File name: Pandora256s1_MiamiFL-FIU_20240605_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T104206.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240605_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240605T110741.4Z 8922.463673 73 1 54.53 2 82.99 68.22 70.23 72.38 0.00 1 0.00 1 0 25 5.537e-01 2.057e-02 2.548e-01 5.519e-03 8.686890e-01 3.015977e-03 9.018213e-03 -6.000000e+00 3.197124e-01 229.89 -2.00 3.16 -2.00 321.80 0.00e+00 -1.934463e-03 1.837037e-03 7.549254e-03 -6.000000e+00 1.465449e-02 293.33 -2.00 20.00 -2.00 321.21 0.00e+00 7.507 0.004 302.00 328.00 3 9.6969e-01 1.2329e-02 9.5912e-02 -6.0000e+00 7.9535e-01 7.4851e-01 1.7201e-02 7.3531e-02 -6.0000e+00 8.6113e-01 -9.6441e-01 1.4827e-02 2.6281e-02 -6.0000e+00 5.1552e-01 3.6940e-01 6.7571e-03 8.1367e-03 -6.0000e+00 2.1918e-01 5.0435e-05 -2.1649e-04 1.4133e-04 8.8934e-05 -6.0000e+00 1.5141e-02 1.0123e-03 0.0000e+00 12 8 8 10 0 0 56.10 26.97 0.73 0.00101 -0.00061 59 6 1 5 0 924.130 35.25 20.00 26.97 33.34 5.6 982.16 -105405 146229 -166543 16504 -115933 30923 -195966 -144799 -173408 -131637 -157556 -65812 3761 -135517 -117397 -59598 101394 -79393 -8025 46695 -57608 -107138 -50275 59330 -49781 -24093 100014 -84458 -40214 -46028 4622 56945 154996 32292 62267 47680 15805 21869 68116 35215 7895 97255 67905 182008 5247 9420 28661 56700 55251 7277 11356 45169 4391 21875 27838 13703 51764 33809 16839 34780 3249 8682 6204 14456 7178 18472 7813 11786 17709 10685 15938 7972 6831 1709 2186 894 180 -6420 -17588 1643 3724 -2356 803 -350 -2441 695 -811 -726 -2555 4133 866 -2366 -747 -1846 -2715 -1269 -49 -1096 -2334 -1969 4 -4098 -3260 -843 -4581 -3102 -810 -661 622 -200 -86 887 170 478 -592 -190 -820 357 209 274 926 2046 2318 1221 39 2274 -87 561 1322 -551 -236 847 -78 -506 725 -92 358 108 -35 -128 -290 -1141 -786 -1135 787 -3830 89 -1305 166 -4890 -2409 -4242 -2254 -3623 -676 24 -4376 -3906 -1443 546 -2820 -147 503 -1736 -5132 -1407 607 -1634 -635 754 -3773 -1104 -1437 104 919 1084 817 1106 949 468 718 1723 1478 489 2617 2522 2155 359 618 1573 2441 2557 591 996 3185 513 2343 2996 1777 4708 3621 2030 3351 434 1201 1008 2466 1406 3221 1530 2347 3727 2783 4332 2433 2059 503 574 212 41 -1614 -5698 531 1403 -1093 364 -171 -1302 381 -472 -432 -1536 2229 451 -1207 -409 -994 -1704 -931 -42 -1099 -2382 -2014 4 -3909 -2798 -706 -4268 -3017 -819 -727 695 -260 -127 1400 255 705 -919 -287 -1263 571 327 439 1441 3246 3526 1821 57 3157 -121 839 2103 -1031 -494 1766 -176 -1232 1751 -236 929 284 -91 -317 -717 -2647 -1763 SS 20240605T111758.8Z 8922.470819 76 1 54.53 2 80.83 69.22 68.08 73.16 0.00 1 0.00 1 0 17 5.418e-01 1.184e-02 6.172e-02 1.943e-03 7.292218e-01 1.034440e-03 7.811507e-03 -6.000000e+00 3.128175e-01 229.89 -2.00 3.16 -2.00 320.88 0.00e+00 6.469813e-04 4.820684e-04 4.141426e-03 -6.000000e+00 1.433920e-02 293.33 -2.00 20.00 -2.00 320.16 0.00e+00 5.952 0.002 302.00 328.00 3 9.8516e-01 3.4916e-03 7.1233e-02 -6.0000e+00 7.7819e-01 1.6063e-01 4.6719e-03 4.4076e-02 -6.0000e+00 8.4257e-01 -2.3583e-01 4.2994e-03 1.8559e-02 -6.0000e+00 5.0441e-01 8.9671e-02 2.0872e-03 5.1290e-03 -6.0000e+00 2.1445e-01 2.6709e-04 -4.1866e-05 5.0572e-05 7.1958e-05 -6.0000e+00 1.4816e-02 1.2873e-03 0.0000e+00 12 8 8 10 0 0 91.98 26.97 0.54 0.00129 0.00097 148 15 1 5 0 368.400 35.25 20.00 26.97 34.01 5.6 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480 -201 1082 1239 1356 -584 585 736 447 1058 681 639 1314 339 1258 1317 1033 1953 693 375 1267 22 842 1132 1279 959 1004 945 728 1237 1577 1552 910 720 848 7 -203 -718 -1196 -2116 -443 -689 -1044 -931 -1090 -1166 -247 41 287 -193 741 1 -308 -849 -1046 -869 -275 -106 381 -660 -1187 -1323 -1583 -1341 -268 -1539 -1514 -947 -347 632 777 875 697 596 -154 -182 366 176 639 658 189 706 1429 1761 785 571 406 101 1086 424 -252 -472 -551 -462 -502 149 -447 813 1150 66 -55 -392 -1203 -1346 SS 20240605T112748.9Z 8922.477649 81 1 54.43 2 78.75 70.15 66.01 73.89 0.00 1 0.00 1 0 17 3.140e-01 9.236e-03 1.682e-02 8.645e-04 6.226922e-01 4.483137e-04 6.533648e-03 -6.000000e+00 1.813042e-01 229.89 -2.00 3.16 -2.00 319.97 0.00e+00 1.584097e-03 1.522169e-04 1.760915e-03 -6.000000e+00 8.309770e-03 293.33 -2.00 20.00 -2.00 319.14 0.00e+00 4.948 0.001 302.00 328.00 3 5.7159e-01 1.3393e-03 5.7510e-02 -6.0000e+00 4.5103e-01 6.2728e-02 1.6471e-03 3.0719e-02 -6.0000e+00 4.8833e-01 -9.3423e-02 1.3771e-03 1.4881e-02 -6.0000e+00 2.9234e-01 3.1734e-02 7.0980e-04 4.0121e-03 -6.0000e+00 1.2430e-01 1.1515e-03 -3.5332e-05 2.3096e-05 5.1167e-05 -6.0000e+00 8.5859e-03 5.8445e-04 0.0000e+00 11 8 0 10 0 0 94.88 26.96 0.46 0.00058 0.00032 346 35 1 5 0 157.290 35.25 19.99 26.96 34.82 5.6 992.06 -107711 -98229 -109719 -96284 -109221 -109257 -115486 -107703 -103601 -81172 -74438 -76589 -58450 -56091 -34517 -29903 -28527 -24336 -13441 -19546 -19384 -23563 -17603 -14768 -20089 -13522 -11008 -16396 -17248 -13835 -9762 -6010 -2186 -2932 -3389 -6017 -4193 -3413 1162 1986 711 3963 2951 4606 1325 1759 1845 1581 1456 1667 2963 2753 1813 3128 2846 2671 2723 1104 660 1896 1420 1934 3526 3159 1798 1573 641 324 1256 1488 1509 879 740 232 -432 -1067 -1793 -2144 -2209 -1611 -1405 -1670 -2291 -1809 -1226 -641 -4 273 436 685 479 -67 -522 -339 -375 -367 64 548 -34 -587 -803 -1142 -610 -250 -1189 -1023 -852 -570 179 596 654 307 321 -77 -83 258 279 476 336 192 157 599 765 529 549 84 319 792 343 -45 -204 -361 -258 -87 -102 -97 309 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