File name: Pandora157s1_MexicoCity-Vallejo_20210105_L2Fit_fout2c6d20191023p1-8.txt File generation date: 20240926T220046.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20210105_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20210105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1173 305.2579 305.3985 305.5391 305.6797 305.8202 305.9608 306.1013 306.2418 306.3823 306.5228 306.6633 306.8037 306.9442 307.0847 307.2251 307.3655 307.5059 307.6463 307.7867 307.9271 308.0674 308.2078 308.3481 308.4884 308.6288 308.7691 308.9093 309.0496 309.1899 309.3301 309.4704 309.6106 309.7508 309.8910 310.0312 310.1714 310.3116 310.4517 310.5919 310.7320 310.8721 311.0122 311.1523 311.2924 311.4325 311.5726 311.7126 311.8526 311.9927 312.1327 312.2727 312.4127 312.5527 312.6926 312.8326 312.9725 313.1124 313.2524 313.3923 313.5322 313.6720 313.8119 313.9518 314.0916 314.2314 314.3713 314.5111 314.6509 314.7906 314.9304 315.0702 315.2099 315.3497 315.4894 315.6291 315.7688 315.9085 316.0481 316.1878 316.3275 316.4671 316.6067 316.7463 316.8859 317.0255 317.1651 317.3047 317.4442 317.5838 317.7233 317.8628 318.0023 318.1418 318.2813 318.4208 318.5602 318.6997 318.8391 318.9785 319.1179 319.2573 319.3967 319.5361 319.6754 319.8148 319.9541 320.0934 320.2328 320.3721 320.5113 320.6506 320.7899 320.9291 321.0684 321.2076 321.3468 321.4860 321.6252 321.7644 321.9035 322.0427 322.1818 322.3210 322.4601 322.5992 322.7383 322.8774 323.0164 323.1555 323.2945 323.4336 323.5726 323.7116 323.8506 323.9896 324.1285 324.2675 324.4064 324.5454 324.6843 324.8232 324.9621 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210105T140052.6Z 7675.583942 258 1 49.10 2 80.48 118.14 34.34 243.97 0.00 1 0.00 1 0 25 4.231e-01 1.341e-02 3.261e-01 1.003e-02 5.872519e-01 5.529911e-03 5.907843e-03 -6.000000e+00 2.499965e-01 223.46 -2.00 3.11 -2.00 321.23 0.00e+00 5.436188e-03 2.608184e-03 1.069955e-03 -6.000000e+00 1.148379e-02 279.65 -2.00 20.00 -2.00 320.69 0.00e+00 5.776 0.001 302.00 328.00 3 3.5702e+00 1.8576e-02 5.2610e-02 -6.0000e+00 6.1591e-01 8.1248e-02 2.4378e-02 3.1003e-02 -6.0000e+00 6.7017e-01 -1.6504e-01 2.3448e-02 1.4579e-02 -6.0000e+00 3.9922e-01 6.3621e-02 1.1298e-02 7.5220e-03 -6.0000e+00 1.6864e-01 9.5858e-05 -1.1837e-03 3.2853e-04 8.4569e-05 -6.0000e+00 1.3042e-02 -2.6880e-02 0.0000e+00 12 8 8 10 0 0 86.55 18.43 0.53 -0.02688 -0.03577 31 6 1 8 0 1583.540 20.96 15.00 18.43 19.29 22.2 783.60 217133 -123393 -134554 -22174 730 -161080 -90088 -81865 -158703 900000 63658 64766 -20859 10723 -45304 -48080 12371 -70181 -22678 -49489 -39361 239007 63053 -3293 -31933 -33534 43328 -2236 36949 -30022 222 5428 14440 3861 -22251 -21356 -6909 -16759 -5269 -4974 4277 19015 1814 1849 14334 -3078 18643 -10433 22402 1808 -3160 17494 5034 22927 4601 10326 -2580 1209 2818 -2541 -2747 8692 4743 5770 3281 3471 6239 -2720 3850 2005 404 1517 -785 -183 -1730 1113 3709 948 -5824 515 -2015 -556 -614 -3495 -3193 -3161 -2835 2242 -260 -1108 1496 2220 1658 2489 -1363 1431 -510 -726 -1282 551 1311 -1074 1871 -1882 -1495 -564 -628 -267 -1059 1862 745 708 -967 -964 873 566 211 -833 1386 215 -843 -1550 1205 -917 875 1217 693 1770 -684 -229 210 -79 -191 391 -44 222 -34 791 -598 -710 -264 325 -151 2122 -1752 -2243 -217 7 -3116 -928 -860 -3854 900000 622 633 -215 105 -929 -1180 191 -2621 -577 -1703 -1248 2336 772 -82 -1114 -1234 759 -60 691 -1164 8 203 556 173 -1266 -1228 -377 -1176 -396 -434 379 1564 186 195 1364 -357 1799 -1374 2242 235 -473 2356 838 3426 869 1907 -546 248 558 -530 -599 1857 1183 1567 954 997 1717 -844 1226 732 163 632 -332 -73 -645 371 1132 301 -2186 211 -982 -299 -361 -2258 -2191 -2305 -2167 1674 -198 -824 1032 1425 1030 1571 -984 1149 -479 -763 -1459 621 1403 -1076 1700 -1774 -1480 -588 -694 -314 -1369 2557 1129 1129 -1573 -1517 1295 810 303 -1255 2150 350 -1397 -2521 1842 -1398 1262 1685 942 2453 -1065 -392 390 -157 -395 849 -102 538 -86 1997 -1528 -1768 -622 729 -333 SS 20210105T141520.1Z 7675.593983 266 1 50.22 2 77.50 119.66 37.42 246.98 0.00 1 0.00 1 0 25 9.101e-02 6.443e-03 5.706e-02 2.448e-03 4.674420e-01 1.314461e-03 4.862041e-03 -6.000000e+00 5.377388e-02 223.46 -2.00 3.11 -2.00 320.34 0.00e+00 4.096218e-03 4.669692e-04 8.889166e-04 -6.000000e+00 2.383095e-03 279.65 -2.00 20.00 -2.00 319.72 0.00e+00 4.498 0.000 302.00 328.00 3 2.7539e+00 3.9451e-03 4.0991e-02 -6.0000e+00 1.3229e-01 -1.0432e-02 4.8237e-03 2.3995e-02 -6.0000e+00 1.4387e-01 -2.2901e-02 4.2213e-03 1.1050e-02 -6.0000e+00 8.5873e-02 1.1460e-03 2.1401e-03 5.6189e-03 -6.0000e+00 3.6244e-02 6.3430e-04 -8.8138e-04 8.1507e-05 5.7134e-05 -6.0000e+00 2.8021e-03 -2.7647e-02 0.0000e+00 11 8 0 10 0 0 92.54 18.42 0.32 -0.02765 -0.03427 115 24 1 8 0 432.830 20.96 15.00 18.42 20.35 22.3 783.42 -5179 -46170 -5339 -29562 -32875 -26104 -14285 -27832 -30581 -43459 -16871 -9293 -38522 3380 -10338 2519 -6127 -4156 -883 -10296 8670 -6392 -2664 -2460 -673 -7086 -307 -7701 -3427 -8049 -3344 1844 -1775 4872 1321 -4171 -1842 -3073 -2029 -3690 -1266 -2558 -703 -1719 1157 1539 -415 107 -367 2299 1212 1497 385 2355 569 1498 -170 99 406 -647 1405 48 1726 1066 517 422 1433 1433 1951 1093 81 827 -218 -304 553 305 1601 68 1561 -900 -322 -1706 -1571 -1611 -1446 -708 -718 85 -463 389 537 1319 1037 1248 1534 189 500 263 11 -721 -108 -662 80 918 -981 -1240 -1210 -829 -268 46 11 -202 -143 -163 537 674 1323 387 -84 -740 -1038 -509 -99 408 322 1102 1036 1318 845 233 59 -290 75 275 105 -133 32 -83 -373 -376 -117 -16 163 -49 -752 -60 -411 -442 -323 -167 -417 -518 -887 -278 -159 -1070 76 -323 80 -234 -169 -37 -496 354 -307 -127 -124 -35 -414 -17 -445 -189 -491 -220 132 -146 391 108 -364 -172 -343 -268 -576 -214 -469 -132 -335 223 300 -84 22 -77 493 284 383 108 689 177 477 -56 32 131 -211 468 18 693 467 234 186 606 614 904 572 47 493 -131 -174 291 146 706 30 741 -501 -204 -1227 -1225 -1338 -1172 -607 -647 78 -427 344 486 1101 823 995 1319 185 508 299 13 -888 -125 -709 87 1001 -1058 -1425 -1466 -1062 -368 69 17 -337 -237 -257 793 948 1841 563 -129 -1206 -1718 -823 -155 612 464 1511 1380 1784 1241 378 104 -537 144 554 225 -299 73 -196 -884 -871 -260 -33 336 SS 20210105T142116.2Z 7675.598104 269 1 50.44 2 76.29 120.32 38.69 248.10 0.00 1 0.00 1 0 25 1.201e-01 7.846e-03 7.731e-02 4.370e-03 4.294619e-01 2.311217e-03 4.463897e-03 -6.000000e+00 7.096746e-02 223.46 -2.00 3.11 -2.00 320.13 0.00e+00 3.870689e-03 7.700279e-04 2.678580e-04 -6.000000e+00 3.145182e-03 279.65 -2.00 20.00 -2.00 319.51 0.00e+00 4.126 0.000 302.00 328.00 3 3.9849e+00 6.7785e-03 3.7173e-02 -6.0000e+00 1.7459e-01 -3.6785e-03 8.1671e-03 2.0539e-02 -6.0000e+00 1.8987e-01 -2.4346e-02 6.8060e-03 1.0328e-02 -6.0000e+00 1.1333e-01 3.3951e-03 3.4800e-03 5.0682e-03 -6.0000e+00 4.7830e-02 2.5343e-04 -7.5572e-04 1.4567e-04 5.6281e-05 -6.0000e+00 3.6983e-03 -2.7294e-02 0.0000e+00 11 8 0 10 0 0 93.37 18.42 0.41 -0.02729 -0.03297 31 6 1 8 0 1626.770 20.96 14.99 18.42 20.71 22.4 783.57 -44403 -38640 -44549 -57513 26341 -64175 -3710 25988 -1875 -31414 -25897 -3490 -41536 2416 -9357 28362 -6311 9333 1816 3299 4123 2159 -763 -1162 -8158 -10958 -3405 -1747 -16857 -5836 -7648 -1897 -2000 4005 -4354 984 -6265 -4131 -2722 -880 -1941 -2544 2648 -2312 -2910 1811 2570 4483 2601 2908 1736 2765 3790 2798 1124 2846 687 2396 4076 -1893 1062 2443 1135 744 -430 1777 -1617 116 1456 3013 -1041 395 -534 -810 -1367 162 65 887 -203 -422 -322 -2643 -2318 -883 -1224 -776 -536 455 -307 269 941 1540 -581 1474 1794 -12 1278 -199 -354 -697 -271 -243 249 644 -1853 -1636 -907 -211 301 415 154 -304 -33 174 558 96 657 688 243 -673 -839 -342 723 352 -88 605 665 1114 899 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