 1681 1178 1483 623 1583 296 197 525 345 1144 1402 1387 976 744 612 1216 963 1849 1203 303 224 -120 143 21 180 148 100 571 -372 -956 -1494 -1512 -1379 -805 -916 -427 -201 -113 204 546 975 841 1191 986 590 413 149 -257 -653 -494 -555 308 269 -763 -1213 -869 -635 -123 362 31 15 -25 210 412 762 950 360 -18 -667 -703 -515 -107 124 457 518 764 1255 775 222 41 -151 -69 216 -33 -248 -108 -131 -180 -260 14 -80 126 -306 -28 -358 -273 -262 -424 -324 -527 -340 -468 -332 -390 -259 -303 -95 -124 -241 -13 -211 -2 -125 -92 23 -107 -145 -451 -199 -504 -99 -162 14 66 -5 -96 -289 -249 -414 -122 -251 -397 -419 -430 -226 -335 47 -67 117 -21 126 264 467 472 360 481 214 556 107 71 186 122 419 557 609 464 363 290 555 448 927 680 188 145 -77 88 12 92 71 48 293 -220 -650 -1140 -1251 -1213 -750 -909 -443 -213 -120 208 518 857 702 998 896 605 479 177 -327 -833 -593 -670 347 306 -930 -1444 -1087 -840 -175 554 51 25 -43 338 622 1095 1357 536 -29 -1107 -1180 -847 -169 190 667 724 1033 1722 1154 364 73 -282 -124 404 -65 -518 -233 -286 -394 -557 28 -156 241 SS 20200902T133150.0Z 7550.563773 241 1 50.05 2 74.39 87.30 102.28 262.59 0.00 1 0.00 1 0 25 4.352e-02 5.613e-03 8.488e-03 6.356e-04 4.322357e-01 3.331578e-04 4.474225e-03 -6.000000e+00 2.598298e-02 226.33 -2.00 3.11 -2.00 319.62 0.00e+00 1.583301e-03 9.724394e-05 1.734751e-04 -6.000000e+00 1.153857e-03 282.68 -2.00 20.00 -2.00 318.94 0.00e+00 3.653 0.000 302.00 328.00 3 1.2011e+00 9.4906e-04 3.4244e-02 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