File name: Pandora256s1_MiamiFL-FIU_20240420_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T102619.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240420_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240420T113243.7Z 8876.481061 185 1 53.95 2 82.16 80.65 121.79 293.71 0.00 1 0.00 1 0 17 6.662e-01 2.380e-02 2.905e-01 6.351e-03 8.306156e-01 3.553388e-03 8.259564e-03 -6.000000e+00 3.874620e-01 229.76 -2.00 3.16 -2.00 321.71 0.00e+00 -1.109278e-02 2.056695e-03 5.953831e-03 -6.000000e+00 1.864833e-02 290.60 -2.00 20.00 -2.00 321.14 0.00e+00 6.833 0.003 302.00 328.00 3 1.9639e+00 1.3881e-02 8.9239e-02 -6.0000e+00 9.6188e-01 5.8523e-01 1.9672e-02 7.3752e-02 -6.0000e+00 1.0426e+00 -8.6895e-01 1.7515e-02 2.2526e-02 -6.0000e+00 6.2250e-01 3.4651e-01 7.9151e-03 1.3601e-02 -6.0000e+00 2.6422e-01 3.8929e-05 -6.0202e-04 1.7122e-04 9.0160e-05 -6.0000e+00 1.8587e-02 1.9197e-03 0.0000e+00 12 8 8 10 0 0 -30.45 26.63 1.06 0.00192 -0.00260 39 4 1 5 0 1383.240 35.25 20.00 26.63 29.98 5.6 963.11 -97424 -102113 -95657 900000 -158535 900000 -152184 -84157 -162333 -152875 -586 -109895 -48213 -157113 -90247 205152 129233 -22168 51710 227041 -69598 -88622 -54471 900000 -60795 -32568 900000 -82707 71443 -20874 13769 -12229 16976 74628 69751 117203 138546 232785 201045 23594 14315 257533 140109 900000 10597 19268 40496 54285 64734 39400 11496 41427 50610 19467 10215 19827 59635 40933 7823 67518 7814 1982 9194 10502 4185 24382 6559 4992 9689 1196 16798 7666 2471 2855 2160 11594 -1070 -10910 -19884 -488 5901 -5913 8888 -539 -502 -2999 -2267 -2240 -574 4639 3599 -2994 -193 -2623 -1396 -484 -2516 -1072 -2250 -1775 198 -4823 -3312 968 -6627 -2136 482 1419 2077 -463 170 1895 -685 1075 -2102 66 -771 670 -571 307 500 3452 2274 920 856 1122 -1333 132 1185 -1579 -207 -279 57 1011 115 -172 1412 690 -398 -749 -346 -846 -1233 -1041 -1264 -1130 900000 -2854 900000 -2739 -899 -4383 -4128 -4 -2225 -624 -7247 -2538 1269 800 -466 544 1405 -2498 -3784 -1753 900000 -2671 -1149 900000 -4401 752 -568 307 -416 494 1293 1208 1233 1286 1440 1493 1256 948 1594 2861 900000 754 1240 2105 2519 2844 2414 1046 3153 3883 2241 1391 2601 5461 4483 1133 5097 1069 310 1519 1937 873 4119 1331 1087 2260 352 4667 2433 812 873 599 2604 -256 -2970 -6730 -163 2191 -2861 4119 -267 -267 -1736 -1364 -1380 -345 2539 1860 -1568 -107 -1437 -865 -349 -2169 -1051 -2444 -1929 198 -4556 -2810 790 -6263 -2047 478 1510 2451 -588 243 2870 -1088 1648 -3195 95 -1136 1020 -931 511 813 5209 3344 1330 1199 1519 -1814 189 1936 -2813 -406 -592 119 2255 279 -439 3624 1806 -1042 -1873 -800 -1837 -2604 SS 20240420T114821.0Z 8876.491909 190 1 54.32 2 78.68 82.26 124.91 296.23 0.00 1 0.00 1 0 17 3.395e-01 8.834e-03 3.321e-02 1.352e-03 6.311611e-01 7.060291e-04 6.627197e-03 -6.000000e+00 1.959132e-01 229.76 -2.00 3.16 -2.00 320.26 0.00e+00 1.629499e-03 2.628959e-04 2.009790e-03 -6.000000e+00 8.881207e-03 290.60 -2.00 20.00 -2.00 319.49 0.00e+00 4.921 0.001 302.00 328.00 3 1.4536e+00 2.1667e-03 5.7771e-02 -6.0000e+00 4.8769e-01 3.1751e-02 2.7308e-03 3.1822e-02 -6.0000e+00 5.2835e-01 -9.5092e-02 2.4045e-03 1.5571e-02 -6.0000e+00 3.1579e-01 3.2545e-02 1.2129e-03 4.2235e-03 -6.0000e+00 1.3390e-01 4.9315e-04 -9.7050e-05 3.6392e-05 5.8079e-05 -6.0000e+00 9.2832e-03 1.4137e-03 0.0000e+00 11 8 0 10 0 0 3.42 26.62 0.52 0.00141 0.00068 187 19 1 5 0 290.460 35.00 20.00 26.62 31.04 5.7 969.69 -102780 -108861 -124360 -100013 -122338 -96616 -118006 -113645 -97498 -108535 -86123 -89454 -55393 -74436 -51903 -27599 -25246 -36680 -13270 -36003 -27013 -30128 -21061 -12188 -24939 -19168 -10629 -28679 -20714 -19110 -10644 -9192 -3933 -4643 -4897 -3234 -6510 -1695 249 2582 -932 4935 3578 4464 2139 2297 2094 2116 3330 1309 1390 3801 2861 3417 2316 1981 3979 1880 127 1563 1033 1722 2844 3616 1891 1864 889 300 1265 1647 1865 869 1179 115 -158 -1038 -1584 -2204 -2660 -1202 -1275 -2025 -2045 -1536 -1006 -776 -177 527 553 861 375 -155 -754 -677 -620 -234 547 432 -385 -255 -473 -1112 -1063 -145 -1331 -1156 -769 -358 361 653 584 460 173 171 -305 245 182 479 181 24 81 749 764 447 253 152 189 658 367 -141 -334 -256 -419 43 -63 -170 365 437 -56 -22 -342 -413 -319 -1003 -1334 -1934 -1200 -1693 -1019 -1680 -1783 -1491 -2032 -1362 -1651 -913 -1903 -1334 -669 -679 -1228 -383 -1386 -983 -1140 -766 -447 -1134 -877 -457 -1436 -942 -919 -557 -567 -268 -343 -351 -227 -522 -155 28 337 -143 769 541 688 343 376 351 367 598 257 304 911 762 988 721 648 1318 636 42 510 351 587 1090 1543 863 833 395 138 641 886 1106 544 730 68 -86 -512 -796 -1130 -1415 -746 -861 -1572 -1624 -1292 -902 -695 -166 505 529 790 345 -134 -630 -584 -561 -243 616 524 -483 -319 -587 -1327 -1171 -160 -1515 -1391 -974 -460 504 965 906 752 284 270 -457 368 276 724 291 41 135 1195 1177 700 381 221 267 969 581 -239 -597 -484 -800 86 -131 -357 781 950 -121 -46 -704 -836 -630 SS 20240420T115346.0Z 8876.495671 193 1 54.42 2 77.47 82.81 125.97 297.15 0.00 1 0.00 1 0 17 2.366e-01 8.337e-03 1.826e-02 9.718e-04 5.827834e-01 5.010890e-04 6.094192e-03 -6.000000e+00 1.365328e-01 229.76 -2.00 3.16 -2.00 319.79 0.00e+00 1.806110e-03 1.598472e-04 1.403866e-03 -6.000000e+00 6.189213e-03 290.60 -2.00 20.00 -2.00 318.99 0.00e+00 4.480 0.001 302.00 328.00 3 1.3049e+00 1.4713e-03 5.2475e-02 -6.0000e+00 3.3988e-01 1.6403e-02 1.7851e-03 2.8199e-02 -6.0000e+00 3.6821e-01 -6.6848e-02 1.4696e-03 1.4015e-02 -6.0000e+00 2.2008e-01 2.0990e-02 7.6199e-04 4.0286e-03 -6.0000e+00 9.3317e-02 9.0660e-04 -3.6537e-05 2.6398e-05 4.9193e-05 -6.0000e+00 6.4694e-03 1.2813e-03 0.0000e+00 11 8 0 10 0 0 -7.39 26.62 0.48 0.00128 0.00101 268 27 1 5 0 203.040 35.00 20.00 26.62 31.43 5.7 972.93 -81636 -66207 -55015 -80296 -78886 -82555 -91728 -79026 -72915 -66496 -69871 -64158 -47277 -49711 -35702 -16246 -19719 -17105 -8956 -13009 -14333 -16822 -17221 -8400 -12789 -9441 -5887 -16367 -12859 -11642 -3884 -5371 -767 141 -6678 -5364 -4264 -1792 802 633 1179 2087 1548 2881 1780 2476 1457 1454 1533 365 1252 2762 2694 2169 2528 2061 2601 1317 469 1407 1168 1835 2817 2691 1646 1035 767 -166 744 1248 1231 648 64 299 -334 -1215 -1834 -2486 -2283 -1455 -1487 -1721 -2136 -1716 -1056 -614 317 655 684 770 299 -238 -510 -260 -458 -8 466 690 -153 -290 -567 -1090 -882 -356 -1167 -1203 -733 -565 136 686 659 350 315 -8 -99 115 171 399 259 133 143 665 765 479 412 66 238 775 298 -27 -243 -349 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