File name: Pandora256s1_MiamiFL-FIU_20240507_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T102951.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240507_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240507T111945.6Z 8893.472056 56 1 54.00 2 82.32 74.76 75.16 79.31 0.00 1 0.00 1 0 17 6.933e-01 2.161e-02 2.662e-01 6.270e-03 8.428678e-01 3.615541e-03 8.404716e-03 -6.000000e+00 4.078787e-01 230.43 -2.00 3.16 -2.00 321.77 0.00e+00 -5.087398e-03 2.160581e-03 5.244767e-03 -6.000000e+00 2.049656e-02 291.52 -2.00 20.00 -2.00 321.19 0.00e+00 6.953 0.003 302.00 328.00 3 1.8308e+00 1.4551e-02 8.6354e-02 -6.0000e+00 1.0169e+00 5.7451e-01 2.1130e-02 6.1865e-02 -6.0000e+00 1.1058e+00 -7.7372e-01 1.9491e-02 2.4054e-02 -6.0000e+00 6.5912e-01 2.9142e-01 8.7416e-03 7.8482e-03 -6.0000e+00 2.8349e-01 3.8087e-05 -1.3154e-04 1.7155e-04 8.1162e-05 -6.0000e+00 2.0461e-02 1.4614e-03 0.0000e+00 12 8 8 10 0 0 26.87 26.75 0.93 0.00146 0.00047 38 4 1 5 0 1420.820 35.25 20.00 26.75 30.70 5.7 967.05 900000 -199831 900000 900000 -66433 900000 -162688 -165604 -214132 -187478 -33169 -72670 -121061 -134704 -96223 900000 -4934 -91233 900000 167934 -48970 -126785 -68374 900000 -53961 -67806 900000 -65192 255731 -21292 900000 -4063 381932 83836 9912 900000 150735 900000 900000 22239 7560 78215 144635 900000 10310 7419 29505 30740 86430 30630 18886 54917 48852 23024 9556 8987 47084 14139 8856 36190 -5984 -4234 10421 6067 4782 27062 11076 4351 10475 7216 12594 5203 2173 1933 4377 3710 1869 -5772 -20584 3936 8263 -1983 4275 -2556 -2656 1953 -1338 -8 -2861 3895 2358 -3043 -1101 -4411 1047 501 -1814 -313 -1548 -2286 706 -4107 -4866 -66 -3621 -2568 1943 1202 1494 -509 -612 2382 -1313 491 -1800 -377 -1011 359 -217 108 344 3420 1765 617 335 2189 -798 172 1037 -769 -843 180 28 227 39 -317 1437 969 -33 -230 -78 -631 -2069 900000 -3878 900000 900000 -405 900000 -1984 -2387 -5699 -4158 -202 -604 -2014 -3211 -1921 900000 -57 -2726 900000 1024 -1045 -5799 -1835 900000 -1547 -2357 900000 -2068 1560 -442 900000 -102 2329 1074 254 900000 1011 900000 900000 963 429 2337 2293 900000 616 457 1476 1575 2688 1812 1417 3249 3397 2275 1160 1157 4279 1768 1113 3311 -843 -640 1557 1077 916 4126 1999 889 2261 1862 3395 1571 663 551 1094 833 404 -1398 -6629 1195 2852 -878 1971 -1226 -1364 1018 -754 -4 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0.00028 212 22 1 5 0 256.760 35.25 20.00 26.74 31.77 5.6 973.70 -119354 -116567 -118210 -93215 -134767 -106649 -146480 -121994 -113356 -108922 -102646 -87573 -72329 -68128 -49459 -25476 -38979 -36056 -22231 -28171 -27050 -28396 -27599 -7840 -19754 -20402 -7547 -20047 -19995 -16693 -10559 -7714 -1367 -6978 -5941 -7147 -4748 -2835 3766 1777 749 5554 3411 6441 1572 2975 2416 2742 2861 2033 2353 4859 3508 3611 3055 3354 4279 997 915 2290 1011 2577 3161 3312 1878 1901 692 105 1653 1732 1415 847 609 663 101 -836 -1769 -2465 -2892 -1328 -1665 -1728 -1871 -1766 -1197 -554 -458 424 333 807 244 -501 -474 -696 -708 -347 159 340 -275 -260 -546 -1252 -825 -88 -1252 -913 -713 -283 377 666 564 466 250 -20 -158 66 331 373 147 68 152 759 867 508 308 20 270 782 294 -147 -325 -186 -291 78 -23 -142 283 459 7 -138 -255 -482 -511 -1442 -1617 -1809 -1092 -2208 -1301 -2908 -2188 -2142 -2162 -2025 -1676 -1488 -1719 -1301 -634 -1259 -1255 -734 -1048 -1029 -1104 -1122 -289 -898 -995 -331 -969 -947 -820 -577 -490 -95 -551 -450 -544 -391 -274 421 245 107 820 542 1019 265 505 421 492 537 413 532 1202 969 1087 986 1037 1356 326 292 710 328 907 1257 1476 893 884 321 51 804 971 817 515 368 408 57 -429 -857 -1218 -1607 -799 -1176 -1301 -1548 -1455 -1051 -516 -449 399 313 772 219 -424 -412 -587 -668 -355 176 408 -360 -340 -670 -1475 -893 -95 -1484 -1081 -891 -378 520 975 871 759 407 -32 -247 98 498 588 236 114 252 1202 1325 787 459 29 396 1139 462 -249 -578 -350 -556 151 -47 -299 608 999 15 -289 -523 -974 -1008 SS 20240507T114141.7Z 8893.487288 64 1 54.36 2 77.53 76.92 70.41 81.25 0.00 1 0.00 1 0 17 2.470e-01 8.583e-03 1.587e-02 8.959e-04 5.870920e-01 4.633109e-04 6.134362e-03 -6.000000e+00 1.429311e-01 230.43 -2.00 3.16 -2.00 319.78 0.00e+00 1.484037e-03 1.476264e-04 1.393594e-03 -6.000000e+00 6.487950e-03 291.52 -2.00 20.00 -2.00 318.97 0.00e+00 4.499 0.001 302.00 328.00 3 1.1177e+00 1.3598e-03 5.2793e-02 -6.0000e+00 3.5627e-01 2.6493e-02 1.6456e-03 2.8491e-02 -6.0000e+00 3.8570e-01 -7.0115e-02 1.3372e-03 1.3922e-02 -6.0000e+00 2.3053e-01 2.3572e-02 6.9392e-04 3.8515e-03 -6.0000e+00 9.7718e-02 1.0624e-03 -4.6241e-05 2.4287e-05 4.7705e-05 -6.0000e+00 6.7561e-03 6.0886e-04 0.0000e+00 11 8 0 10 0 0 30.35 26.74 0.44 0.00061 0.00026 297 30 1 5 0 183.010 35.25 20.00 26.74 32.07 5.7 976.04 -79093 -76892 -69079 -80826 -93470 -77358 -95560 -83834 -77365 -77927 -65999 -63232 -44669 -42624 -27881 -22467 -21057 -19766 -10650 -17361 -14722 -19099 -13010 -5461 -12634 -10109 -7365 -15041 -10199 -12753 -4994 -4359 256 -1187 -6621 -5707 -3324 -1714 403 1201 1657 1738 2263 3225 1972 2229 2354 760 2483 752 2393 3235 2969 2020 2150 2013 2677 1019 897 1666 1333 2215 3325 2583 1531 1253 319 -17 876 883 1293 641 273 229 -348 -928 -1527 -2239 -2551 -1638 -1402 -1859 -2050 -1769 -1135 -473 -26 299 702 524 349 30 -578 -260 -143 -76 415 448 -171 -317 -616 -1010 -730 -137 -1135 -1090 -885 -611 184 584 598 431 289 -19 -258 256 329 419 369 150 93 679 644 481 533 104 253 757 352 -95 -186 -328 -301 -82 -43 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