File name: Pandora256s1_MiamiFL-FIU_20240529_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240530T052245.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240529_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240529T111046.3Z 8915.465814 221 1 54.58 2 82.48 69.45 45.20 192.08 0.00 1 0.00 1 0 17 6.508e-01 2.325e-02 2.787e-01 6.796e-03 8.125421e-01 3.752674e-03 8.103340e-03 -6.000000e+00 3.755418e-01 230.16 -2.00 3.16 -2.00 321.70 0.00e+00 -1.231955e-02 2.131184e-03 6.647493e-03 -6.000000e+00 1.796566e-02 292.87 -2.00 20.00 -2.00 321.08 0.00e+00 7.079 0.003 302.00 328.00 3 1.7041e+00 1.4720e-02 9.3707e-02 -6.0000e+00 9.3350e-01 6.3253e-01 2.0400e-02 8.1297e-02 -6.0000e+00 1.0110e+00 -9.2909e-01 1.7107e-02 2.2092e-02 -6.0000e+00 6.0565e-01 3.6986e-01 7.8091e-03 1.5497e-02 -6.0000e+00 2.5881e-01 4.1284e-05 -5.1199e-04 1.8334e-04 9.5867e-05 -6.0000e+00 1.8115e-02 1.2715e-02 6.9341e-06 12 8 8 10 0 0 22.78 27.02 1.01 0.01271 0.00887 38 4 1 5 0 1436.160 35.50 19.99 27.02 33.35 5.6 982.54 64343 -134738 900000 -3923 4313 -100831 -137322 -132185 -136412 -100607 -37783 -59784 -67283 -134842 13831 -24233 2306 -33572 187823 -2471 -49578 -102837 -51468 900000 -56575 -43781 900000 -80779 11690 -19086 379568 -3867 177728 108984 5294 134162 70359 900000 53120 57397 13707 98126 107815 329707 -1187 27778 51484 33195 61857 22104 13391 45290 54949 14122 11645 7646 50606 25283 13206 49899 6906 -1811 13663 6259 6309 4832 5627 5598 12074 4528 18936 8405 4615 3445 -2847 7875 1097 -14134 -7522 -1795 7777 -2286 4051 511 -2948 227 398 940 -3410 4132 1647 -2633 -1219 -4559 -3515 363 -3288 -1038 -2676 -2009 -501 -5572 -4599 -37 -5541 -3019 422 1319 2339 -526 -464 2089 -1299 130 -678 433 -113 -83 406 601 887 3253 2335 855 460 2357 -1214 399 971 -1175 -612 1078 -236 240 -178 -169 973 715 3 -240 -196 -1343 -1171 426 -3245 900000 -26 29 -1336 -2894 -3104 -3860 -2181 -455 -972 -1377 -6413 175 -511 44 -978 1244 -56 -1773 -6130 -1943 900000 -2885 -2088 900000 -5029 263 -594 2514 -138 1177 1516 196 1333 1444 900000 1935 2433 1017 3314 3356 2184 -104 1784 2591 2044 2990 1713 1268 3509 4258 1805 1643 1190 5329 3399 1898 4693 992 -306 2235 1244 1325 1015 1174 1231 2791 1308 5229 2688 1507 1063 -843 1862 260 -4006 -2262 -610 2838 -1067 1969 275 -1601 127 233 561 -2112 2504 955 -1510 -679 -2784 -2209 258 -2825 -1006 -2885 -2160 -498 -5237 -3907 -30 -5158 -2905 416 1396 2732 -662 -661 3123 -2049 198 -1000 611 -162 -126 647 987 1423 4879 3409 1229 642 3135 -1639 565 1577 -2237 -1191 2228 -526 573 -426 -426 2478 1851 8 -590 -448 -3132 -2643 SS 20240529T112823.9Z 8915.478055 226 1 54.44 2 78.75 71.14 46.13 197.66 0.00 1 0.00 1 0 17 2.999e-01 8.753e-03 3.023e-02 1.349e-03 6.053682e-01 7.016306e-04 6.347643e-03 -6.000000e+00 1.725836e-01 230.16 -2.00 3.16 -2.00 320.16 0.00e+00 9.386139e-04 2.553065e-04 1.833136e-03 -6.000000e+00 7.886113e-03 292.87 -2.00 20.00 -2.00 319.36 0.00e+00 4.945 0.001 302.00 328.00 3 1.3228e+00 2.1387e-03 5.7238e-02 -6.0000e+00 4.2970e-01 2.6606e-02 2.6634e-03 3.0471e-02 -6.0000e+00 4.6522e-01 -8.7341e-02 2.2771e-03 1.4426e-02 -6.0000e+00 2.7835e-01 2.9863e-02 1.1620e-03 3.7997e-03 -6.0000e+00 1.1838e-01 5.7094e-04 7.2476e-06 3.6442e-05 4.8404e-05 -6.0000e+00 8.1024e-03 1.2454e-02 2.5767e-05 11 8 0 10 0 0 35.14 27.00 0.55 0.01245 0.01251 183 19 1 5 0 297.480 35.25 20.00 27.00 34.22 5.5 987.44 -116838 -79689 -101617 -93641 -92176 -84950 -102205 -112079 -87987 -87608 -86087 -78259 -58984 -57346 -41026 -29691 -19050 -25084 -20858 -21607 -20270 -34517 -21240 -8586 -20742 -12747 -8102 -16308 -19302 -17666 -5362 -10626 -2113 -3751 -6091 -7679 -6310 -3900 2741 -787 -336 3332 4318 4168 156 1005 2497 2218 1419 392 2167 3140 3780 2801 2150 1984 4083 2457 464 2235 966 2625 3649 3459 1912 2413 239 -7 879 1287 1892 1388 226 561 -253 -725 -2080 -2439 -3131 -1352 -1764 -1723 -1922 -1735 -1146 -243 187 591 391 984 647 105 -833 -878 -530 -461 194 420 -188 -451 -532 -1374 -940 -145 -974 -1197 -736 -259 320 571 638 518 343 93 -179 -133 38 303 345 210 376 532 572 317 203 238 110 512 386 9 -170 -288 -346 -88 -6 0 377 442 22 -106 -363 -413 -483 -1630 -902 -1551 -1294 -1152 -972 -1520 -2124 -1505 -1637 -1665 -1565 -1211 -1471 -1117 -863 -561 -868 -752 -833 -797 -1576 -894 -351 -1048 -634 -393 -833 -990 -951 -300 -744 -157 -305 -490 -622 -559 -403 328 -118 -51 530 716 710 28 183 456 418 281 84 506 814 1068 871 717 635 1324 810 152 774 321 945 1475 1569 922 1126 112 -3 430 724 1171 838 137 346 -144 -373 -1096 -1201 -1732 -868 -1233 -1373 -1567 -1500 -1057 -223 180 583 386 930 572 93 -714 -774 -488 -489 221 516 -238 -570 -666 -1568 -1045 -163 -1125 -1466 -948 -337 453 853 997 851 563 146 -266 -200 58 458 554 337 625 854 887 476 308 347 156 755 610 16 -300 -541 -653 -177 -13 1 799 952 47 -219 -740 -833 -951 SS 20240529T113347.2Z 8915.481796 229 1 54.37 2 77.60 71.65 46.49 199.32 0.00 1 0.00 1 0 17 2.133e-01 8.273e-03 1.753e-02 9.979e-04 5.588398e-01 5.141651e-04 5.864393e-03 -6.000000e+00 1.227589e-01 230.16 -2.00 3.16 -2.00 319.75 0.00e+00 1.699293e-03 1.623496e-04 1.315714e-03 -6.000000e+00 5.609263e-03 292.87 -2.00 20.00 -2.00 318.91 0.00e+00 4.521 0.001 302.00 328.00 3 1.2203e+00 1.5095e-03 5.2176e-02 -6.0000e+00 3.0564e-01 6.0462e-03 1.8230e-03 2.7069e-02 -6.0000e+00 3.3091e-01 -5.5184e-02 1.4591e-03 1.3254e-02 -6.0000e+00 1.9799e-01 1.6628e-02 7.6033e-04 3.7068e-03 -6.0000e+00 8.4208e-02 9.8664e-04 -3.7218e-05 2.7347e-05 4.5805e-05 -6.0000e+00 5.7631e-03 1.2266e-02 2.4694e-05 11 9 0 11 8 0 8.13 27.00 0.49 0.01227 0.01199 251 26 1 5 0 216.610 35.25 19.99 27.00 34.38 5.5 988.32 -61485 -60449 -73555 -67255 -63104 -71307 -83408 -84458 -64222 -65373 -61572 -59170 -35189 -34610 -23208 -18961 -15560 -12411 -11529 -14900 -10853 -16512 -15906 -4285 -10929 -8013 -6207 -11796 -10915 -12101 -4776 -3338 1005 -827 -4898 -6345 -4094 -1706 203 1925 -19 2836 1664 3507 774 1570 1086 1511 1559 674 1846 2635 3020 2593 2365 1740 2722 1212 564 1645 1043 2345 2687 2777 1288 786 178 -528 586 1230 1118 680 674 331 -490 -1230 -1830 -2262 -2566 -1719 -1519 -1701 -2089 -1854 -1192 -446 77 691 524 819 802 -31 -765 -728 -85 -96 437 731 -49 -286 -537 -1298 -718 -452 -1102 -1114 -873 -287 370 751 646 500 279 43 -228 82 122 228 278 163 110 559 684 492 440 152 32 578 210 -9 -54 -341 -402 -90 -35 -42 301 367 75 -44 -259 -427 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