File name: Pandora256s1_MiamiFL-FIU_20240502_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T102849.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240502_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240502 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240502T112129.5Z 8888.473258 171 1 38.60 2 82.63 76.19 46.83 155.30 0.00 1 0.00 1 0 17 6.585e-01 2.595e-02 3.205e-01 8.902e-03 9.017058e-01 5.106164e-03 8.905711e-03 -6.000000e+00 3.869034e-01 230.23 -2.00 3.16 -2.00 321.91 0.00e+00 -1.125603e-02 3.060497e-03 9.961429e-04 -6.000000e+00 1.953505e-02 291.25 -2.00 20.00 -2.00 321.33 0.00e+00 7.198 0.003 302.00 328.00 3 1.7266e+00 2.0791e-02 8.4222e-02 -6.0000e+00 9.6316e-01 8.3980e-01 2.9382e-02 4.7922e-02 -6.0000e+00 1.0457e+00 -1.1737e+00 2.5098e-02 2.2779e-02 -6.0000e+00 6.2445e-01 4.6537e-01 1.1205e-02 9.6130e-03 -6.0000e+00 2.6507e-01 3.0834e-05 -9.8807e-04 2.3602e-04 1.0852e-04 -6.0000e+00 1.9016e-02 1.7197e-03 0.0000e+00 12 9 9 12 1 1 99.09 26.66 0.77 0.00172 -0.00571 22 3 1 5 0 1677.990 35.00 20.00 26.66 30.21 5.7 963.28 10747 -26083 -26112 900000 -172345 900000 -108928 -66320 -100723 -151167 900000 6948 114967 -146138 -75724 900000 900000 -78250 23721 318390 -36463 -84291 -12422 900000 -49391 -67883 900000 -76014 -1288 -2612 900000 49188 302104 63124 27516 23747 213707 92065 900000 55778 17667 135944 256073 900000 34677 32507 67620 82661 85063 9052 25289 62941 75863 31136 42209 35143 86601 35492 19167 82780 17717 12192 12926 15513 -203 19372 6929 16249 13011 1103 30991 8671 8354 -1028 6983 2370 -4672 2993 -26059 4528 12714 69 2448 -1191 -5194 432 -2833 3197 -3108 5735 2338 -2209 -3882 -3220 -2589 281 -2101 364 -2595 -2344 -1198 -3861 -3844 3753 -6264 -3158 2344 778 754 -239 -2022 19 -910 159 -813 212 -902 812 856 276 -1661 3304 2647 1190 1682 2534 -1492 2168 1840 -1048 -721 270 431 286 -142 34 1414 259 -544 197 305 -1069 -2238 93 -226 -226 900000 -5023 900000 -1716 -784 -1904 -5120 900000 60 996 -7482 -2267 900000 900000 -3143 355 2759 -977 -3519 -291 900000 -2097 -3647 900000 -3952 -29 -61 900000 938 2618 1258 739 638 1852 1595 900000 2078 1087 2709 2219 900000 1803 1690 2461 2650 2801 690 1841 3545 4141 2914 3803 3593 5478 3690 2209 4734 1919 1500 1792 2379 -39 3038 1243 2816 2615 289 6632 2412 2280 -286 1603 505 -1004 617 -8219 1267 3900 28 1078 -582 -2822 235 -1515 1809 -1687 3002 1183 -1112 -1974 -1744 -1608 182 -1643 323 -2604 -2367 -1123 -3327 -2997 2702 -5339 -2766 2064 757 824 -305 -2745 27 -1368 235 -1166 292 -1275 1184 1316 438 -2622 4719 3654 1618 2205 3493 -2105 2899 2870 -1950 -1386 560 956 684 -341 86 3587 673 -1406 478 738 -2432 -4970 SS 20240502T113923.0Z 8888.485682 176 1 54.33 2 78.70 77.98 45.29 160.70 0.00 1 0.00 1 0 17 4.024e-01 1.005e-02 2.318e-02 1.037e-03 6.700174e-01 5.423623e-04 7.016220e-03 -6.000000e+00 2.326153e-01 230.24 -2.00 3.16 -2.00 320.25 0.00e+00 1.430262e-03 2.043732e-04 2.258143e-03 -6.000000e+00 1.055516e-02 291.25 -2.00 20.00 -2.00 319.49 0.00e+00 4.926 0.001 302.00 328.00 3 8.8609e-01 1.6618e-03 5.8964e-02 -6.0000e+00 5.7960e-01 7.2059e-02 2.0920e-03 3.3964e-02 -6.0000e+00 6.2761e-01 -1.2445e-01 1.8356e-03 1.6335e-02 -6.0000e+00 3.7512e-01 4.6320e-02 9.2941e-04 4.3332e-03 -6.0000e+00 1.5901e-01 8.0979e-04 -4.5710e-05 2.7242e-05 5.9802e-05 -6.0000e+00 1.1004e-02 1.0434e-03 0.0000e+00 12 9 8 11 8 0 36.83 26.64 0.46 0.00104 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-1104 -489 -641 -161 -83 -722 -598 -355 -354 385 306 434 632 533 1024 486 476 592 293 496 289 712 1105 1055 1017 985 886 1225 563 415 752 378 825 1495 1375 911 820 382 495 918 774 1158 756 430 493 -80 -450 -793 -1167 -1443 -757 -907 -1242 -1615 -1514 -964 -786 -265 153 464 456 246 -68 -665 -571 -855 -260 238 551 -393 -406 -1094 -1309 -898 -202 -1304 -1394 -845 -446 153 733 930 485 323 69 -342 333 586 685 563 113 284 1304 1152 1195 647 323 207 1159 348 178 -359 -568 -614 -102 -278 -283 817 923 46 -320 -679 -884 -1124 SS 20240502T114446.8Z 8888.489430 179 1 54.39 2 77.51 78.52 44.89 162.40 0.00 1 0.00 1 0 17 2.851e-01 9.062e-03 1.324e-02 7.243e-04 6.180459e-01 3.755931e-04 6.450782e-03 -6.000000e+00 1.648092e-01 230.24 -2.00 3.16 -2.00 319.83 0.00e+00 1.342750e-03 1.210658e-04 1.503428e-03 -6.000000e+00 7.477970e-03 291.25 -2.00 20.00 -2.00 319.02 0.00e+00 4.492 0.001 302.00 328.00 3 6.7838e-01 1.1033e-03 5.3574e-02 -6.0000e+00 4.1065e-01 4.4358e-02 1.3399e-03 3.0016e-02 -6.0000e+00 4.4466e-01 -8.0142e-02 1.1034e-03 1.4638e-02 -6.0000e+00 2.6577e-01 2.7460e-02 5.7169e-04 4.0105e-03 -6.0000e+00 1.1267e-01 1.5817e-03 -1.5460e-05 1.9351e-05 4.9426e-05 -6.0000e+00 7.7957e-03 7.2329e-04 0.0000e+00 11 8 0 10 0 0 8.38 26.65 0.41 0.00072 0.00061 437 45 1 5 0 124.440 35.00 20.00 26.65 31.70 5.6 974.02 -93683 -93700 -92324 -88676 -95076 -101330 -109220 -97917 -85667 -86222 -73185 -63526 -57861 -50482 -34219 -23284 -19725 -23602 -17610 -17812 -16413 -19103 -17221 -10005 -14568 -11838 -9316 -13479 -13936 -13141 -7473 -4991 31 -2140 -6510 -5758 -5946 -2279 1195 1717 1015 3580 2375 3051 2138 2636 1730 999 1026 1934 2349 2828 3045 2945 2868 2669 2226 958 941 1072 1666 2140 3120 3198 1791 1464 484 138 1169 1326 1275 940 571 149 -436 -984 -1555 -2216 -2063 -1696 -1522 -1611 -2404 -1890 -1267 -718 -77 354 524 664 331 -253 -569 -460 -276 -66 310 636 -175 -460 -635 -1149 -685 -157 -1074 -1037 -739 -461 145 481 579 395 252 78 -35 174 243 398 408 87 200 573 680 606 567 103 284 707 345 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