File name: Pandora256s1_MiamiFL-FIU_20240206_L2Fit_fwvt1c7d20231207p1-8.txt File generation date: 20260123T095114.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240206_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.1084 492.2295 492.3506 492.4717 492.5927 492.7138 492.8348 492.9558 493.0768 493.1978 493.3188 493.4397 493.5607 493.6816 493.8025 493.9234 494.0442 494.1651 494.2859 494.4067 494.5275 494.6483 494.7691 494.8898 495.0105 495.1312 495.2519 495.3726 495.4933 495.6139 495.7346 495.8552 495.9758 496.0963 496.2169 496.3374 496.4580 496.5785 496.6990 496.8194 496.9399 497.0603 497.1808 497.3012 497.4216 497.5419 497.6623 497.7826 497.9030 498.0233 498.1436 498.2638 498.3841 498.5043 498.6246 498.7448 498.8649 498.9851 499.1053 499.2254 499.3455 499.4656 499.5857 499.7058 499.8258 499.9459 500.0659 500.1859 500.3059 500.4258 500.5458 500.6657 500.7856 500.9055 501.0254 501.1453 501.2651 501.3849 501.5048 501.6246 501.7443 501.8641 501.9838 502.1036 502.2233 502.3430 502.4626 502.5823 502.7019 502.8216 502.9412 503.0608 503.1803 503.2999 503.4194 503.5390 503.6585 503.7779 503.8974 504.0169 504.1363 504.2557 504.3751 504.4945 504.6139 504.7332 504.8526 504.9719 505.0912 505.2105 505.3297 505.4490 505.5682 505.6874 505.8066 505.9258 506.0449 506.1641 506.2832 506.4023 506.5214 506.6405 506.7595 506.8786 506.9976 507.1166 507.2356 507.3546 507.4735 507.5925 507.7114 507.8303 507.9492 508.0680 508.1869 508.3057 508.4245 508.5433 508.6621 508.7809 508.8996 509.0183 509.1370 509.2557 509.3744 509.4931 509.6117 509.7303 509.8489 509.9675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240206T125817.5Z 8802.540481 145 1 54.46 2 79.11 113.47 58.27 158.86 0.00 1 0.00 1 0 22 3.734e-03 3.709e-03 6.439e-04 6.425e-04 4.668976e+03 3.991711e+01 3.227909e+02 -6.000000e+00 2.037076e+02 287.71 -2.00 20.00 -2.00 505.27 0.00e+00 9.028698e-04 1.763893e-05 5.313163e-05 -6.000000e+00 1.045927e-04 287.71 -2.00 20.00 -2.00 500.43 0.00e+00 6.441614e-01 1.242149e-02 3.173060e-02 -6.000000e+00 7.212779e-02 224.90 -2.00 3.16 -2.00 502.03 0.00e+00 5.096 0.001 489.00 513.00 1 6.4274e+00 9.5206e-04 7.8603e-03 -6.0000e+00 5.5318e-03 1.2561e-02 2.4681e-04 8.4650e-04 -6.0000e+00 1.4463e-03 1.4352e-03 1.0221e-03 5.4748e-05 3.7986e-05 -6.0000e+00 3.3030e-04 3.8788e-03 -4.4253e-05 10 0 0 10 0 0 99.98 25.82 1.91 0.00388 0.01097 66 7 1 4 0 825.040 34.50 19.99 25.82 18.90 5.8 892.59 -1082 -710 -429 -24 276 533 519 424 418 407 126 -148 -285 -446 -409 -366 -95 70 161 254 139 162 540 505 359 368 613 -176 -256 -560 -636 -503 33 5 123 370 -33 -7 39 -150 -221 -67 218 221 611 501 395 171 -3 -373 -547 -890 -865 -498 -200 8 384 214 208 214 216 402 275 91 189 -156 10 -283 -431 -447 -271 -9 194 368 304 -62 -27 -338 -445 -424 -319 -366 -485 -21 -237 35 34 -100 -253 -107 355 272 210 419 458 302 -38 -383 -699 -692 -597 -378 193 84 137 -215 -405 -165 -169 -547 -210 42 100 301 551 624 574 344 493 130 53 132 275 106 428 335 151 371 633 -72 -120 53 -317 -617 -417 -380 -180 30 216 248 348 331 306 296 230 -65 -599 -430 -661 -447 -1066 -701 -432 -24 287 563 548 450 440 422 132 -153 -289 -457 -419 -371 -98 73 168 266 146 170 565 532 380 390 643 -183 -261 -565 -639 -511 34 5 129 392 -35 -7 40 -153 -226 -69 228 230 638 522 408 177 -4 -376 -544 -871 -843 -493 -201 8 395 221 214 220 223 409 281 93 194 -158 10 -282 -425 -435 -263 -9 191 361 299 -62 -26 -324 -431 -410 -306 -355 -473 -20 -233 35 33 -97 -249 -106 351 270 210 415 452 292 -37 -359 -654 -640 -556 -355 185 82 137 -214 -396 -161 -165 -534 -208 41 100 300 551 627 572 343 493 128 52 129 267 104 421 329 146 364 618 -69 -116 51 -303 -587 -392 -365 -174 30 211 244 343 328 306 296 230 -65 -579 -412 -628 -426 SQ 20240206T143809.4Z 8802.609831 211 1 19.00 2 59.80 128.85 55.00 184.06 0.00 1 0.00 1 0 29 5.250e-02 7.331e-02 2.017e-03 2.008e-03 2.133670e+03 1.179968e+02 2.827698e+02 -6.000000e+00 2.864730e+03 287.71 -2.00 20.00 -2.00 505.25 0.00e+00 4.903307e-03 5.482277e-05 3.325079e-04 -6.000000e+00 1.470513e-03 287.71 -2.00 20.00 -2.00 500.37 0.00e+00 1.143808e+00 3.877579e-02 4.852770e-02 -6.000000e+00 1.013225e+00 224.90 -2.00 3.16 -2.00 501.97 0.00e+00 1.980 0.000 489.00 513.00 1 7.7564e+00 2.9704e-03 8.9695e-03 -6.0000e+00 7.7723e-02 -3.7020e-03 7.7368e-04 4.6235e-04 -6.0000e+00 2.0297e-02 5.3960e-04 4.6081e-03 1.7272e-04 1.0497e-04 -6.0000e+00 4.6415e-03 9.6793e-04 3.5418e-05 12 9 9 12 1 1 99.92 25.81 2.10 0.00097 0.03293 5 2 1 4 0 3166.680 34.50 19.99 25.81 19.37 5.8 895.32 858 2207 2335 2354 2231 2270 2067 1216 940 974 462 -259 -9 -71 269 514 446 443 75 -371 -838 -708 -44 352 503 562 637 -920 -1395 -893 -322 -161 1188 840 266 -173 -740 -448 382 654 1256 1688 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-1353 -1253 -1000 -846 -495 -1841 -2658 -3265 -3399 -2500 -2182 -1357 -1116 -509 -41 505 866 1156 495 -149 405 -562 -573 567 1001 1017 813 1400 1170 1811 2423 1073 623 776 782 306 925 1683 1240 1370 1397 986 1176 1150 618 747 228 -542 -1043 -348 -406 505 SQ 20240206T144647.7Z 8802.615830 214 1 0.85 2 58.30 130.53 55.17 186.30 0.00 1 0.00 1 0 15 3.364e-03 3.354e-03 1.708e-03 1.704e-03 1.676628e+03 9.819603e+01 1.218732e+02 -6.000000e+00 1.835406e+02 287.71 -2.00 20.00 -2.00 505.24 0.00e+00 4.458565e-04 4.667091e-05 2.278005e-05 -6.000000e+00 9.425812e-05 287.71 -2.00 20.00 -2.00 500.37 0.00e+00 1.074946e-01 3.288701e-02 1.146025e-02 -6.000000e+00 6.508980e-02 224.90 -2.00 3.16 -2.00 501.97 0.00e+00 1.896 0.000 489.00 513.00 1 4.4850e+00 2.5224e-03 2.9296e-03 -6.0000e+00 4.9904e-03 1.7072e-02 6.5895e-04 3.0800e-04 -6.0000e+00 1.3072e-03 1.6618e-02 3.1396e-03 1.4718e-04 1.5379e-05 -6.0000e+00 2.9782e-04 7.5107e-03 -1.7245e-04 12 1 1 12 1 1 19.54 25.81 2.01 0.00751 0.02929 3 26 1 4 0 211.520 34.50 20.00 25.81 19.48 5.7 895.49 -997 -395 -126 -181 356 316 336 588 184 -37 247 -82 -514 -402 -155 -450 -78 11 183 -14 315 442 462 430 330 377 450 68 -398 -222 -508 -441 254 -245 256 169 79 -124 -230 5 -513 -244 -61 460 409 407 392 76 -254 -66 -357 -1003 -635 -251 -160 25 263 104 390 450 275 -101 311 324 -139 28 63 -313 -280 -63 -85 -217 533 60 330 -218 108 -292 -219 -337 -654 -426 -284 -70 -314 -95 67 -139 -160 -49 167 439 521 256 418 122 -54 -254 -330 -519 -526 -459 230 -123 238 277 -361 -280 -362 -364 -145 113 135 39 481 507 492 -14 294 351 -55 -99 481 56 320 223 101 146 231 83 94 -142 -195 -487 -129 -520 -45 -172 142 74 323 632 354 326 279 -178 -210 -461 -585 -565 -992 -396 -129 -187 374 336 359 629 196 -39 257 -85 -527 -411 -158 -460 -81 11 194 -15 335 468 489 457 350 398 477 71 -410 -223 -510 -447 260 -258 272 179 82 -129 -237 5 -528 -253 -63 480 426 427 406 79 -258 -66 -351 -982 -618 -248 -160 26 270 106 398 458 282 -103 318 329 -141 28 63 -311 -274 -61 -83 -211 521 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