File name: Pandora256s1_MiamiFL-FIU_20240622_L2Fit_fout2c7d20231207p1-8.txt File generation date: 20260123T104552.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v7d20231207.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240622_L1_smca1c7d20231207p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0508 305.1918 305.3328 305.4738 305.6147 305.7557 305.8966 306.0376 306.1785 306.3194 306.4603 306.6012 306.7421 306.8829 307.0238 307.1646 307.3055 307.4463 307.5871 307.7279 307.8687 308.0095 308.1502 308.2910 308.4317 308.5724 308.7132 308.8539 308.9946 309.1353 309.2759 309.4166 309.5572 309.6979 309.8385 309.9791 310.1197 310.2603 310.4009 310.5415 310.6820 310.8226 310.9631 311.1037 311.2442 311.3847 311.5252 311.6657 311.8061 311.9466 312.0870 312.2275 312.3679 312.5083 312.6487 312.7891 312.9295 313.0698 313.2102 313.3505 313.4909 313.6312 313.7715 313.9118 314.0521 314.1924 314.3326 314.4729 314.6131 314.7534 314.8936 315.0338 315.1740 315.3142 315.4544 315.5945 315.7347 315.8748 316.0149 316.1550 316.2952 316.4352 316.5753 316.7154 316.8555 316.9955 317.1355 317.2756 317.4156 317.5556 317.6956 317.8355 317.9755 318.1155 318.2554 318.3953 318.5353 318.6752 318.8151 318.9550 319.0948 319.2347 319.3745 319.5144 319.6542 319.7940 319.9338 320.0736 320.2134 320.3532 320.4929 320.6327 320.7724 320.9121 321.0519 321.1916 321.3312 321.4709 321.6106 321.7502 321.8899 322.0295 322.1691 322.3087 322.4483 322.5879 322.7275 322.8670 323.0066 323.1461 323.2857 323.4252 323.5647 323.7042 323.8436 323.9831 324.1226 324.2620 324.4014 324.5409 324.6803 324.8197 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240622T111138.6Z 8939.466418 218 1 54.51 2 82.56 67.53 95.60 240.78 0.00 1 0.00 1 0 17 6.404e-01 1.849e-02 1.283e-01 3.512e-03 8.592583e-01 1.909137e-03 9.021440e-03 -6.000000e+00 3.688172e-01 229.21 -2.00 3.16 -2.00 321.56 0.00e+00 -2.442656e-03 1.098937e-03 6.554134e-03 -6.000000e+00 1.700715e-02 294.13 -2.00 20.00 -2.00 320.92 0.00e+00 7.141 0.003 302.00 328.00 3 6.8787e-01 7.4730e-03 8.9824e-02 -6.0000e+00 9.1573e-01 5.0193e-01 1.0588e-02 6.5991e-02 -6.0000e+00 9.9186e-01 -6.9712e-01 9.4878e-03 2.4083e-02 -6.0000e+00 5.9442e-01 2.7826e-01 4.3423e-03 7.9236e-03 -6.0000e+00 2.5328e-01 1.0047e-04 -3.6119e-04 8.8067e-05 8.9308e-05 -6.0000e+00 1.7510e-02 1.6407e-03 0.0000e+00 12 8 8 10 0 0 73.95 26.93 0.61 0.00164 -0.00107 90 9 1 5 0 605.650 35.25 20.00 26.93 33.17 5.6 980.42 -192290 -170107 -234149 -129297 -152220 -115091 -220825 -230050 -200569 -177581 -197698 -162788 -98070 -157187 -86178 -113698 -51584 -97940 -37274 -47221 -86136 -86368 -65677 75447 -67369 -70684 44976 -81525 -39167 -32658 14957 -6479 50392 21842 41863 34623 -20432 30281 58209 23944 12697 55495 35605 62780 8776 18773 29505 30848 23473 24215 10160 24015 27015 16806 16923 10310 34065 13938 11689 21521 3474 5382 10227 11674 6455 13357 7209 5322 8116 8323 11713 7523 2739 4296 2832 1752 -1221 -4040 -7971 230 2098 -2780 -138 -1312 -601 -760 -394 189 -1245 1564 -248 -152 -2345 -2721 -1526 -459 -712 -717 -2002 -1800 -983 -3395 -2017 195 -2726 -3053 -441 -264 -605 158 -391 271 -569 -280 74 348 101 356 629 810 895 2098 1588 883 681 1592 151 1067 653 -109 -208 127 -10 -260 7 -340 648 760 177 -446 -488 -946 -916 -2335 -1907 -5250 -966 -1280 -645 -3851 -5015 -3685 -3102 -4469 -2955 -1176 -4361 -1476 -3077 -848 -2818 -626 -906 -2449 -2426 -1575 491 -2008 -2300 462 -2820 -859 -727 251 -164 846 524 789 688 -770 819 1475 1033 696 2129 1732 2344 559 1093 1577 1701 1487 1667 912 2131 2582 1957 2116 1451 3909 1938 1589 2551 501 837 1745 2247 1404 2713 1578 1260 2102 2492 3743 2373 889 1407 847 473 -322 -1143 -2706 79 845 -1364 -73 -754 -367 -494 -267 130 -866 1016 -153 -89 -1394 -1737 -1111 -359 -658 -769 -2203 -1988 -1009 -3458 -1838 174 -2681 -3192 -477 -286 -740 220 -578 429 -930 -449 113 518 152 565 1050 1387 1492 3292 2407 1307 977 2194 207 1561 1111 -201 -402 266 -22 -590 16 -823 1587 1881 435 -1110 -1127 -2175 -2040 SS 20240622T114819.0Z 8939.491886 235 1 25.15 2 74.84 70.94 102.60 244.10 0.00 1 0.00 1 0 17 2.781e-01 1.956e-02 2.222e-01 9.150e-03 4.958856e-01 4.718510e-03 5.205675e-03 -6.000000e+00 1.600949e-01 229.21 -2.00 3.16 -2.00 319.88 0.00e+00 1.069022e-03 1.546760e-03 1.753612e-03 -6.000000e+00 7.751191e-03 294.13 -2.00 20.00 -2.00 319.00 0.00e+00 3.750 0.000 302.00 328.00 3 4.9515e+00 1.4064e-02 4.4388e-02 -6.0000e+00 3.9763e-01 1.3818e-01 1.7133e-02 2.5276e-02 -6.0000e+00 4.3095e-01 -7.0123e-02 1.3431e-02 1.1792e-02 -6.0000e+00 2.5808e-01 1.5131e-02 6.9564e-03 3.0957e-03 -6.0000e+00 1.1022e-01 4.8136e-05 -4.8291e-04 2.6286e-04 3.7840e-05 -6.0000e+00 7.6674e-03 6.7319e-03 0.0000e+00 12 9 9 12 1 1 100.00 26.95 0.91 0.00673 0.00310 6 2 1 5 0 3591.810 35.25 19.99 26.95 34.43 5.5 987.23 94155 20440 -19594 -50616 100741 189460 -4727 -73574 -34336 -37792 900000 -29955 98138 -82743 -53734 359 31608 -33868 -10251 59405 15706 -22361 -14676 37117 6042 -4198 52849 -32472 22342 -34595 -940 -11630 24261 6984 -6833 5602 16772 28092 12959 -4990 -2890 19139 19090 15601 -4391 361 2648 5455 8178 -2135 -7287 6755 16178 -761 -3399 -3628 5199 10380 -2027 6229 -2152 1039 364 733 -3115 573 -2283 -35 -177 245 5560 597 -2860 -1929 -633 -1053 -1836 -3371 -11348 -684 5028 -1630 -651 -813 -3376 391 -1343 -637 -220 2346 816 -154 276 -52 -1586 619 91 1158 860 752 1744 -1882 -3657 3060 -3623 -814 1538 2039 718 1478 35 815 -398 -870 -779 -1172 -486 1794 1328 676 -672 1775 1625 -1371 -424 1980 -1148 -1223 -420 -1891 -1614 100 258 -1360 524 -269 1288 1062 429 -977 -769 980 -362 840 219 -332 -1129 899 1690 -63 -2232 -796 -978 900000 -802 876 -5536 -3260 15 1043 -2327 -594 1802 757 -1576 -995 1623 388 -315 2263 -3129 1196 -3395 -75 -1183 1948 704 -756 540 1586 2807 1838 -1006 -637 3603 3747 3229 -1116 88 638 1290 1919 -581 -2275 2019 4763 -285 -1374 -1521 2046 3862 -832 2323 -900 459 164 361 -1640 278 -1096 -17 -92 144 3413 402 -1971 -1252 -372 -558 -994 -1834 -6636 -417 3332 -1298 -556 -734 -3346 365 -1341 -649 -222 2218 793 -139 236 -45 -1523 605 101 1442 1149 995 2135 -2167 -3994 3192 -4352 -1004 1949 2728 1048 2169 56 1346 -655 -1362 -1137 -1773 -734 2769 2023 1084 -1093 2736 2426 -2026 -642 2803 -1616 -1780 -669 -3106 -2843 182 484 -2541 1024 -555 2676 2250 911 -2029 -1511 1938 -710 SS 20240622T115653.2Z 8939.497838 238 1 28.13 2 73.02 71.69 104.27 244.82 0.00 1 0.00 1 0 17 7.900e-02 7.905e-03 2.762e-02 2.905e-03 4.488785e-01 1.480871e-03 4.720238e-03 -6.000000e+00 4.550993e-02 229.21 -2.00 3.16 -2.00 318.89 0.00e+00 5.344408e-04 3.532462e-04 6.389703e-04 -6.000000e+00 2.097860e-03 294.13 -2.00 20.00 -2.00 317.97 0.00e+00 3.371 0.000 302.00 328.00 3 3.8073e+00 4.1162e-03 3.9530e-02 -6.0000e+00 1.1300e-01 5.3315e-02 4.7949e-03 2.1204e-02 -6.0000e+00 1.2238e-01 -2.1195e-02 3.3534e-03 1.0237e-02 -6.0000e+00 7.3343e-02 2.6330e-04 1.7650e-03 2.7724e-03 -6.0000e+00 3.1261e-02 2.3797e-04 -6.0085e-05 8.2069e-05 2.9828e-05 -6.0000e+00 2.1598e-03 -3.7169e-04 0.0000e+00 12 9 1 12 1 1 -5.36 26.96 0.33 -0.00037 -0.00082 12 3 1 5 0 2163.710 35.25 20.00 26.96 34.64 5.6 988.95 -21827 1208 -29761 -30865 -16596 -36325 -38038 -18448 -31109 -10458 -15557 -18813 -191 -18168 -7688 -7347 -4145 -11101 891 1723 -3638 -6850 -4438 1143 -2710 -3131 3866 -10451 -4799 -7762 3454 -519 3555 439 2632 -7405 821 -2987 794 511 -2010 2601 2472 3408 131 762 818 506 2996 259 1110 1553 3404 830 1040 95 1091 1554 -814 2180 -319 1662 1748 2154 10 335 -498 -1284 906 264 1553 997 473 -152 -197 -508 -410 -2496 -3208 -1347 -213 -1753 -1482 -1915 -1232 -784 -84 275 105 946 692 108 -196 -55 -254 -38 365 514 300 -100 -483 -1504 -671 86 -1032 -857 -345 -210 -56 714 830 358 117 -310 223 169 242 642 435 -127 -42 667 635 570 130 -14 42 670 578 -587 -135 -358 -63 -377 -48 63 552 423 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