File name: Pandora256s1_MiamiFL-FIU_20240608_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T104142.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240608_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240608T114553.1Z 8925.490198 76 1 54.02 2 74.92 71.48 95.74 55.88 0.00 1 0.00 1 0 17 1.047e-01 6.649e-03 3.285e-02 1.964e-03 4.997070e-01 1.003961e-03 5.213821e-03 -6.000000e+00 6.044221e-02 229.77 -2.00 3.16 -2.00 319.47 0.00e+00 1.005351e-03 2.900701e-04 7.624369e-04 -6.000000e+00 2.773778e-03 293.53 -2.00 20.00 -2.00 318.59 0.00e+00 3.769 0.000 302.00 328.00 3 3.3161e+00 2.8975e-03 4.4216e-02 -6.0000e+00 1.5031e-01 2.5306e-02 3.4542e-03 2.3716e-02 -6.0000e+00 1.6275e-01 -1.6460e-02 2.6521e-03 1.1559e-02 -6.0000e+00 9.7451e-02 -3.4398e-03 1.3922e-03 3.2109e-03 -6.0000e+00 4.1454e-02 2.5487e-04 2.4875e-06 5.5098e-05 3.5847e-05 -6.0000e+00 2.8635e-03 5.7415e-04 0.0000e+00 11 9 0 11 8 0 99.72 26.93 0.56 0.00057 0.00059 59 6 1 5 0 915.490 35.25 20.00 26.93 30.64 5.7 965.35 -23889 -14318 -35688 3105 -28681 -32206 -52562 -51653 -25800 -19253 -34543 -35028 -4956 -25662 -15491 -16386 -745 -9256 -42 -5337 -8362 -10019 -12728 5382 -9826 -544 -221 -9967 -3837 -4354 1490 -6800 1971 1255 -4919 -3121 -139 -1044 2707 -41 -1616 853 1824 3529 -1601 -554 87 -537 2974 351 -207 3280 1836 1570 600 470 2206 1891 -526 2170 108 1206 1905 2001 474 864 -63 -806 718 639 1514 918 395 311 -384 -666 -1150 -2471 -2890 -914 -677 -1310 -1673 -1406 -1250 -541 -316 181 402 766 650 7 229 -69 -406 -67 322 554 273 -149 -158 -945 -939 189 -1275 -836 -135 -220 414 532 703 462 -59 -201 -12 92 270 398 131 -83 -111 301 568 155 308 166 -231 668 263 -160 -132 -457 -145 -310 149 -163 385 376 -13 16 -177 -293 -361 -348 -219 -725 42 -483 -549 -1188 -1326 -583 -443 -959 -1067 -135 -1062 -706 -882 -38 -558 -2 -352 -586 -718 -978 375 -864 -46 -19 -911 -318 -378 139 -796 240 164 -656 -404 -19 -173 481 -9 -402 221 490 954 -460 -160 25 -158 866 110 -71 1207 683 631 257 209 993 853 -237 943 49 597 1048 1118 278 483 -35 -448 429 438 1051 670 288 216 -266 -416 -667 -1439 -1846 -665 -526 -1155 -1501 -1331 -1266 -546 -335 196 435 794 669 7 207 -63 -409 -72 368 713 357 -194 -204 -1118 -1099 224 -1551 -1071 -180 -296 597 797 1083 739 -93 -319 -18 138 403 589 207 -130 -175 485 883 234 466 242 -325 963 398 -255 -227 -786 -257 -583 284 -327 754 750 -26 33 -339 -561 -677 SS 20240608T115558.5Z 8925.497205 79 1 54.39 2 72.76 72.37 93.93 57.02 0.00 1 0.00 1 0 17 4.762e-02 6.601e-03 2.442e-03 4.030e-04 4.448331e-01 2.055431e-04 4.689738e-03 -6.000000e+00 2.748739e-02 229.77 -2.00 3.16 -2.00 318.28 0.00e+00 9.565744e-04 4.031872e-05 3.602919e-04 -6.000000e+00 1.261415e-03 293.53 -2.00 20.00 -2.00 317.34 0.00e+00 3.324 0.000 302.00 328.00 3 8.6609e-01 5.5853e-04 3.9016e-02 -6.0000e+00 6.8356e-02 1.0254e-02 6.3838e-04 2.0785e-02 -6.0000e+00 7.4012e-02 -2.2787e-02 4.1250e-04 1.0065e-02 -6.0000e+00 4.4318e-02 5.4364e-03 2.1431e-04 2.8128e-03 -6.0000e+00 1.8852e-02 4.8450e-03 -6.1569e-05 1.1260e-05 3.0515e-05 -6.0000e+00 1.3022e-03 4.6811e-04 0.0000e+00 11 8 0 10 0 0 99.93 26.92 0.39 0.00047 0.00001 565 58 1 5 0 96.260 35.25 20.00 26.92 31.87 5.8 976.33 -14948 -12570 -14775 -11887 -19108 -19930 -19325 -15914 -13553 -13072 -14784 -11623 -9749 -6744 -2840 -1592 -1387 -650 256 465 -16 -634 0 93 -713 -239 -425 -2021 -2013 -1156 61 1142 1361 -604 -2359 -2826 -2439 -781 340 322 182 520 674 500 861 795 434 516 -112 650 940 1093 1391 1326 1111 1227 993 535 170 489 1003 1468 2149 1897 706 190 -205 -369 626 580 469 456 201 157 -278 -593 -1094 -1362 -1173 -1233 -1390 -1710 -2189 -1770 -1093 -726 -159 189 390 448 418 198 -67 177 106 -24 443 603 -52 -351 -552 -861 -405 -109 -1022 -1014 -723 -479 127 505 490 297 271 81 -33 332 378 387 294 56 -52 387 532 550 594 196 471 915 413 92 -112 -245 -199 26 -15 -157 219 343 -155 -154 -427 -495 -548 -669 -629 -801 -604 -948 -966 -999 -905 -853 -883 -1041 -851 -829 -615 -299 -191 -182 -91 38 72 -3 -102 0 15 -127 -45 -81 -374 -356 -208 12 256 316 -151 -574 -680 -641 -238 116 122 72 219 295 224 387 362 199 237 -53 314 461 588 761 779 650 742 617 334 104 296 623 938 1443 1396 514 138 -143 -260 473 457 391 398 175 131 -224 -450 -802 -982 -871 -1012 -1256 -1605 -2151 -1831 -1159 -792 -182 214 442 506 453 206 -68 180 113 -27 523 774 -70 -468 -713 -1048 -474 -130 -1290 -1311 -950 -646 177 745 759 463 414 119 -49 473 525 563 444 87 -81 588 804 798 846 277 655 1264 609 142 -179 -402 -328 43 -27 -283 403 628 -286 -281 -761 -864 -935 SS 20240608T120225.0Z 8925.501678 83 1 54.43 2 71.38 72.93 92.76 57.73 0.00 1 0.00 1 0 17 3.417e-02 6.442e-03 1.947e-03 3.905e-04 4.141767e-01 1.992557e-04 4.379751e-03 -6.000000e+00 1.972338e-02 229.77 -2.00 3.16 -2.00 318.03 0.00e+00 7.807208e-04 3.612723e-05 2.848812e-04 -6.000000e+00 9.051105e-04 293.53 -2.00 20.00 -2.00 317.08 0.00e+00 3.092 0.000 302.00 328.00 3 1.0573e+00 5.3714e-04 3.6295e-02 -6.0000e+00 4.9048e-02 6.4312e-03 6.1137e-04 1.9337e-02 -6.0000e+00 5.3107e-02 -1.6464e-02 3.8410e-04 9.3680e-03 -6.0000e+00 3.1800e-02 2.5500e-03 1.9669e-04 2.6065e-03 -6.0000e+00 1.3528e-02 5.1930e-03 -3.3835e-05 1.0983e-05 2.8215e-05 -6.0000e+00 9.3437e-04 4.0202e-04 0.0000e+00 11 8 0 10 0 0 95.29 26.91 0.41 0.00040 0.00015 641 66 1 5 0 84.910 35.25 19.99 26.91 33.21 5.8 984.99 -10970 -6539 -10097 -10513 -14349 -12985 -13262 -11006 -9857 -9720 -10631 -9524 -6004 -4066 -2184 -571 25 567 1090 941 497 -95 657 671 244 18 -464 -1565 -1787 -493 416 1197 1501 -795 -2552 -2628 -2290 -860 65 268 66 421 336 375 591 610 361 224 -318 464 943 1055 1336 1299 1007 1141 908 507 303 662 1008 1617 2057 1900 646 132 -395 -423 516 474 411 254 158 187 -227 -684 -1105 -1327 -1122 -1302 -1390 -1658 -2159 -1715 -1103 -690 -100 204 368 498 477 114 -32 209 169 92 466 651 44 -307 -531 -831 -423 -20 -1044 -962 -757 -450 105 512 527 339 264 70 -5 320 352 375 282 38 16 394 434 449 532 206 486 862 364 132 -118 -320 -178 17 -14 -153 235 295 -137 -152 -351 -470 -536 -625 -406 -684 -689 -884 -762 -835 -770 -772 -817 -919 -867 -562 -450 -283 -83 4 95 177 160 87 -17 119 131 51 4 -105 -341 -372 -103 95 284 397 -226 -705 -715 -679 -275 23 114 30 199 155 176 279 290 172 107 -153 230 501 579 787 776 632 738 573 321 198 427 669 1099 1468 1410 495 101 -288 -309 386 386 353 228 142 160 -189 -537 -837 -982 -851 -1087 -1273 -1573 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