File name: Pandora157s1_MexicoCity-Vallejo_20200923_L2Fit_fout2c6d20191023p1-8.txt File generation date: 20240926T205420.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20200923_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20200923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1173 305.2579 305.3985 305.5391 305.6797 305.8202 305.9608 306.1013 306.2418 306.3823 306.5228 306.6633 306.8037 306.9442 307.0847 307.2251 307.3655 307.5059 307.6463 307.7867 307.9271 308.0674 308.2078 308.3481 308.4884 308.6288 308.7691 308.9093 309.0496 309.1899 309.3301 309.4704 309.6106 309.7508 309.8910 310.0312 310.1714 310.3116 310.4517 310.5919 310.7320 310.8721 311.0122 311.1523 311.2924 311.4325 311.5726 311.7126 311.8526 311.9927 312.1327 312.2727 312.4127 312.5527 312.6926 312.8326 312.9725 313.1124 313.2524 313.3923 313.5322 313.6720 313.8119 313.9518 314.0916 314.2314 314.3713 314.5111 314.6509 314.7906 314.9304 315.0702 315.2099 315.3497 315.4894 315.6291 315.7688 315.9085 316.0481 316.1878 316.3275 316.4671 316.6067 316.7463 316.8859 317.0255 317.1651 317.3047 317.4442 317.5838 317.7233 317.8628 318.0023 318.1418 318.2813 318.4208 318.5602 318.6997 318.8391 318.9785 319.1179 319.2573 319.3967 319.5361 319.6754 319.8148 319.9541 320.0934 320.2328 320.3721 320.5113 320.6506 320.7899 320.9291 321.0684 321.2076 321.3468 321.4860 321.6252 321.7644 321.9035 322.0427 322.1818 322.3210 322.4601 322.5992 322.7383 322.8774 323.0164 323.1555 323.2945 323.4336 323.5726 323.7116 323.8506 323.9896 324.1285 324.2675 324.4064 324.5454 324.6843 324.8232 324.9621 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200923T130305.1Z 7571.543809 48 1 50.23 2 82.05 93.25 165.12 107.52 0.00 1 0.00 1 0 25 3.764e-01 2.623e-02 4.147e-01 2.067e-02 7.436854e-01 1.234554e-02 7.577615e-03 -6.000000e+00 2.299252e-01 226.19 -2.00 3.11 -2.00 321.69 0.00e+00 2.036597e-03 6.553083e-03 3.313469e-03 -6.000000e+00 1.247419e-02 282.39 -2.00 20.00 -2.00 321.17 0.00e+00 6.776 0.001 302.00 328.00 3 3.5415e+00 4.5145e-02 6.5085e-02 -6.0000e+00 5.7724e-01 4.3359e-01 6.1319e-02 4.3244e-02 -6.0000e+00 6.3144e-01 -5.6956e-01 5.6933e-02 2.0522e-02 -6.0000e+00 3.6800e-01 2.2745e-01 2.6525e-02 5.5964e-03 -6.0000e+00 1.5763e-01 3.6724e-05 -1.6761e-03 6.6236e-04 9.8037e-05 -6.0000e+00 1.2512e-02 -2.6988e-02 0.0000e+00 12 8 8 10 0 0 10.93 18.81 0.68 -0.02699 -0.03958 15 3 1 8 0 3348.470 21.27 15.00 18.81 25.05 25.2 782.90 900000 900000 -134924 900000 -52493 -113963 30043 900000 900000 900000 900000 900000 82352 -45410 67573 -69908 900000 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2360 5428 3198 1000 -1372 3901 -5154 -89 4389 1492 3589 4723 814 676 2212 4005 4212 4479 -1253 137 700 3953 942 -1414 860 -2044 2191 -1674 455 2034 1669 3440 -1857 -1404 -1642 598 -4202 -1597 -1594 -669 -1170 5121 -1394 1474 -1987 -4924 -18 -3609 -1454 645 -445 -1439 -1867 -1902 -4342 901 -127 1228 -735 2048 1450 3685 362 -1491 2375 -1206 2852 -4545 -132 -2029 2901 2083 3237 5606 -397 2561 -4913 2738 2909 3078 -120 -1547 -630 -6896 2786 -719 -304 435 1555 -1713 SS 20200923T131813.8Z 7571.554326 53 1 49.59 2 78.49 94.55 161.88 105.56 0.00 1 0.00 1 0 25 1.833e-01 6.467e-03 9.735e-02 2.863e-03 5.529215e-01 1.556660e-03 5.635072e-03 -6.000000e+00 1.094052e-01 226.19 -2.00 3.11 -2.00 320.77 0.00e+00 3.791195e-03 6.566935e-04 9.939767e-04 -6.000000e+00 4.855226e-03 282.39 -2.00 20.00 -2.00 320.17 0.00e+00 4.855 0.001 302.00 328.00 3 2.6194e+00 4.9589e-03 4.5828e-02 -6.0000e+00 2.7056e-01 4.9255e-02 6.3501e-03 2.8403e-02 -6.0000e+00 2.9358e-01 -5.4361e-02 5.8312e-03 1.3272e-02 -6.0000e+00 1.7516e-01 8.7728e-03 2.8609e-03 6.2537e-03 -6.0000e+00 7.3671e-02 4.8756e-04 -8.7718e-04 9.2006e-05 6.5649e-05 -6.0000e+00 5.6501e-03 -2.4573e-02 0.0000e+00 11 8 0 10 0 0 34.37 18.81 0.41 -0.02457 -0.03116 77 16 1 8 0 644.010 21.27 15.00 18.81 26.38 25.4 782.98 -58248 -88668 -52186 -29131 -85948 -52469 -76860 18850 -63644 -50453 -9421 -51724 648 -40714 -20333 -10906 -14124 -31433 -5949 -5722 -8546 -6996 -7121 4042 -10344 -7573 -23037 -2037 255 -10838 -2490 -18614 10218 -1227 1069 -4442 539 -1333 -864 -1206 -5379 -309 -2772 310 -1441 3235 828 950 2425 574 3593 3287 4491 1123 3582 2264 1059 249 -988 3059 40 3182 2247 1889 635 1220 1679 -555 1826 1256 669 -704 399 279 -7 -893 -183 436 -732 150 -781 -1068 -1401 -2509 -916 -968 -118 67 263 -450 869 830 1530 1127 543 562 155 468 -441 -130 -349 19 230 211 -561 -1579 -694 -1108 111 -107 -53 -245 -137 225 293 849 978 647 -88 -773 -1006 -314 308 31 825 523 634 985 878 36 329 -60 -284 369 -100 -26 -190 -155 -308 -273 -179 38 260 -504 -1188 -510 -220 -1080 -469 -944 100 -853 -634 -84 -809 7 -887 -443 -253 -379 -1097 -173 -174 -274 -225 -239 130 -410 -304 -1087 -77 9 -484 -118 -1211 559 -79 66 -295 38 -112 -87 -130 -673 -39 -380 42 -204 446 119 140 366 94 625 633 930 258 845 561 271 64 -252 750 11 890 708 653 230 432 580 -201 709 551 322 -357 198 132 -3 -358 -75 179 -334 71 -432 -667 -956 -1846 -706 -794 -101 59 228 -380 680 607 1064 802 426 501 158 534 -544 -160 -407 20 229 211 -596 -1798 -827 -1413 152 -161 -86 -417 -233 366 452 1246 1431 987 -142 -1309 -1716 -519 488 48 1207 737 870 1383 1348 62 611 -118 -588 735 -212 -59 -436 -362 -716 -618 -386 86 565 SS 20200923T132425.0Z 7571.558622 56 1 49.95 2 77.04 95.10 160.55 105.01 0.00 1 0.00 1 0 25 1.149e-01 6.039e-03 3.824e-02 1.594e-03 5.004932e-01 8.526875e-04 5.096332e-03 -6.000000e+00 6.858487e-02 226.19 -2.00 3.11 -2.00 320.35 0.00e+00 2.600824e-03 3.117272e-04 2.501166e-04 -6.000000e+00 3.043526e-03 282.39 -2.00 20.00 -2.00 319.71 0.00e+00 4.348 0.000 302.00 328.00 3 2.1795e+00 2.5630e-03 4.0428e-02 -6.0000e+00 1.6961e-01 1.7593e-02 3.1652e-03 2.3343e-02 -6.0000e+00 1.8404e-01 -2.2541e-02 2.7568e-03 1.1881e-02 -6.0000e+00 1.0980e-01 -2.5313e-03 1.3944e-03 4.5714e-03 -6.0000e+00 4.6186e-02 1.1758e-03 -6.7850e-04 5.1486e-05 5.2059e-05 -6.0000e+00 3.5417e-03 -2.5058e-02 0.0000e+00 10 0 0 10 0 0 39.93 18.81 0.33 -0.02506 -0.03016 149 31 1 8 0 332.940 21.27 15.00 18.81 26.98 25.1 783.04 -31163 -37343 -45601 -52111 -36281 -20149 -55943 1191 -36414 -18813 -42796 -18966 -18918 -23381 3103 -18940 3465 -13866 2458 -7576 -2548 -7920 -6083 -95 -6995 -858 -12614 -4180 -6764 -4233 -2504 -940 1514 -4748 -24 -1054 -301 -1429 -661 -3522 -2345 -988 -2705 458 -393 1783 -552 647 356 1413 2559 1042 2024 812 2146 718 1393 -641 641 792 852 1814 687 1945 588 2007 835 1417 2266 1271 635 -216 577 -522 296 -428 791 501 316 -227 -1345 -1000 -2013 -1367 -962 -964 -438 -320 182 -17 843 760 1352 970 1059 559 511 399 -207 -532 -786 -359 -19 250 -907 -1489 -785 -866 -142 53 105 -145 41 209 484 784 897 555 -156 -441 -808 -278 108 220 483 253 668 1223 1039 37 41 -224 -19 312 -48 -336 -299 -57 -253 -122 -72 -92 240 -334 -482 -666 -786 -440 -207 -887 12 -594 -275 -845 -333 -403 -643 79 -695 113 -582 94 -334 -110 -366 -287 -5 -383 -46 -763 -227 -376 -243 -161 -68 120 -415 -2 -89 -28 -158 -87 -558 -408 -181 -480 89 -78 351 -113 133 75 313 609 251 524 227 623 219 430 -201 196 241 270 621 263 799 252 826 339 583 1008 641 351 -125 330 -287 149 -197 370 235 147 -122 -836 -694 -1533 -1102 -823 -877 -417 -312 175 -16 732 615 1035 755 894 535 555 484 -271 -697 -975 -407 -20 267 -1036 -1816 -1003 -1176 -207 77 164 -235 67 321 700 1182 1347 795 -237 -701 -1301 -437 164 350 735 369 945 1760 1624 58 71 -406 -36 619 -101 -746 -685 -133 -586 -276 -155 -189 480 SS 20200923T133002.1Z 7571.562524 59 1 50.16 2 75.72 95.60 159.33 104.60 0.00 1 0.00 1 0 25 5.993e-02 5.719e-03 1.964e-02 1.127e-03 4.597694e-01 6.020317e-04 4.804280e-03 -6.000000e+00 3.576189e-02 226.19 -2.00 3.11 -2.00 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