File name: Pandora256s1_MiamiFL-FIU_20240223_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T100459.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240223_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240223T121921.8Z 8819.513447 252 1 54.00 2 84.48 103.80 100.42 294.90 0.00 1 0.00 1 0 17 5.792e-01 3.211e-02 2.819e-01 9.637e-03 8.205356e-01 5.274298e-03 8.277795e-03 -6.000000e+00 3.306236e-01 225.77 -2.00 3.16 -2.00 321.94 0.00e+00 -1.318826e-02 2.929897e-03 1.125124e-02 -6.000000e+00 1.548310e-02 288.01 -2.00 20.00 -2.00 321.36 0.00e+00 9.102 0.007 302.00 328.00 3 3.2517e-01 2.0813e-02 1.2542e-01 -6.0000e+00 8.1567e-01 1.1357e+00 2.7422e-02 1.2055e-01 -6.0000e+00 8.8807e-01 -1.4735e+00 1.9756e-02 3.4431e-02 -6.0000e+00 5.3075e-01 5.7276e-01 9.0311e-03 1.4496e-02 -6.0000e+00 2.2633e-01 2.2871e-05 -3.8121e-04 2.6351e-04 8.0000e-05 -6.0000e+00 1.6290e-02 2.8737e-03 0.0000e+00 12 8 8 10 0 0 -35.06 26.03 1.31 0.00287 0.00001 43 4 1 5 0 1255.800 34.75 20.00 26.03 24.19 5.8 927.46 126707 46600 147506 101659 -81470 153646 -72820 -36670 -100670 -56951 18026 11682 -28177 -79927 13607 118964 44543 21358 65275 28144 5670 -59395 -29668 183121 -15902 -22129 900000 -45043 7525 -15937 62353 68209 78343 68416 205228 900000 96936 900000 161480 45770 44851 123301 131345 256924 37934 38086 79636 84287 150133 43657 24478 83282 79312 35268 24089 22480 100703 26295 7017 58210 -3471 12 18160 12911 6911 33218 6620 3432 19042 6975 23315 9668 6507 6549 -937 7358 -7959 -10921 -6402 -9380 13209 -4030 18047 4346 -158 -1784 1908 -2080 -4350 1064 837 -5494 -1871 -1516 -3534 368 -2369 -2902 -4824 -5051 211 -6166 -9145 1903 -10597 -3538 5299 929 2621 -720 -1677 4641 -1099 371 -4227 -429 509 1934 -1276 804 1118 7140 3763 906 395 3132 -1698 1240 863 -2812 -1139 698 219 727 6 -523 1446 1329 -91 -59 -10 -1529 -2305 1190 915 1386 955 -3966 1443 -3171 -1253 -7221 -2772 416 299 -1203 -6484 488 1625 1331 821 1616 985 237 -4514 -1723 1720 -978 -1642 900000 -3554 311 -823 1640 1922 2208 2185 1928 900000 2185 900000 2730 2924 3202 4170 4071 2413 2708 2612 3516 3563 3385 3035 2276 4772 5141 3843 3123 3104 6527 3507 1061 4921 -535 2 2695 2256 1344 4868 1262 709 3756 1782 5541 2724 1846 1722 -238 1521 -1794 -2606 -1654 -2978 3946 -1651 6561 1935 -79 -959 1033 -1196 -2534 562 414 -2745 -893 -769 -2098 247 -1909 -2465 -4568 -4813 179 -5519 -7722 1451 -8968 -3260 4758 862 2680 -874 -2329 6540 -1679 550 -6317 -601 717 2825 -2040 1299 1767 10189 5369 1295 552 4137 -2319 1765 1427 -5089 -2264 1474 497 1770 17 -1349 3741 3489 -241 -160 -25 -3670 -5419 SS 20240223T123027.8Z 8819.521155 255 1 54.36 2 82.05 105.08 102.62 296.24 0.00 1 0.00 1 0 17 4.999e-01 1.196e-02 5.401e-02 2.014e-03 6.794043e-01 1.056824e-03 7.292788e-03 -6.000000e+00 2.841751e-01 225.77 -2.00 3.16 -2.00 320.90 0.00e+00 2.019719e-03 4.886629e-04 3.798024e-03 -6.000000e+00 1.293348e-02 288.01 -2.00 20.00 -2.00 320.24 0.00e+00 6.754 0.003 302.00 328.00 3 3.8726e-01 3.5051e-03 7.5834e-02 -6.0000e+00 7.0140e-01 1.7689e-01 4.6648e-03 3.9326e-02 -6.0000e+00 7.6249e-01 -2.3867e-01 4.3670e-03 1.8582e-02 -6.0000e+00 4.5648e-01 9.0375e-02 2.1125e-03 4.7845e-03 -6.0000e+00 1.9464e-01 2.4566e-04 -1.1506e-04 5.4074e-05 8.6626e-05 -6.0000e+00 1.3655e-02 2.2586e-03 0.0000e+00 12 8 8 10 0 0 16.16 26.03 0.58 0.00226 0.00139 171 18 1 5 0 317.890 34.75 20.00 26.03 25.01 5.8 933.54 -135851 -170924 -153635 -104920 -197360 -160949 -170976 -153885 -160241 -142552 -120227 -136566 -105172 -125842 -81671 -38050 -57493 -41085 -28408 -36454 -49200 -58739 -55105 -12989 -41295 -42635 -3094 -41407 -34769 -32424 -19848 -1630 -4192 1056 7271 6953 -6299 6567 6957 4031 72 12935 8035 15213 4285 5821 8750 8677 6749 6084 6651 7180 7652 6666 5720 5139 8406 3769 -950 7366 -125 2350 5075 4585 2706 2336 1262 704 2178 2691 3475 1241 588 1351 -1019 554 -2446 -5470 -2608 -943 -1645 -1615 -910 -684 -680 -452 -90 654 229 975 -91 -633 -1035 -1203 -760 -494 -276 268 -682 -729 -608 -1649 -1238 -183 -2110 -1427 -755 -167 128 208 344 711 80 34 -537 -259 296 513 456 227 728 1110 854 533 492 328 341 657 385 -84 -241 -155 -239 27 -207 -59 455 312 -31 -163 -170 -526 -681 -1228 -2585 -2113 -866 -3761 -2087 -2653 -2297 -2896 -2352 -1677 -2549 -1818 -3461 -1829 -665 -1389 -936 -619 -909 -1430 -1881 -1786 -304 -1395 -1549 -77 -1472 -1141 -1127 -729 -60 -185 48 299 284 -324 355 462 332 7 1192 819 1482 472 647 969 1001 837 820 998 1207 1413 1359 1256 1081 1767 828 -213 1641 -28 573 1377 1414 899 768 417 243 826 1174 1661 581 274 643 -453 218 -932 -2204 -1156 -450 -930 -1047 -645 -476 -507 -359 -75 557 195 795 -70 -461 -735 -895 -637 -447 -290 300 -838 -895 -698 -1849 -1272 -189 -2386 -1586 -885 -209 166 305 524 1145 131 53 -809 -400 459 786 743 384 1212 1775 1324 802 759 489 497 1010 634 -149 -444 -306 -498 57 -447 -133 1048 731 -72 -367 -377 -1106 -1399 SS 20240223T124548.9Z 8819.531816 260 1 54.43 2 78.73 106.90 105.62 298.18 0.00 1 0.00 1 0 17 1.648e-01 7.971e-03 9.109e-03 6.653e-04 5.243025e-01 3.375730e-04 5.520591e-03 -6.000000e+00 9.366656e-02 225.77 -2.00 3.16 -2.00 319.46 0.00e+00 1.556905e-03 9.645798e-05 1.045523e-03 -6.000000e+00 4.262772e-03 288.01 -2.00 20.00 -2.00 318.68 0.00e+00 4.940 0.001 302.00 328.00 3 2.5231e-01 9.6114e-04 5.4585e-02 -6.0000e+00 2.3119e-01 3.8484e-02 1.1415e-03 2.4741e-02 -6.0000e+00 2.5132e-01 -5.4245e-02 8.9046e-04 1.2336e-02 -6.0000e+00 1.5046e-01 1.6885e-02 4.6674e-04 3.6680e-03 -6.0000e+00 6.4158e-02 1.8144e-03 3.6523e-05 1.8428e-05 4.1933e-05 -6.0000e+00 4.5006e-03 1.9669e-03 0.0000e+00 11 8 0 10 0 0 19.97 26.00 0.46 0.00197 0.00224 519 53 1 5 0 104.860 34.50 19.99 26.00 26.36 5.8 942.34 -58938 -42978 -56404 -45561 -56898 -61905 -63100 -61120 -47277 -46174 -46673 -41258 -30239 -29831 -19003 -10244 -9883 -10399 -6037 -8643 -8697 -8293 -7428 -6120 -7140 -6652 -5274 -7778 -9137 -5875 -3412 -1090 -748 -1389 -3107 -4533 -3054 -1345 1149 1917 729 1862 1166 2115 1748 1722 793 1085 636 1064 1572 2070 2173 2231 1933 2184 1523 744 438 1035 1423 2214 3100 2769 1323 672 334 -161 877 1242 993 699 484 133 -561 -1162 -1692 -1952 -1777 -1646 -1580 -1864 -2093 -1781 -1219 -583 131 448 405 532 335 -93 -400 -451 -142 -147 487 686 -97 -355 -598 -967 -481 -119 -1168 -1059 -849 -539 125 529 444 327 157 46 -183 312 292 482 297 213 162 633 624 599 539 156 344 800 395 2 -256 -354 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