File name: Pandora256s1_MiamiFL-FIU_20240730_L2Fit_fout2c6d20240708p1-8.txt File generation date: 20260123T105651.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v6d20240708.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240730_L1_smca1c6d20240708p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0470 305.1880 305.3290 305.4700 305.6110 305.7520 305.8929 306.0339 306.1749 306.3158 306.4567 306.5976 306.7385 306.8794 307.0203 307.1612 307.3020 307.4429 307.5837 307.7245 307.8653 308.0061 308.1469 308.2877 308.4284 308.5692 308.7099 308.8507 308.9914 309.1321 309.2728 309.4135 309.5542 309.6948 309.8355 309.9761 310.1167 310.2574 310.3980 310.5386 310.6791 310.8197 310.9603 311.1008 311.2414 311.3819 311.5224 311.6629 311.8034 311.9439 312.0844 312.2248 312.3653 312.5057 312.6461 312.7865 312.9269 313.0673 313.2077 313.3481 313.4884 313.6288 313.7691 313.9094 314.0497 314.1900 314.3303 314.4706 314.6109 314.7511 314.8914 315.0316 315.1718 315.3120 315.4522 315.5924 315.7326 315.8727 316.0129 316.1530 316.2931 316.4332 316.5733 316.7134 316.8535 316.9936 317.1336 317.2737 317.4137 317.5537 317.6938 317.8338 317.9737 318.1137 318.2537 318.3936 318.5336 318.6735 318.8134 318.9533 319.0932 319.2331 319.3730 319.5128 319.6527 319.7925 319.9324 320.0722 320.2120 320.3518 320.4915 320.6313 320.7711 320.9108 321.0505 321.1903 321.3300 321.4697 321.6094 321.7490 321.8887 322.0283 322.1680 322.3076 322.4472 322.5868 322.7264 322.8660 323.0056 323.1451 323.2847 323.4242 323.5637 323.7032 323.8427 323.9822 324.1217 324.2612 324.4006 324.5400 324.6795 324.8189 324.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240730T124240.2Z 8977.529632 237 1 54.97 2 65.78 80.49 6.55 85.64 0.00 1 0.00 1 0 17 2.472e-02 7.177e-03 9.512e-03 2.475e-03 3.092907e-01 1.250808e-03 3.310021e-03 -6.000000e+00 1.418789e-02 228.15 -2.00 3.16 -2.00 317.65 0.00e+00 6.128030e-04 2.084189e-04 3.186847e-04 -6.000000e+00 6.584777e-04 294.83 -2.00 20.00 -2.00 316.70 0.00e+00 2.420 0.000 302.00 328.00 3 5.2354e+00 3.3342e-03 2.7944e-02 -6.0000e+00 3.5129e-02 4.6361e-02 3.7869e-03 1.4392e-02 -6.0000e+00 3.8071e-02 -9.3599e-04 2.3012e-03 6.9834e-03 -6.0000e+00 2.2848e-02 -8.4319e-03 1.1584e-03 1.9223e-03 -6.0000e+00 9.7657e-03 1.7236e-04 4.5583e-04 7.1362e-05 2.1422e-05 -6.0000e+00 6.7572e-04 8.7168e-04 0.0000e+00 11 8 0 10 0 0 74.24 25.25 0.50 0.00087 0.00430 14 1 1 5 0 3926.350 33.50 20.00 25.25 35.20 5.5 989.72 -8318 -4132 4039 1639 -6601 141 -7685 -15036 -7744 -6218 -3464 -4639 2410 -9687 -2977 -1679 1030 -1562 2704 1895 -3641 -2764 -127 4334 721 -841 1765 -2885 -433 -1871 1297 -297 3157 -283 -1840 -435 -906 1160 1148 -1560 -691 -24 764 1737 -469 -460 429 1112 969 -654 -331 839 931 494 527 1360 1431 1234 213 1129 533 441 2194 1192 -137 -56 -322 -644 305 263 1357 1140 533 459 38 -1140 -1225 -1848 -1579 -1378 -282 -1152 -2002 -1754 -1157 -844 -200 63 243 583 310 -130 -637 -587 -428 -339 405 748 217 -515 135 -1021 -1118 226 -1523 -626 36 51 428 544 894 751 213 -77 -223 271 -36 488 394 -235 -15 458 686 40 457 579 325 345 732 -33 -376 -343 90 -240 15 -247 363 384 -172 -169 -300 -356 -655 -713 -378 353 139 -545 10 -647 -1535 -824 -692 -375 -526 289 -1532 -510 -317 201 -328 570 419 -790 -592 -27 939 172 -212 435 -705 -107 -464 334 -78 873 -84 -524 -119 -272 399 476 -714 -345 -12 408 932 -257 -253 230 583 503 -350 -187 506 597 311 344 900 965 830 142 739 362 323 1728 943 -110 -46 -243 -479 241 219 1222 1073 504 416 32 -943 -921 -1342 -1208 -1191 -253 -1154 -2021 -1857 -1303 -951 -237 76 294 676 356 -137 -666 -601 -435 -383 475 972 282 -706 173 -1208 -1337 275 -1916 -824 49 70 611 832 1361 1161 320 -115 -306 372 -49 658 569 -362 -23 701 1018 57 657 792 427 459 1043 -48 -581 -545 138 -385 26 -418 626 676 -306 -291 -498 -600 -1086 SS 20240730T125121.0Z 8977.535660 242 1 53.90 2 63.85 81.29 4.65 84.74 0.00 1 0.00 1 0 17 1.175e-02 6.073e-03 2.868e-03 1.126e-03 2.878696e-01 5.723003e-04 3.077816e-03 -6.000000e+00 6.745698e-03 228.15 -2.00 3.16 -2.00 316.75 0.00e+00 3.965071e-04 7.580056e-05 1.082042e-04 -6.000000e+00 3.130380e-04 294.83 -2.00 20.00 -2.00 315.82 0.00e+00 2.255 0.000 302.00 328.00 3 4.0629e+00 1.4986e-03 2.5997e-02 -6.0000e+00 1.6702e-02 2.4872e-02 1.6883e-03 1.3294e-02 -6.0000e+00 1.8100e-02 -2.0976e-03 9.8345e-04 6.4502e-03 -6.0000e+00 1.0863e-02 -5.0541e-03 4.7177e-04 1.7941e-03 -6.0000e+00 4.6437e-03 6.8228e-04 6.9377e-04 3.2227e-05 2.0754e-05 -6.0000e+00 3.2122e-04 -6.2908e-05 0.0000e+00 10 0 0 10 0 0 -0.93 25.25 0.44 -0.00006 0.00515 42 4 1 5 0 1283.270 33.75 20.00 25.25 35.38 5.6 991.59 -3390 -487 -2362 -3542 -4142 -2251 -2543 -3280 -2653 -2839 -2690 -3011 -1994 -2825 -254 88 -222 -226 1460 1980 242 -784 1311 2133 1122 308 410 -1525 -124 518 1098 1664 1748 -342 -1840 -1796 -1900 -379 9 -408 -681 -108 124 459 -79 -204 -278 307 -50 33 -55 649 1260 850 312 487 969 481 118 598 578 1107 1839 1440 108 -216 -244 -515 595 420 416 449 228 350 -140 -357 -580 -1142 -1050 -1048 -970 -1483 -2302 -1666 -1085 -663 -337 128 364 621 513 231 54 348 336 196 632 562 -132 -320 -429 -868 -490 112 -1046 -675 -625 -428 168 313 604 408 154 118 -2 130 305 437 377 15 -32 355 349 299 317 197 392 898 546 126 -224 -263 18 -20 69 -63 206 347 -192 -241 -339 -551 -552 -453 -70 -357 -512 -538 -301 -360 -478 -431 -489 -461 -533 -394 -652 -60 23 -62 -65 435 609 77 -252 422 721 375 108 144 -515 -42 171 385 585 669 -138 -711 -677 -781 -167 5 -236 -407 -67 80 296 -51 -133 -178 191 -31 20 -36 431 882 631 241 363 732 364 88 466 438 899 1532 1286 98 -182 -202 -420 513 389 401 429 229 338 -126 -304 -475 -900 -870 -929 -921 -1490 -2493 -1799 -1246 -778 -397 155 441 752 574 248 56 351 360 223 763 721 -173 -413 -541 -1055 -562 133 -1298 -882 -820 -589 233 447 907 621 226 168 -3 175 408 587 522 22 -46 523 501 412 431 265 504 1165 732 175 -329 -383 27 -31 110 -101 339 583 -325 -397 -557 -874 -860 SS 20240730T125641.5Z 8977.539369 245 1 54.42 2 62.66 81.78 3.48 83.44 0.00 1 0.00 1 0 17 1.028e-02 6.285e-03 1.466e-03 6.915e-04 2.779309e-01 3.520023e-04 2.986385e-03 -6.000000e+00 5.902712e-03 228.15 -2.00 3.16 -2.00 316.34 0.00e+00 4.274879e-04 4.195179e-05 7.167994e-05 -6.000000e+00 2.739410e-04 294.83 -2.00 20.00 -2.00 315.44 0.00e+00 2.165 0.000 302.00 328.00 3 3.2604e+00 9.1560e-04 2.4997e-02 -6.0000e+00 1.4615e-02 1.7973e-02 1.0274e-03 1.2824e-02 -6.0000e+00 1.5839e-02 -2.3167e-03 5.9216e-04 6.2299e-03 -6.0000e+00 9.5054e-03 -4.3527e-03 2.7788e-04 1.7422e-03 -6.0000e+00 4.0631e-03 1.6914e-03 6.8972e-04 1.9764e-05 2.0656e-05 -6.0000e+00 2.8111e-04 5.5477e-04 0.0000e+00 10 0 0 10 0 0 85.63 25.26 0.38 0.00055 0.00574 99 10 1 5 0 549.620 33.50 20.00 25.26 35.56 5.6 993.63 -1221 -1081 -1681 -3146 -4152 -2520 -2683 -1276 -1424 -2011 -2750 -2503 -1409 -688 -190 -97 508 238 979 1343 755 648 1361 1430 971 893 106 -398 -197 742 1077 1408 1743 -873 -1980 -2053 -2056 -1124 -224 -639 -640 -373 -201 15 82 48 -315 115 -300 62 749 505 1073 936 800 851 586 485 265 528 874 1182 1753 1419 185 -183 -460 -607 518 568 354 406 315 268 -15 -307 -686 -1019 -895 -1181 -1204 -1788 -2178 -1732 -1071 -587 -176 191 349 293 359 177 89 323 346 230 612 671 44 -243 -510 -819 -359 60 -996 -803 -693 -495 141 504 511 296 171 41 -23 276 234 377 356 38 -88 311 359 356 618 270 507 949 519 116 -57 -238 -93 46 130 -126 264 266 -243 -171 -511 -598 -559 -205 -200 -323 -579 -751 -427 -480 -232 -290 -436 -598 -557 -348 -180 -57 -30 163 80 341 483 279 238 507 526 379 363 44 -155 -76 282 404 573 769 -383 -881 -893 -912 -543 -122 -387 -404 -247 -136 10 56 33 -213 76 -195 41 513 355 796 700 620 673 473 391 209 414 705 978 1505 1304 165 -158 -387 -501 451 515 339 405 314 257 -14 -268 -568 -845 -746 -1067 -1177 -1867 -2349 -1884 -1197 -677 -213 230 434 349 409 191 92 337 369 262 722 848 58 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