File name: Pandora256s1_MiamiFL-FIU_20240413_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T102427.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240413_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240413T112844.2Z 8869.478290 42 1 54.63 2 84.45 82.31 120.41 28.20 0.00 1 0.00 1 0 25 7.324e-01 4.256e-02 3.387e-01 1.551e-02 9.237803e-01 9.033527e-03 8.886151e-03 -6.000000e+00 4.327568e-01 229.45 -2.00 3.16 -2.00 322.14 0.00e+00 -2.231668e-02 4.913724e-03 1.146010e-02 -6.000000e+00 2.034135e-02 290.22 -2.00 20.00 -2.00 321.54 0.00e+00 9.062 0.007 302.00 328.00 3 7.9121e-01 3.5450e-02 1.3323e-01 -6.0000e+00 1.0805e+00 1.5782e+00 4.5786e-02 1.3799e-01 -6.0000e+00 1.1793e+00 -1.8869e+00 2.9923e-02 3.5555e-02 -6.0000e+00 6.9670e-01 6.9292e-01 1.4037e-02 2.0652e-02 -6.0000e+00 2.9673e-01 1.1698e-05 8.8259e-05 4.2705e-04 1.8580e-04 -6.0000e+00 2.1372e-02 4.2087e-03 0.0000e+00 12 8 8 10 0 0 98.63 26.29 1.49 0.00421 0.00487 24 2 1 5 0 2276.110 34.75 19.99 26.29 23.90 5.8 924.10 48729 900000 126666 86439 72317 900000 2932 -34841 -21327 -48948 118435 39635 136267 -44301 14881 156553 133291 -26900 900000 132463 -648 -53058 -20594 900000 63985 -2510 290225 -30522 900000 -12763 900000 14018 142839 900000 105517 900000 143763 900000 900000 85268 30103 900000 900000 900000 36771 -12287 63432 129190 900000 50968 18136 183348 900000 42853 24425 14617 367861 170076 34058 346310 930 -8405 30670 14677 12264 43311 7089 15516 20912 13172 74614 30003 13621 1153 -220 -3256 539 -20692 -52744 1478 33700 3237 15243 2092 -6354 -7273 7453 -1357 -8894 6660 7737 3364 5852 813 2083 8441 -1472 -2314 -2708 -3645 1463 -10485 -9913 13756 -16145 -1393 6970 4298 3851 -554 239 2319 -2808 2846 -5667 -2203 -84 -399 542 1112 2377 7844 6940 -1623 -713 4306 -4966 -344 435 -4240 -1709 467 1621 515 1282 -1296 2507 528 -481 -787 215 -1365 -916 1938 900000 2084 1778 1388 900000 113 -2245 -1345 -4296 1949 1467 2055 -4374 877 2361 2559 -2545 900000 2361 -41 -5311 -1553 900000 2632 -206 4378 -2637 900000 -753 900000 769 2585 900000 2547 900000 2385 900000 900000 4373 2951 900000 900000 900000 2829 -1446 3349 3508 900000 3306 1806 3872 900000 4331 3168 2205 5549 5387 3853 5224 128 -1331 3655 2280 2035 5161 1219 2598 3722 2901 9679 6245 3226 284 -48 -648 97 -4744 -18935 368 7167 1079 4989 833 -2933 -3576 3283 -661 -4588 2793 2988 1294 2198 347 1015 4545 -1024 -1871 -2397 -3261 1163 -8398 -7192 7926 -13467 -1061 5194 3585 3642 -634 281 2913 -3827 3633 -7623 -2795 -106 -531 753 1574 3230 10566 9096 -2257 -956 5352 -6704 -482 642 -7616 -3364 982 3628 1261 3368 -3367 6400 1391 -1262 -2137 533 -3203 -2079 SS 20240413T113939.0Z 8869.485869 45 1 54.49 2 82.01 83.46 119.25 30.48 0.00 1 0.00 1 0 17 6.006e-01 1.572e-02 5.735e-02 2.238e-03 7.625479e-01 1.203252e-03 8.126696e-03 -6.000000e+00 3.460761e-01 229.45 -2.00 3.16 -2.00 321.20 0.00e+00 1.776144e-03 6.089273e-04 4.744356e-03 -6.000000e+00 1.568662e-02 290.22 -2.00 20.00 -2.00 320.56 0.00e+00 6.718 0.003 302.00 328.00 3 4.7571e-01 4.2504e-03 7.9185e-02 -6.0000e+00 8.6096e-01 2.8811e-01 5.8301e-03 4.7843e-02 -6.0000e+00 9.3310e-01 -4.4591e-01 5.3518e-03 2.1427e-02 -6.0000e+00 5.5771e-01 1.8173e-01 2.5136e-03 5.2105e-03 -6.0000e+00 2.3647e-01 2.0966e-04 -2.4809e-04 5.8168e-05 9.8191e-05 -6.0000e+00 1.6422e-02 3.4433e-03 0.0000e+00 12 8 8 10 0 0 57.10 26.28 0.60 0.00344 0.00158 166 17 1 5 0 328.220 34.75 20.00 26.28 24.40 5.8 927.85 -179504 -178360 -149513 -182174 -206351 -182922 -208022 -163453 -186190 -202155 -174069 -150308 -123498 -145611 -115309 -43855 -58969 -66061 -53711 -48136 -55547 -71422 -60853 -19368 -57411 -60610 -18844 -51563 -34573 -44838 -11266 -9379 3629 14939 -4018 5267 5955 6451 21476 6615 22470 20799 22777 31061 7557 10239 15313 13980 20727 6350 9853 17897 12082 13143 9212 10447 15761 4824 5669 10708 3346 5965 7337 7109 5381 7082 4289 3108 4660 3719 5008 3321 1575 1944 779 -2304 -4200 -4568 -6493 -1349 -1410 -2411 -169 -594 -209 -218 205 45 674 956 312 -601 -1746 -1615 -1547 -1175 -881 -270 -1274 -1004 -917 -1934 -1738 -241 -2717 -1913 -926 -694 75 286 292 616 418 -238 -777 60 209 396 320 135 537 1241 1417 1050 895 717 585 941 521 -93 105 73 -130 15 -71 -63 506 342 6 -191 -468 -861 -911 -2030 -2336 -1730 -2823 -3693 -2515 -3950 -2248 -3617 -4986 -3419 -2657 -2129 -4068 -3020 -680 -1210 -1615 -1254 -1114 -1406 -2105 -1687 -389 -1830 -2103 -436 -1598 -890 -1399 -305 -303 120 476 -149 176 217 279 984 423 1388 1407 1586 2034 632 852 1243 1202 1769 681 1148 2176 1722 2031 1582 1858 2742 931 1048 1839 638 1225 1709 1717 1407 1807 1129 870 1438 1340 1968 1384 658 759 279 -763 -1341 -1516 -2515 -598 -740 -1351 -102 -385 -145 -161 158 36 531 723 222 -408 -1175 -1147 -1254 -1030 -902 -295 -1534 -1208 -1033 -1977 -1748 -241 -2777 -2056 -1047 -849 94 409 440 987 680 -380 -1191 88 313 620 531 219 903 1987 2184 1572 1295 1074 860 1377 877 -169 199 149 -267 32 -160 -150 1213 834 14 -443 -1072 -1858 -1915 SS 20240413T115431.4Z 8869.496197 50 1 54.46 2 78.67 85.01 117.56 33.45 0.00 1 0.00 1 0 17 2.734e-01 8.799e-03 1.296e-02 7.230e-04 5.921490e-01 3.733426e-04 6.179329e-03 -6.000000e+00 1.575491e-01 229.45 -2.00 3.16 -2.00 319.86 0.00e+00 1.315628e-03 1.221142e-04 1.419203e-03 -6.000000e+00 7.140335e-03 290.22 -2.00 20.00 -2.00 319.07 0.00e+00 4.917 0.001 302.00 328.00 3 3.2671e-01 1.1006e-03 5.6374e-02 -6.0000e+00 3.9195e-01 2.9346e-02 1.3365e-03 2.8757e-02 -6.0000e+00 4.2478e-01 -7.2258e-02 1.1032e-03 1.4067e-02 -6.0000e+00 2.5389e-01 2.6374e-02 5.7041e-04 3.8976e-03 -6.0000e+00 1.0766e-01 1.5862e-03 -8.1622e-06 1.9563e-05 4.7111e-05 -6.0000e+00 7.4750e-03 2.6605e-03 0.0000e+00 11 8 0 10 0 0 2.13 26.25 0.45 0.00266 0.00260 492 50 1 5 0 110.680 34.75 20.00 26.25 25.23 5.7 932.76 -96843 -82188 -91227 -79690 -101182 -94647 -94867 -94442 -82288 -77621 -73199 -69220 -52160 -49484 -35059 -21976 -25678 -20475 -15507 -17276 -15745 -20183 -15944 -9509 -14877 -11619 -10980 -14235 -12287 -10870 -7333 -4624 -1905 -2919 -3988 -5006 -4003 -2206 1313 1490 1237 2796 2441 3558 1890 2179 1736 1438 1656 2061 2299 3223 3469 3053 2486 2296 2622 976 693 1347 1196 2237 3061 3193 1544 955 433 75 1206 1192 1043 939 682 251 -417 -914 -1712 -2187 -1971 -1508 -1297 -1831 -2192 -1779 -1136 -602 -113 128 352 685 429 20 -452 -262 -249 -317 228 450 -129 -431 -673 -998 -567 -253 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