File name: Pandora256s1_MiamiFL-FIU_20240205_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T095247.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240205_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240205T141420.9Z 8801.593297 225 1 54.37 2 64.29 124.83 55.13 193.75 0.00 1 0.00 1 0 17 1.686e-02 7.040e-03 7.597e-03 2.180e-03 2.870062e-01 1.090178e-03 3.091468e-03 -6.000000e+00 9.554865e-03 224.88 -2.00 3.16 -2.00 317.47 0.00e+00 5.376714e-04 1.707711e-04 2.303862e-04 -6.000000e+00 4.355037e-04 287.71 -2.00 20.00 -2.00 316.66 0.00e+00 2.291 0.000 302.00 328.00 3 5.1662e+00 2.8732e-03 2.6196e-02 -6.0000e+00 2.3538e-02 2.7976e-02 3.2557e-03 1.3137e-02 -6.0000e+00 2.5602e-02 3.4754e-03 1.9718e-03 6.4624e-03 -6.0000e+00 1.5335e-02 -7.6408e-03 9.8504e-04 1.8323e-03 -6.0000e+00 6.5525e-03 2.1825e-04 1.4749e-04 6.3026e-05 2.0403e-05 -6.0000e+00 4.6028e-04 -1.0581e-03 0.0000e+00 11 8 0 10 0 0 100.00 26.12 0.62 -0.00106 0.00005 73 7 1 5 0 744.680 34.75 20.00 26.12 25.26 5.7 933.13 1416 -2492 1147 -352 -6940 1656 -2022 -3874 -2834 -3647 -2645 -5102 147 -8420 -4169 3089 -2246 -1388 2021 687 -2460 -3954 -1436 4813 -1379 -526 1856 -3511 -174 -804 1364 2104 144 -980 -3030 -598 -816 228 178 -73 -567 -49 607 1777 334 540 -15 447 1106 -743 -10 1102 899 959 27 507 1667 -200 -167 1365 383 1178 1939 1705 198 159 -707 -748 632 491 1100 363 72 334 -299 -327 -1191 -1924 -1777 -1245 -920 -1912 -1473 -1371 -1351 -834 -158 170 354 539 692 -256 -346 225 -292 130 697 823 165 -338 -165 -756 -771 408 -1328 -1125 -256 -310 515 373 714 802 233 4 -637 127 -3 421 85 249 -103 748 438 298 360 301 -44 627 406 -339 -469 -161 -141 274 -58 -498 592 494 36 -39 -161 -530 -809 128 -260 119 -35 -661 138 -184 -404 -327 -450 -322 -655 20 -1462 -800 613 -497 -317 467 167 -573 -928 -336 1232 -362 -142 491 -927 -46 -210 372 565 43 -306 -912 -171 -254 82 77 -34 -292 -26 335 982 187 302 -8 242 585 -404 -6 670 582 654 19 340 1125 -137 -121 970 262 859 1530 1441 170 127 -531 -550 489 431 975 338 67 299 -269 -265 -882 -1487 -1330 -1047 -869 -1875 -1539 -1503 -1478 -972 -193 214 444 648 770 -281 -351 221 -305 151 834 1089 219 -443 -216 -913 -881 476 -1707 -1431 -338 -429 747 546 1099 1250 353 6 -886 165 -4 570 124 384 -153 1153 658 430 493 420 -59 841 548 -495 -724 -240 -214 433 -98 -835 1008 860 64 -67 -266 -893 -1340 SS 20240205T175114.1Z 8801.743914 376 1 54.46 2 41.85 185.69 82.82 234.07 0.00 1 0.00 1 0 17 8.009e-03 6.333e-03 7.810e-04 5.451e-04 1.735549e-01 2.774418e-04 1.916036e-03 -6.000000e+00 4.540054e-03 224.88 -2.00 3.16 -2.00 314.82 0.00e+00 3.911295e-04 2.382638e-05 1.885242e-05 -6.000000e+00 2.069122e-04 287.71 -2.00 20.00 -2.00 314.18 0.00e+00 1.341 0.000 302.00 328.00 3 3.7616e+00 7.0466e-04 1.5471e-02 -6.0000e+00 1.1185e-02 2.9538e-02 7.8562e-04 7.9395e-03 -6.0000e+00 1.2165e-02 2.4706e-03 4.5112e-04 3.9078e-03 -6.0000e+00 7.2865e-03 -5.7172e-03 1.9952e-04 1.1249e-03 -6.0000e+00 3.1137e-03 2.7327e-03 1.6698e-04 1.5485e-05 1.4794e-05 -6.0000e+00 2.1868e-04 -1.6910e-03 0.0000e+00 10 0 0 10 0 0 100.00 26.06 0.44 -0.00169 -0.00044 588 60 1 5 0 92.600 34.75 19.99 26.06 25.37 5.7 936.84 511 -373 -174 -2416 -2479 -1117 -224 349 862 -522 -1445 -1191 -652 -393 341 258 -335 264 864 904 765 414 1125 986 955 645 158 -515 -127 754 1277 1424 1614 -595 -2219 -2021 -2179 -1082 -327 -523 -687 -656 -486 -463 -108 -170 -514 -470 -358 -33 557 783 883 951 710 951 774 321 245 511 842 1211 1496 1387 120 -145 -643 -411 562 554 305 284 263 316 27 -281 -708 -1004 -737 -1048 -1170 -1645 -1999 -1574 -1002 -720 -230 214 397 399 325 106 -144 373 273 242 583 782 121 -176 -419 -657 -383 53 -879 -849 -575 -476 -33 508 474 453 407 5 -99 185 140 212 234 43 -71 247 282 430 578 285 488 926 454 196 -79 -220 -186 151 -2 -127 238 224 -104 -164 -357 -617 -685 176 -130 -61 -875 -790 -329 -68 117 319 -204 -559 -458 -250 -168 162 123 -165 132 441 474 408 219 596 545 552 360 88 -289 -65 371 642 756 909 -349 -1235 -1086 -1265 -671 -225 -393 -562 -527 -399 -382 -88 -138 -431 -379 -278 -25 440 655 731 821 630 852 704 292 219 453 766 1110 1471 1364 117 -138 -590 -361 514 540 309 301 279 324 27 -256 -614 -867 -652 -977 -1152 -1692 -2191 -1711 -1158 -850 -286 261 484 490 386 115 -148 385 279 270 682 956 150 -224 -501 -764 -424 61 -1052 -1075 -724 -625 -45 695 676 647 554 7 -125 228 171 259 307 58 -99 339 377 550 731 343 583 1099 571 249 -106 -287 -245 205 -3 -185 354 327 -153 -237 -520 -874 -955 SS 20240205T180610.1Z 8801.754283 389 1 0.93 2 42.33 190.99 85.48 235.83 0.00 1 0.00 1 0 17 8.663e-03 7.197e-03 3.734e-03 2.844e-03 1.740594e-01 1.454740e-03 1.926926e-03 -6.000000e+00 4.913014e-03 224.88 -2.00 3.16 -2.00 314.37 0.00e+00 4.020709e-04 1.153367e-04 1.610592e-05 -6.000000e+00 2.238004e-04 287.71 -2.00 20.00 -2.00 313.78 0.00e+00 1.351 0.000 302.00 328.00 3 2.8102e+00 3.6794e-03 1.5570e-02 -6.0000e+00 1.2104e-02 2.1103e-02 4.0907e-03 7.9663e-03 -6.0000e+00 1.3162e-02 3.1704e-03 2.3545e-03 3.9161e-03 -6.0000e+00 7.8841e-03 -4.7494e-03 1.0285e-03 1.1259e-03 -6.0000e+00 3.3711e-03 7.0165e-03 6.7110e-04 8.0299e-05 1.5340e-05 -6.0000e+00 2.3651e-04 -5.4112e-03 0.0000e+00 12 9 1 12 1 1 94.52 26.07 0.38 -0.00541 -0.00037 3 24 1 5 0 230.690 34.75 20.00 26.07 26.32 5.7 943.06 -554 -829 -430 -2598 -965 -880 -796 739 262 151 -824 -997 -523 915 387 1208 979 877 1137 35 800 611 814 586 812 1176 98 376 -747 1140 253 1857 1423 -936 -2305 -2842 -2312 -1316 -508 -164 -1467 -908 -1340 -940 -87 -69 -607 -489 -478 -364 807 902 873 995 587 637 1281 687 167 649 533 1664 1462 1400 315 -34 -485 -649 268 681 947 788 307 235 -552 -226 -822 295 -631 -1125 -687 -1567 -2119 -2001 -681 -663 37 264 564 562 61 353 -455 43 -200 -572 881 519 380 84 -1062 -852 -159 148 -1021 -825 -588 -342 -79 428 491 658 215 361 -92 -104 70 522 282 -51 -255 529 311 177 819 242 656 724 334 -246 -73 -68 -254 612 -108 -27 321 100 -70 -188 -368 -466 -849 -225 -346 -181 -1097 -372 -318 -299 304 113 65 -350 -445 -240 442 201 642 536 490 652 20 460 348 466 351 487 724 61 226 -436 629 145 1061 869 -572 -1389 -1667 -1396 -876 -371 -129 -1194 -764 -1159 -814 -74 -58 -504 -403 -379 -295 650 746 757 872 530 582 1144 614 152 584 480 1583 1417 1389 312 -33 -439 -583 243 673 966 818 321 244 -555 -215 -729 258 -556 -1040 -685 -1632 -2294 -2205 -773 -787 45 322 689 677 70 384 -477 44 -209 -637 1013 627 472 103 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