File name: Pandora157s1_MexicoCity-Vallejo_20201005_L2Fit_fout2c6d20191023p1-8.txt File generation date: 20240926T210310.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20201005_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20201005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1173 305.2579 305.3985 305.5391 305.6797 305.8202 305.9608 306.1013 306.2418 306.3823 306.5228 306.6633 306.8037 306.9442 307.0847 307.2251 307.3655 307.5059 307.6463 307.7867 307.9271 308.0674 308.2078 308.3481 308.4884 308.6288 308.7691 308.9093 309.0496 309.1899 309.3301 309.4704 309.6106 309.7508 309.8910 310.0312 310.1714 310.3116 310.4517 310.5919 310.7320 310.8721 311.0122 311.1523 311.2924 311.4325 311.5726 311.7126 311.8526 311.9927 312.1327 312.2727 312.4127 312.5527 312.6926 312.8326 312.9725 313.1124 313.2524 313.3923 313.5322 313.6720 313.8119 313.9518 314.0916 314.2314 314.3713 314.5111 314.6509 314.7906 314.9304 315.0702 315.2099 315.3497 315.4894 315.6291 315.7688 315.9085 316.0481 316.1878 316.3275 316.4671 316.6067 316.7463 316.8859 317.0255 317.1651 317.3047 317.4442 317.5838 317.7233 317.8628 318.0023 318.1418 318.2813 318.4208 318.5602 318.6997 318.8391 318.9785 319.1179 319.2573 319.3967 319.5361 319.6754 319.8148 319.9541 320.0934 320.2328 320.3721 320.5113 320.6506 320.7899 320.9291 321.0684 321.2076 321.3468 321.4860 321.6252 321.7644 321.9035 322.0427 322.1818 322.3210 322.4601 322.5992 322.7383 322.8774 323.0164 323.1555 323.2945 323.4336 323.5726 323.7116 323.8506 323.9896 324.1285 324.2675 324.4064 324.5454 324.6843 324.8232 324.9621 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201005T130438.2Z 7583.544886 238 1 8.32 2 82.37 98.13 58.49 277.03 0.00 1 0.00 1 0 25 4.527e-01 2.720e-02 3.554e-01 1.846e-02 7.573495e-01 1.136718e-02 7.447071e-03 -6.000000e+00 2.843875e-01 226.08 -2.00 3.11 -2.00 321.61 0.00e+00 -3.009130e-03 6.319604e-03 1.271021e-03 -6.000000e+00 1.799961e-02 282.09 -2.00 20.00 -2.00 321.11 0.00e+00 7.018 0.002 302.00 328.00 3 2.7643e+00 4.1798e-02 6.5305e-02 -6.0000e+00 7.1157e-01 2.7470e-01 5.9000e-02 3.9673e-02 -6.0000e+00 7.8231e-01 -4.7752e-01 5.7601e-02 1.9298e-02 -6.0000e+00 4.5243e-01 2.1172e-01 2.6290e-02 7.6139e-03 -6.0000e+00 1.9043e-01 7.1559e-05 -1.6507e-03 6.0484e-04 9.8342e-05 -6.0000e+00 1.5149e-02 -1.8798e-02 0.0000e+00 12 9 9 12 9 1 -15.19 18.62 0.17 -0.01880 -0.03120 3 5 1 8 0 2037.860 21.06 15.00 18.62 18.53 24.2 785.17 900000 45663 900000 900000 -27571 900000 900000 900000 -282395 900000 900000 900000 900000 -31029 900000 900000 -13373 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2575 3236 2319 5203 663 4947 4342 2806 322 -1263 -549 2907 1838 1682 5575 -1513 1689 3707 4495 -2822 3405 719 -3025 340 4583 1017 2675 -415 -258 -2046 3360 2229 -2256 1037 -1687 105 -1565 -1625 1073 801 -44 -2715 -42 -145 1324 -2429 -5211 -867 982 -2427 -1941 -572 -1675 1092 -3838 -173 -3318 -86 -511 -3498 -707 -624 559 356 4558 807 450 3534 -1878 -325 934 1154 3695 375 1817 1776 1835 3000 874 754 1740 -29 1283 -1158 475 -2815 -2696 849 1415 -1250 -2499 4 SS 20201005T132110.1Z 7583.556367 243 1 50.18 2 78.52 99.62 62.25 278.12 0.00 1 0.00 1 0 25 1.364e-01 5.470e-03 3.400e-02 1.043e-03 5.372899e-01 5.641502e-04 5.482808e-03 -6.000000e+00 8.133229e-02 226.08 -2.00 3.11 -2.00 320.54 0.00e+00 6.273867e-03 2.227744e-04 1.017092e-03 -6.000000e+00 3.606700e-03 282.09 -2.00 20.00 -2.00 319.93 0.00e+00 4.866 0.001 302.00 328.00 3 9.6515e-01 1.7446e-03 4.5725e-02 -6.0000e+00 2.0111e-01 3.7710e-02 2.2000e-03 2.8820e-02 -6.0000e+00 2.1826e-01 -3.6084e-02 2.0163e-03 1.3560e-02 -6.0000e+00 1.3021e-01 3.9352e-03 1.0050e-03 8.9017e-03 -6.0000e+00 5.4750e-02 2.5632e-03 -7.4000e-04 3.3265e-05 7.9650e-05 -6.0000e+00 4.2025e-03 -2.3635e-02 0.0000e+00 10 0 0 10 0 0 78.16 18.62 0.33 -0.02363 -0.02920 372 77 1 8 0 133.450 21.06 14.99 18.62 20.07 24.5 785.27 -64285 -19210 -53058 361 -54254 -45661 -52913 -50541 -27732 -51913 -25766 -37361 -18753 -23806 -14932 -9986 -6023 -4704 -8260 487 -12209 -2579 -6354 -5934 -8539 -7026 -7992 -9920 -627 -4118 1194 -1482 225 -1682 -4359 -3526 -4973 319 -4117 -1742 -3150 -932 -2223 -1730 740 -713 780 83 1407 1277 2131 1739 2079 2232 832 1867 65 216 -208 1060 881 1545 1615 1098 867 780 1358 1228 1781 674 347 6 -306 106 -511 239 75 407 -201 -726 -742 -1367 -1366 -1581 -847 -868 -341 -231 -68 287 616 1066 916 1351 833 684 395 125 -131 -509 -166 -287 781 315 -573 -1254 -735 -642 -318 199 -236 -148 -96 256 477 773 876 239 -92 -744 -796 -599 -58 100 388 443 863 1288 673 214 -29 -71 89 269 -138 -217 -51 -144 -272 -335 23 -70 317 -652 -142 -580 2 -550 -420 -557 -577 -276 -698 -285 -535 -278 -471 -333 -249 -162 -137 -268 15 -443 -86 -227 -224 -351 -295 -340 -427 -25 -184 59 -88 15 -117 -307 -250 -394 27 -444 -213 -434 -135 -342 -274 117 -117 129 14 247 238 431 389 503 577 229 524 19 62 -59 300 262 501 568 424 347 307 520 483 761 327 184 3 -168 55 -246 107 31 172 -94 -383 -451 -939 -991 -1225 -694 -756 -311 -216 -63 256 514 851 700 1047 690 645 414 147 -166 -630 -199 -314 817 333 -645 -1467 -904 -839 -437 299 -375 -244 -158 403 726 1126 1274 363 -148 -1219 -1312 -989 -92 152 568 639 1208 1845 1029 364 -52 -135 173 549 -293 -482 -116 -334 -631 -756 50 -147 647 SS 20201005T132717.8Z 7583.560623 246 1 49.62 2 77.10 100.18 63.64 278.53 0.00 1 0.00 1 0 33 8.108e-02 5.593e-03 1.617e-02 7.452e-04 4.864393e-01 3.994030e-04 5.039395e-03 -6.000000e+00 4.835140e-02 226.08 -2.00 3.11 -2.00 320.17 0.00e+00 5.558275e-03 1.399653e-04 8.318452e-04 -6.000000e+00 2.144143e-03 282.09 -2.00 20.00 -2.00 319.55 0.00e+00 4.366 0.000 302.00 328.00 3 8.5529e-01 1.1917e-03 4.0932e-02 -6.0000e+00 1.1956e-01 2.8544e-02 1.4527e-03 2.5504e-02 -6.0000e+00 1.2975e-01 -2.8652e-02 1.2354e-03 1.1922e-02 -6.0000e+00 7.7406e-02 2.4374e-03 6.2641e-04 7.5307e-03 -6.0000e+00 3.2549e-02 4.3834e-03 -6.1924e-04 2.3813e-05 6.7219e-05 -6.0000e+00 2.4983e-03 -2.3682e-02 0.0000e+00 10 0 0 10 0 0 77.80 18.61 0.28 -0.02368 -0.02834 507 105 1 8 0 97.870 21.06 15.00 18.61 20.79 24.3 785.73 -24291 -20395 -30523 -17401 -35016 -23131 -33472 -24069 -19479 -31139 -19076 -26565 -12276 -15927 -6656 -8936 -3155 -954 -4273 486 -5202 -1217 -4339 -2930 -5522 -3842 -4847 -5223 -2114 -3766 981 -1055 102 -1629 -2144 -360 -2176 -1071 -2419 -1638 -2430 -1048 -1542 -940 32 52 790 57 1475 883 1985 1397 1645 1233 657 1088 501 230 194 975 911 1646 1343 905 724 455 1344 914 1916 649 280 -43 127 73 -65 177 95 405 18 -206 -923 -1320 -1652 -1464 -927 -914 -461 -289 -86 285 582 909 994 1240 869 793 439 109 -302 -483 -271 -189 585 346 -621 -1272 -660 -583 -115 86 -184 -196 -149 157 518 915 906 318 -131 -819 -814 -622 -65 82 464 397 945 1287 862 238 96 3 46 273 -55 -216 -108 -160 -291 -295 -13 -100 245 -293 -268 -464 -224 -504 -291 -496 -360 -304 -577 -331 -564 -277 -464 -215 -342 -126 -41 -201 23 -264 -60 -227 -160 -327 -231 -295 -314 -124 -240 68 -86 9 -154 -201 -34 -227 -130 -356 -277 -416 -189 -293 -183 6 10 159 12 310 196 474 367 467 374 209 355 167 77 64 319 312 612 556 408 336 206 586 407 921 353 167 -27 78 43 -35 87 44 185 9 -118 -612 -983 -1338 -1260 -844 -885 -429 -275 -89 283 540 782 812 1022 781 805 465 130 -383 -615 -324 -208 656 393 -689 -1507 -820 -769 -163 132 -306 -311 -253 254 789 1327 1312 481 -210 -1380 -1384 -1034 -104 127 683 561 1289 1790 1305 397 173 5 84 524 -112 -464 -239 -359 -652 -645 -28 -200 474 SS 20201005T133252.1Z 7583.564491 249 1 50.13 2 75.81 100.71 64.91 278.90 0.00 1 0.00 1 0 25 5.887e-02 5.747e-03 9.406e-03 5.825e-04 4.487272e-01 3.057010e-04 4.634112e-03 -6.000000e+00 3.511166e-02 226.08 -2.00 3.11 -2.00 319.84 0.00e+00 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