File name: Pandora256s1_MiamiFL-FIU_20240115_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T095535.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240115_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240115T134509.7Z 8780.573029 85 1 29.00 2 72.06 125.26 113.43 85.54 0.00 1 0.00 1 0 17 2.111e-02 6.355e-03 5.829e-03 1.352e-03 3.585313e-01 6.753459e-04 3.842056e-03 -6.000000e+00 1.193885e-02 224.34 -2.00 3.16 -2.00 317.83 0.00e+00 6.113133e-04 1.163882e-04 2.449721e-04 -6.000000e+00 5.454399e-04 287.76 -2.00 20.00 -2.00 317.00 0.00e+00 3.203 0.000 302.00 328.00 3 2.8838e+00 1.7939e-03 3.5630e-02 -6.0000e+00 2.9375e-02 6.5337e-03 2.0384e-03 1.6432e-02 -6.0000e+00 3.1964e-02 -1.2946e-02 1.2711e-03 8.0556e-03 -6.0000e+00 1.9154e-02 2.4625e-04 6.5002e-04 2.2945e-03 -6.0000e+00 8.1929e-03 8.2579e-04 -4.0070e-06 3.8735e-05 2.6241e-05 -6.0000e+00 5.7629e-04 -2.3358e-04 0.0000e+00 12 1 1 12 1 1 98.60 26.48 0.43 -0.00023 -0.00026 48 9 1 5 0 591.660 35.00 20.01 26.48 29.81 5.6 963.56 -5533 -3010 -2501 -6188 -8697 -4887 -7560 -7753 -3906 -6524 -7267 -8078 -4165 -468 -758 1550 -69 393 -280 1380 440 -986 -1166 609 -1213 -40 1721 -2997 -1523 -991 1584 1611 1643 62 -3364 -2620 -2564 -1442 -151 -403 -556 423 684 460 370 959 604 202 454 -479 638 755 1167 1175 461 989 1409 458 172 359 1003 1489 1914 1639 176 116 -375 -699 626 621 549 567 200 456 -402 -494 -961 -1476 -1280 -1214 -993 -1598 -2015 -1735 -1147 -589 -152 368 599 374 741 126 -242 151 345 160 580 633 -57 -387 -363 -868 -520 79 -1178 -1032 -667 -353 -47 468 534 405 315 -5 -171 152 143 612 310 266 -83 454 488 341 544 226 93 790 485 88 -168 -213 -219 40 -150 -180 374 374 -189 -97 -318 -442 -548 -383 -229 -198 -485 -628 -326 -551 -641 -350 -642 -728 -856 -490 -57 -109 247 -12 72 -55 276 91 -206 -252 138 -275 -9 399 -694 -359 -233 363 411 464 18 -992 -752 -802 -484 -61 -178 -272 202 339 232 187 485 305 101 227 -248 349 421 694 744 307 634 920 301 111 230 658 1052 1401 1300 144 89 -273 -506 482 514 475 513 181 395 -343 -400 -715 -1131 -986 -1011 -892 -1533 -2090 -1806 -1271 -666 -181 430 698 439 804 132 -248 153 356 177 690 807 -75 -504 -461 -1057 -621 93 -1510 -1342 -873 -486 -66 682 802 623 488 -7 -240 210 197 847 461 404 -128 685 715 499 787 313 128 1063 684 130 -266 -338 -357 66 -255 -321 660 674 -342 -171 -554 -742 -932 SS 20240115T134946.6Z 8780.576234 88 1 12.85 2 71.22 125.96 112.42 86.03 0.00 1 0.00 1 0 17 1.934e-02 6.370e-03 5.563e-03 1.563e-03 3.437086e-01 7.814880e-04 3.675802e-03 -6.000000e+00 1.094223e-02 224.34 -2.00 3.16 -2.00 317.49 0.00e+00 8.449104e-04 1.225916e-04 1.936079e-04 -6.000000e+00 4.998908e-04 287.76 -2.00 20.00 -2.00 316.66 0.00e+00 3.067 0.000 302.00 328.00 3 2.5305e+00 2.0602e-03 3.4101e-02 -6.0000e+00 2.6923e-02 5.7174e-03 2.3353e-03 1.5672e-02 -6.0000e+00 2.9295e-02 -1.2090e-02 1.4194e-03 7.6944e-03 -6.0000e+00 1.7555e-02 -1.8114e-05 7.1255e-04 2.2421e-03 -6.0000e+00 7.5091e-03 1.3641e-03 2.3021e-05 4.4494e-05 2.4245e-05 -6.0000e+00 5.2816e-04 -4.3547e-04 0.0000e+00 12 1 1 12 9 1 82.87 26.49 0.47 -0.00044 -0.00026 31 14 1 5 0 401.550 35.00 20.00 26.49 30.03 5.6 965.70 -2415 -2959 -3547 -7357 -8318 -7188 -7622 -3763 -4109 -3998 -6491 -6741 -942 -3494 683 169 490 939 1946 2329 -255 -1173 776 1623 -622 253 -796 -2423 -1747 -1039 941 1531 1647 -904 -2961 -1771 -2196 -511 623 67 -344 542 582 628 76 144 139 -80 -99 -93 462 1296 1057 1158 792 1448 668 455 57 578 1051 1449 2043 1346 629 22 -556 -352 412 586 401 288 -88 280 -209 -492 -1190 -1734 -1110 -1386 -1049 -1497 -1823 -1882 -1194 -839 26 283 645 738 486 -127 -324 204 128 381 279 730 105 -256 -413 -911 -546 -123 -972 -857 -509 -391 -34 359 489 354 213 191 -202 389 281 530 330 -12 128 522 659 491 256 262 353 640 434 -44 -78 -343 -307 -145 -26 -186 246 390 92 -188 -402 -457 -514 -212 -293 -335 -758 -777 -636 -718 -385 -431 -447 -749 -816 -124 -556 122 32 97 196 424 527 -61 -280 187 413 -173 67 -215 -686 -464 -275 265 439 520 -306 -970 -561 -761 -190 258 33 -176 290 323 354 43 77 79 -45 -56 -53 264 797 658 766 547 967 460 313 39 407 721 1072 1569 1070 509 18 -423 -264 329 506 364 262 -80 255 -186 -414 -919 -1301 -880 -1196 -978 -1494 -1880 -1964 -1326 -957 30 334 760 870 532 -133 -331 204 138 436 333 933 138 -336 -526 -1109 -648 -145 -1201 -1120 -671 -525 -48 531 746 535 323 280 -284 534 387 735 475 -17 193 768 972 698 359 362 467 861 612 -66 -119 -528 -485 -232 -43 -324 426 687 163 -325 -687 -773 -853 SS 20240115T135354.4Z 8780.579102 91 1 11.83 2 70.47 126.60 111.52 86.47 0.00 1 0.00 1 0 17 1.722e-02 6.563e-03 4.854e-03 1.489e-03 3.335014e-01 7.446668e-04 3.593651e-03 -6.000000e+00 9.738158e-03 224.34 -2.00 3.16 -2.00 317.31 0.00e+00 6.175299e-04 1.112628e-04 1.735711e-04 -6.000000e+00 4.448996e-04 287.76 -2.00 20.00 -2.00 316.48 0.00e+00 2.957 0.000 302.00 328.00 3 2.4805e+00 1.9551e-03 3.2936e-02 -6.0000e+00 2.3960e-02 6.1598e-03 2.2132e-03 1.5241e-02 -6.0000e+00 2.6072e-02 -1.2291e-02 1.3277e-03 7.4772e-03 -6.0000e+00 1.5623e-02 3.4685e-04 6.6009e-04 2.1382e-03 -6.0000e+00 6.6827e-03 1.6162e-03 -2.9041e-05 4.2438e-05 2.4251e-05 -6.0000e+00 4.7006e-04 -2.1850e-04 0.0000e+00 12 9 1 12 1 1 98.55 26.49 0.33 -0.00022 -0.00044 33 16 1 5 0 347.750 35.00 20.00 26.49 30.31 5.6 967.80 -2327 -911 -4217 -3417 -9103 -5716 -5591 -4448 -3045 -2697 -7211 -5550 -2979 -3035 530 -202 689 -254 2055 537 853 -391 384 1255 363 222 418 -973 -849 -178 413 687 1612 -675 -2500 -2517 -1894 -917 -116 101 -355 -166 61 444 29 -335 247 271 -178 -80 1143 1091 1501 1550 989 1211 786 413 92 698 788 989 2025 1623 222 80 -547 -470 568 628 382 436 414 431 -323 -428 -841 -1489 -940 -1168 -1314 -1952 -2050 -1891 -783 -654 -237 328 435 637 353 94 -183 91 110 -30 462 426 105 -300 -440 -846 -695 -99 -919 -870 -726 -584 183 579 800 441 409 -55 -29 125 171 601 35 87 -80 524 500 430 722 23 550 778 470 256 -176 -266 -383 289 96 -247 251 357 -227 -232 -425 -538 -511 -217 -94 -466 -357 -903 -576 -597 -482 -365 -344 -967 -763 -457 -548 99 -43 154 -60 503 139 225 -104 104 332 103 66 125 -280 -230 -48 119 219 560 -232 -830 -881 -666 -374 -53 51 -187 -92 35 257 17 -197 143 154 -101 -47 660 683 947 1038 693 869 550 289 67 499 552 747 1583 1309 183 65 -420 -356 457 548 350 401 380 396 -290 -363 -652 -1176 -746 -1009 -1233 -1966 -2132 -1988 -872 -750 -275 391 519 731 391 99 -187 91 118 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