File name: Pandora256s1_MiamiFL-FIU_20240617_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T104536.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240617_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240617T110010.4Z 8934.458453 118 1 53.34 2 84.73 66.53 142.49 280.76 0.00 1 0.00 1 0 33 8.625e-01 5.301e-02 3.179e-01 1.898e-02 9.769451e-01 1.131574e-02 9.719128e-03 -6.000000e+00 5.223292e-01 229.42 -2.00 3.16 -2.00 322.20 0.00e+00 -1.470109e-02 6.372874e-03 2.328877e-03 -6.000000e+00 2.744355e-02 293.99 -2.00 20.00 -2.00 321.61 0.00e+00 9.414 0.007 302.00 328.00 3 5.4133e-01 4.7183e-02 1.0632e-01 -6.0000e+00 1.3063e+00 1.8966e+00 5.9005e-02 5.8662e-02 -6.0000e+00 1.4352e+00 -2.1454e+00 3.4134e-02 2.2825e-02 -6.0000e+00 8.4309e-01 7.6988e-01 1.6744e-02 1.1431e-02 -6.0000e+00 3.5238e-01 9.1428e-06 8.8451e-05 5.1717e-04 1.3820e-04 -6.0000e+00 2.5777e-02 3.7809e-03 0.0000e+00 12 8 8 10 0 0 99.90 26.97 1.45 0.00378 0.00445 21 2 1 5 0 2539.820 35.25 20.00 26.97 33.39 5.6 981.36 126484 79103 94893 270474 -1073 900000 22170 -20146 40215 26720 900000 59806 900000 -68282 36465 331992 900000 10801 104198 900000 -11484 11056 1597 900000 900000 16190 900000 7977 68786 10772 183027 27793 900000 900000 900000 900000 300276 900000 900000 83822 24453 426662 900000 900000 -10861 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9339 2387 4375 2549 69 764 1244 769 -1987 6576 2316 992 2521 -2834 1801 4243 2680 -2539 4642 -2507 6393 -6561 -9694 8561 -6735 -6143 6626 3359 5663 2479 4337 4556 -7041 -4602 -2638 1222 -1290 6491 -2763 -3801 -4963 9519 4994 -5637 -2977 12983 -7355 -1186 4690 -5582 1795 -721 204 -10964 6943 -3711 6309 6241 277 -695 833 1469 -7030 SS 20240617T111924.7Z 8934.471813 124 1 54.57 2 80.73 68.41 146.57 283.93 0.00 1 0.00 1 0 17 4.043e-01 9.136e-03 1.813e-01 2.630e-03 6.870195e-01 1.399609e-03 7.163134e-03 -6.000000e+00 2.330263e-01 229.42 -2.00 3.16 -2.00 320.94 0.00e+00 1.668911e-03 6.675865e-04 2.371917e-03 -6.000000e+00 1.073112e-02 293.99 -2.00 20.00 -2.00 320.21 0.00e+00 5.892 0.002 302.00 328.00 3 1.5336e+00 4.8165e-03 6.7437e-02 -6.0000e+00 5.7889e-01 1.2034e-01 6.5580e-03 3.5450e-02 -6.0000e+00 6.2693e-01 -1.2703e-01 6.1711e-03 1.7479e-02 -6.0000e+00 3.7563e-01 3.8106e-02 2.9793e-03 4.7533e-03 -6.0000e+00 1.5996e-01 1.6902e-04 -1.3161e-04 7.0769e-05 7.1694e-05 -6.0000e+00 1.1055e-02 1.4917e-03 0.0000e+00 11 8 0 10 0 0 99.97 26.97 0.56 0.00149 0.00050 157 16 1 5 0 347.530 35.25 20.00 26.97 34.16 5.6 985.99 -109287 2763 -162601 -14626 -149096 35538 -155506 -169189 -146757 -102965 -102556 -110187 -25643 -106196 -105682 -42532 -23236 -58672 -18782 -46869 -57533 -78318 -52012 27514 -42031 -32627 245 -41418 -25735 -27752 -9265 -13433 18845 -1720 12034 -362 11260 -4077 7804 757 -5883 16438 6254 19236 -4682 -7748 2386 5076 8729 3270 43 6448 7867 2989 3497 2186 6665 3319 -524 6141 -592 927 2436 3353 2323 2692 -1684 177 998 2067 2855 108 448 286 -1087 -388 -1695 -3957 -6294 -827 -1073 -1758 -1755 -1778 -997 -449 560 326 649 1776 861 161 -278 -446 177 93 487 802 -636 -114 98 -1267 -1091 120 -1790 -2052 -545 95 536 597 598 464 26 -129 -346 228 67 485 443 -114 -294 652 798 -74 202 321 -246 466 173 -16 -316 -11 -257 -504 115 -360 458 375 28 -90 28 -205 -280 -459 7 -1668 -38 -1224 91 -1476 -2126 -1694 -845 -894 -1187 -151 -1825 -2304 -600 -310 -1249 -294 -1034 -1461 -2471 -1334 353 -1186 -895 5 -1243 -654 -783 -261 -479 570 -69 411 -14 427 -216 456 57 -543 1315 585 1628 -512 -896 256 553 969 415 6 1006 1338 585 728 484 1462 752 -120 1296 -138 236 699 980 726 826 -537 58 359 851 1290 53 215 129 -455 -145 -603 -1473 -2709 -402 -615 -1067 -1171 -1265 -754 -361 468 281 556 1447 661 117 -197 -329 147 83 502 943 -767 -137 119 -1393 -1100 121 -1975 -2403 -666 115 713 834 927 762 43 -207 -528 334 99 751 728 -195 -498 1052 1239 -112 293 481 -361 670 282 -27 -605 -21 -521 -1091 250 -828 1070 891 66 -205 60 -438 -584 SS 20240617T112840.5Z 8934.478247 129 1 38.26 2 78.78 69.28 148.52 285.65 0.00 1 0.00 1 0 17 2.580e-01 8.914e-03 4.085e-02 1.846e-03 5.877116e-01 9.550796e-04 6.181414e-03 -6.000000e+00 1.487046e-01 229.42 -2.00 3.16 -2.00 320.01 0.00e+00 1.250557e-03 3.315757e-04 1.694482e-03 -6.000000e+00 6.847696e-03 293.99 -2.00 20.00 -2.00 319.17 0.00e+00 4.959 0.001 302.00 328.00 3 1.6868e+00 2.8772e-03 5.6713e-02 -6.0000e+00 3.6942e-01 6.0691e-02 3.5497e-03 2.9216e-02 -6.0000e+00 4.0007e-01 -7.0994e-02 2.9478e-03 1.3922e-02 -6.0000e+00 2.3970e-01 2.0458e-02 1.5180e-03 3.6848e-03 -6.0000e+00 1.0208e-01 3.8893e-04 -1.6018e-04 5.0388e-05 4.8162e-05 -6.0000e+00 7.0544e-03 1.2209e-03 0.0000e+00 12 9 1 12 1 1 88.55 26.97 0.55 0.00122 0.00002 70 10 1 5 0 538.800 35.25 20.00 26.97 34.49 5.5 987.75 -64131 -84946 -113903 -52350 -52234 -71630 -84303 -99927 -98847 -78310 -74210 -65005 -34722 -61973 -51660 -24099 -18666 -25093 -16475 -11502 -18585 -27645 -20196 5467 -15274 -15006 -955 -15643 -14929 -17304 -1228 -11706 4616 599 -1974 -5932 -1395 -372 2660 3088 -1137 3198 4045 4470 1902 823 1165 1863 3371 1537 2057 3624 3275 2600 2564 1668 3989 744 -322 2347 378 2242 2315 2742 851 1338 -563 -125 1095 1559 1373 1337 732 -125 -790 -912 -1823 -1638 -2808 -2104 -1137 -1790 -2080 -1267 -1290 -724 346 514 673 638 808 -61 -460 -274 -335 85 389 587 38 -539 -616 -1321 -938 -119 -1300 -1360 -745 -359 116 681 893 363 294 -105 -100 128 491 430 298 64 -104 777 728 502 235 241 178 667 250 -236 -194 -301 -327 -238 -14 -305 243 524 143 -117 -221 -294 -510 -646 -1239 -2399 -584 -536 -877 -1275 -2033 -2278 -1607 -1536 -1369 -669 -1986 -1860 -785 -649 -1025 -670 -472 -846 -1388 -989 227 -852 -889 -50 -924 -855 -1078 -76 -952 368 53 -175 -541 -134 -42 362 457 -198 576 759 857 379 169 243 396 734 363 536 1038 1032 822 861 591 1424 274 -117 820 140 891 1040 1264 417 635 -267 -61 577 942 852 869 475 -77 -487 -507 -952 -858 -1653 -1345 -838 -1409 -1796 -1080 -1179 -703 350 503 658 637 751 -53 -412 -251 -321 87 434 704 50 -704 -754 -1556 -1080 -138 -1553 -1720 -937 -481 161 989 1419 580 468 -169 -151 193 713 654 483 104 -167 1260 1141 760 360 355 254 988 397 -400 -343 -540 -613 -454 -28 -630 510 1118 306 -240 -448 -564 -999 SS 20240617T113323.9Z 8934.481526 132 1 54.35 2 77.79 69.72 149.51 286.59 0.00 1 0.00 1 0 17 1.823e-01 8.010e-03 1.060e-02 7.258e-04 5.486141e-01 3.731570e-04 5.756585e-03 -6.000000e+00 1.050685e-01 229.42 -2.00 3.16 -2.00 319.49 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