File name: Pandora256s1_MiamiFL-FIU_20240814_L2Fit_fout2c6d20240708p1-8.txt File generation date: 20260123T110409.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v6d20240708.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240814_L1_smca1c6d20240708p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0470 305.1880 305.3290 305.4700 305.6110 305.7520 305.8929 306.0339 306.1749 306.3158 306.4567 306.5976 306.7385 306.8794 307.0203 307.1612 307.3020 307.4429 307.5837 307.7245 307.8653 308.0061 308.1469 308.2877 308.4284 308.5692 308.7099 308.8507 308.9914 309.1321 309.2728 309.4135 309.5542 309.6948 309.8355 309.9761 310.1167 310.2574 310.3980 310.5386 310.6791 310.8197 310.9603 311.1008 311.2414 311.3819 311.5224 311.6629 311.8034 311.9439 312.0844 312.2248 312.3653 312.5057 312.6461 312.7865 312.9269 313.0673 313.2077 313.3481 313.4884 313.6288 313.7691 313.9094 314.0497 314.1900 314.3303 314.4706 314.6109 314.7511 314.8914 315.0316 315.1718 315.3120 315.4522 315.5924 315.7326 315.8727 316.0129 316.1530 316.2931 316.4332 316.5733 316.7134 316.8535 316.9936 317.1336 317.2737 317.4137 317.5537 317.6938 317.8338 317.9737 318.1137 318.2537 318.3936 318.5336 318.6735 318.8134 318.9533 319.0932 319.2331 319.3730 319.5128 319.6527 319.7925 319.9324 320.0722 320.2120 320.3518 320.4915 320.6313 320.7711 320.9108 321.0505 321.1903 321.3300 321.4697 321.6094 321.7490 321.8887 322.0283 322.1680 322.3076 322.4472 322.5868 322.7264 322.8660 323.0056 323.1451 323.2847 323.4242 323.5637 323.7032 323.8427 323.9822 324.1217 324.2612 324.4006 324.5400 324.6795 324.8189 324.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240814T112324.4Z 8992.474588 44 1 55.07 2 84.51 76.96 164.58 261.34 0.00 1 0.00 1 0 25 6.566e-01 3.252e-02 3.580e-01 1.345e-02 9.137355e-01 7.654086e-03 9.158193e-03 -6.000000e+00 3.795550e-01 228.02 -2.00 3.16 -2.00 322.11 0.00e+00 -1.954714e-02 4.583216e-03 3.819234e-03 -6.000000e+00 1.810719e-02 294.93 -2.00 20.00 -2.00 321.50 0.00e+00 9.131 0.007 302.00 328.00 3 5.7971e-01 3.2250e-02 1.0715e-01 -6.0000e+00 9.4080e-01 1.3671e+00 4.2759e-02 7.4511e-02 -6.0000e+00 1.0235e+00 -1.6787e+00 2.9160e-02 2.2530e-02 -6.0000e+00 6.1184e-01 6.3921e-01 1.3450e-02 1.6893e-02 -6.0000e+00 2.6539e-01 1.4730e-05 -3.1637e-04 3.6380e-04 1.8918e-04 -6.0000e+00 1.8811e-02 1.2251e-06 0.0000e+00 12 8 8 10 0 0 -1.75 25.36 1.26 0.00000 -0.00238 27 3 1 5 0 2039.310 33.75 19.99 25.36 33.75 5.7 981.09 900000 40972 40681 170247 -19936 101559 -41607 -15944 -88728 -26333 126871 68835 900000 -86443 15464 253555 72035 17892 89480 16801 -49712 -63612 15764 900000 15894 -5540 95503 -26322 17203 7232 137572 121344 900000 68921 213548 900000 900000 900000 217503 29484 74639 236598 234864 900000 26858 34843 87426 91088 900000 -13768 10456 56567 86633 29303 34966 -144 110407 72436 16684 257390 -2731 -6676 994 401 546 37940 22782 11866 24801 12338 23318 16311 14094 4905 -2512 -631 20440 -21396 -4143 1732 22805 -11195 9486 6454 -9809 208 -2909 1148 -1529 2681 -2010 -4631 -1322 1726 -2174 1647 -3266 -2474 -400 -6980 5244 -4635 -6475 5884 -8885 -6803 3300 4213 4601 -1326 427 2251 -1519 -879 -2904 -1542 -1991 1992 -579 426 669 5056 3768 450 -1341 5996 -3219 824 737 -1452 -754 723 1225 -3138 1196 -124 2852 1161 -544 425 -993 -468 -2529 900000 878 823 2229 -522 1330 -1337 -455 -5914 -1003 1661 1065 900000 -7717 552 3320 1629 703 1704 640 -3491 -4846 563 900000 719 -323 1932 -1566 573 258 1801 1906 900000 2075 2796 900000 900000 900000 2848 2123 3811 3098 3075 900000 1969 2235 3205 3220 900000 -1532 1013 3851 4764 3108 3754 -23 6071 5690 2119 3370 -372 -996 154 70 100 4719 3311 2035 4189 2714 5037 3908 3359 1182 -579 -126 3078 -5042 -933 440 5554 -4441 3403 2552 -4867 99 -1485 573 -773 1239 -908 -2043 -563 766 -1158 997 -2433 -2116 -368 -6899 4305 -3762 -4858 3898 -7317 -5816 2709 3729 4566 -1469 532 3000 -2171 -1239 -4040 -2061 -2711 2734 -860 644 983 6764 4916 591 -1743 7764 -4100 1086 1135 -2654 -1540 1589 2878 -7632 3005 -333 7570 3171 -1492 1094 -2395 -1136 -6063 SS 20240814T113431.1Z 8992.482305 47 1 54.47 2 82.07 78.10 166.92 261.00 0.00 1 0.00 1 0 17 5.790e-01 1.358e-02 1.065e-01 2.468e-03 7.425908e-01 1.316626e-03 7.922537e-03 -6.000000e+00 3.321386e-01 228.02 -2.00 3.16 -2.00 321.11 0.00e+00 -8.861445e-04 6.638553e-04 4.836293e-03 -6.000000e+00 1.542788e-02 294.93 -2.00 20.00 -2.00 320.40 0.00e+00 6.759 0.003 302.00 328.00 3 6.3938e-01 4.6909e-03 7.9636e-02 -6.0000e+00 8.2207e-01 2.1616e-01 6.4650e-03 5.0193e-02 -6.0000e+00 8.9098e-01 -3.1503e-01 5.8820e-03 1.8911e-02 -6.0000e+00 5.3480e-01 1.2254e-01 2.7952e-03 6.6114e-03 -6.0000e+00 2.2871e-01 1.8044e-04 2.6366e-04 6.4404e-05 7.0012e-05 -6.0000e+00 1.5824e-02 9.2273e-05 0.0000e+00 12 8 8 10 0 0 76.47 25.37 0.52 0.00009 0.00207 121 12 1 5 0 450.130 33.75 19.99 25.37 34.63 5.7 987.90 -193891 -32296 -185565 -160999 -219375 -147207 -216027 -194179 -195354 -177572 -157761 -115324 -116237 -144866 -82736 -28047 -35149 -92101 -53287 -67674 -67911 -75512 -73108 7227 -70773 -59945 -4986 -63517 -45743 -41173 -9602 -12775 3839 1014 -3405 3442 -13518 -1124 5356 2843 5446 19602 10212 29408 4536 14168 5811 5404 9327 9665 3775 9282 11791 7794 9772 5344 13540 7375 3621 10700 1145 3249 4751 5549 2757 5425 4007 2407 4531 2961 3826 3092 1884 2129 -28 435 133 -4104 -3793 -1194 -600 -1464 -1553 -1517 -1927 202 99 792 23 747 103 -1004 -1073 -1425 -1586 -444 -643 -167 -1033 -891 -680 -1897 -1562 -421 -1916 -2047 -658 -342 158 281 539 850 90 -91 -327 -32 310 548 384 -31 706 1275 1079 817 379 383 83 534 608 122 -163 -80 -246 -90 -160 -53 549 319 -34 -174 -358 -555 -696 -1994 -85 -2233 -1627 -3643 -1169 -3743 -3131 -3667 -3077 -2392 -1304 -1678 -3591 -1394 -331 -508 -2615 -1116 -1726 -1781 -2144 -2146 106 -2504 -2034 -100 -2201 -1299 -1209 -247 -412 123 36 -123 115 -592 -52 290 192 408 1378 828 2010 401 1159 530 516 909 1021 477 1258 1728 1307 1726 1040 2519 1457 719 1931 234 716 1183 1417 770 1464 1098 704 1452 1117 1584 1348 821 871 -11 148 43 -1418 -1487 -547 -323 -840 -986 -1029 -1407 154 80 599 17 587 76 -709 -742 -1041 -1322 -396 -671 -185 -1261 -1089 -777 -1973 -1598 -430 -1981 -2246 -756 -424 202 407 816 1368 147 -146 -499 -47 461 854 636 -53 1184 2040 1670 1227 552 576 123 781 1016 220 -308 -161 -502 -195 -355 -123 1301 769 -82 -399 -812 -1185 -1452 SS 20240814T114947.8Z 8992.492915 52 1 54.43 2 78.70 79.65 170.14 259.82 0.00 1 0.00 1 0 17 2.288e-01 8.390e-03 1.295e-02 7.607e-04 5.722195e-01 3.908124e-04 6.027573e-03 -6.000000e+00 1.312707e-01 228.02 -2.00 3.16 -2.00 319.73 0.00e+00 1.311066e-03 1.229420e-04 1.410520e-03 -6.000000e+00 6.097254e-03 294.93 -2.00 20.00 -2.00 318.84 0.00e+00 4.924 0.001 302.00 328.00 3 4.2042e-01 1.1452e-03 5.5687e-02 -6.0000e+00 3.2491e-01 3.5827e-02 1.3896e-03 2.7657e-02 -6.0000e+00 3.5213e-01 -6.1404e-02 1.1065e-03 1.3444e-02 -6.0000e+00 2.1136e-01 1.9110e-02 5.7762e-04 3.6762e-03 -6.0000e+00 9.0396e-02 1.4832e-03 5.0043e-04 2.0667e-05 4.4990e-05 -6.0000e+00 6.2536e-03 -2.6722e-04 0.0000e+00 11 8 0 10 0 0 74.60 25.35 0.43 -0.00027 0.00349 410 42 1 5 0 132.740 33.50 20.00 25.35 36.24 5.7 998.02 -77974 -79059 -64566 -74237 -82227 -79949 -85590 -73506 -63627 -69794 -61939 -61134 -44270 -34360 -28629 -18309 -17398 -12913 -15405 -13606 -14151 -15070 -15280 -8446 -11431 -9438 -8606 -11094 -9876 -8180 -5933 -4503 -152 -658 -6661 -5749 -4978 -2553 898 605 2017 1793 1889 2748 1907 2116 1884 492 1657 1056 1863 2302 2533 2894 2514 2435 1967 996 584 1194 1610 2045 3014 3080 1610 1160 518 77 992 1013 1074 846 186 293 -183 -912 -1676 -2198 -1886 -1916 -1564 -1895 -2198 -1804 -1126 -657 128 457 769 558 357 21 -458 -224 -415 -68 369 560 -211 -366 -653 -1102 -671 -194 -1261 -1093 -696 -533 231 586 537 362 358 77 78 393 321 376 254 -4 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