File name: Pandora256s1_MiamiFL-FIU_20240826_L2Fit_fout2c6d20240708p1-8.txt File generation date: 20260123T110819.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v6d20240708.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240826_L1_smca1c6d20240708p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0470 305.1880 305.3290 305.4700 305.6110 305.7520 305.8929 306.0339 306.1749 306.3158 306.4567 306.5976 306.7385 306.8794 307.0203 307.1612 307.3020 307.4429 307.5837 307.7245 307.8653 308.0061 308.1469 308.2877 308.4284 308.5692 308.7099 308.8507 308.9914 309.1321 309.2728 309.4135 309.5542 309.6948 309.8355 309.9761 310.1167 310.2574 310.3980 310.5386 310.6791 310.8197 310.9603 311.1008 311.2414 311.3819 311.5224 311.6629 311.8034 311.9439 312.0844 312.2248 312.3653 312.5057 312.6461 312.7865 312.9269 313.0673 313.2077 313.3481 313.4884 313.6288 313.7691 313.9094 314.0497 314.1900 314.3303 314.4706 314.6109 314.7511 314.8914 315.0316 315.1718 315.3120 315.4522 315.5924 315.7326 315.8727 316.0129 316.1530 316.2931 316.4332 316.5733 316.7134 316.8535 316.9936 317.1336 317.2737 317.4137 317.5537 317.6938 317.8338 317.9737 318.1137 318.2537 318.3936 318.5336 318.6735 318.8134 318.9533 319.0932 319.2331 319.3730 319.5128 319.6527 319.7925 319.9324 320.0722 320.2120 320.3518 320.4915 320.6313 320.7711 320.9108 321.0505 321.1903 321.3300 321.4697 321.6094 321.7490 321.8887 322.0283 322.1680 322.3076 322.4472 322.5868 322.7264 322.8660 323.0056 323.1451 323.2847 323.4242 323.5637 323.7032 323.8427 323.9822 324.1217 324.2612 324.4006 324.5400 324.6795 324.8189 324.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240826T115825.6Z 9004.498907 241 1 53.76 2 77.75 84.54 11.17 271.26 0.00 1 0.00 1 0 17 1.805e-01 7.797e-03 6.134e-02 2.433e-03 5.430782e-01 1.250311e-03 5.690489e-03 -6.000000e+00 1.034857e-01 227.93 -2.00 3.16 -2.00 319.92 0.00e+00 9.723987e-04 4.236286e-04 1.287398e-03 -6.000000e+00 4.805277e-03 294.72 -2.00 20.00 -2.00 319.07 0.00e+00 4.573 0.001 302.00 328.00 3 2.8973e+00 3.7433e-03 5.2005e-02 -6.0000e+00 2.5610e-01 5.4407e-02 4.6256e-03 2.6333e-02 -6.0000e+00 2.7762e-01 -4.6113e-02 3.7899e-03 1.2762e-02 -6.0000e+00 1.6662e-01 9.5299e-03 1.9557e-03 3.4534e-03 -6.0000e+00 7.1232e-02 1.7525e-04 3.5971e-04 6.7501e-05 4.2493e-05 -6.0000e+00 4.9332e-03 1.9087e-03 0.0000e+00 11 8 0 10 0 0 99.70 25.30 0.44 0.00191 0.00461 40 4 1 5 0 1343.840 33.50 20.00 25.30 34.34 5.7 983.72 -68685 -49879 -56040 -25448 -46353 28924 -45776 -89648 -75252 -73623 -40533 -43846 1660 -27894 -43468 -20707 -1115 -23396 -5592 541 -11469 -20148 -14604 -599 -14055 -12133 -1589 -17300 -1508 -12048 1075 -8929 6540 -374 1183 -1485 -927 -519 3552 -1973 -598 2827 2567 5557 -742 -2460 1998 1286 3426 189 601 1394 3342 1379 2696 410 2754 2614 -207 2415 -471 1563 1295 1710 465 1858 -271 -406 879 659 1185 1514 887 621 -142 -1140 -994 -2616 -2257 -1559 -215 -2060 -2061 -1881 -1687 -173 248 226 725 471 608 -48 -709 -735 124 -118 810 760 -75 -262 40 -1372 -890 -71 -1623 -935 -288 -318 506 971 488 695 403 -20 -257 211 -41 274 92 0 -280 413 563 226 160 155 132 716 27 55 -422 -213 -252 -247 -130 -336 380 502 97 127 -342 -301 -288 -945 -663 -851 -278 -572 165 -597 -2084 -1732 -1817 -750 -926 27 -768 -1722 -771 -38 -1094 -236 23 -561 -1080 -776 -30 -884 -794 -95 -1174 -85 -792 71 -767 551 -36 108 -138 -95 -63 507 -357 -109 535 511 1098 -158 -542 426 282 758 46 159 407 1045 476 972 158 1065 1012 -81 903 -187 668 572 834 238 906 -131 -201 472 407 741 986 576 384 -88 -642 -519 -1388 -1316 -975 -154 -1699 -1719 -1661 -1592 -172 241 226 721 483 579 -43 -606 -641 118 -120 941 937 -100 -348 49 -1668 -1001 -80 -1897 -1148 -371 -437 704 1486 773 1143 657 -31 -400 313 -62 428 144 0 -460 655 863 354 241 223 184 1035 41 93 -738 -392 -459 -476 -253 -691 795 1067 206 260 -666 -585 -548 SS 20240826T120315.5Z 9004.502263 244 1 17.67 2 76.67 85.05 12.24 271.69 0.00 1 0.00 1 0 17 1.092e-01 7.120e-03 1.402e-02 1.248e-03 5.032680e-01 6.356756e-04 5.276220e-03 -6.000000e+00 6.263690e-02 227.93 -2.00 3.16 -2.00 319.08 0.00e+00 1.160752e-03 1.623186e-04 7.831485e-04 -6.000000e+00 2.907606e-03 294.72 -2.00 20.00 -2.00 318.15 0.00e+00 4.227 0.001 302.00 328.00 3 1.0413e+00 1.7868e-03 4.7904e-02 -6.0000e+00 1.5501e-01 2.3593e-02 2.0958e-03 2.3594e-02 -6.0000e+00 1.6802e-01 -3.4580e-02 1.5081e-03 1.1509e-02 -6.0000e+00 1.0084e-01 8.6556e-03 7.9790e-04 3.2612e-03 -6.0000e+00 4.3128e-02 1.6443e-03 6.2361e-04 3.4554e-05 3.6538e-05 -6.0000e+00 2.9847e-03 -4.3280e-04 0.0000e+00 12 9 1 12 1 1 12.04 25.31 0.45 -0.00043 0.00425 92 29 1 5 0 189.910 33.75 20.00 25.31 34.43 5.7 984.36 -41517 -26341 -31973 -25898 -48988 -36442 -39461 -37667 -35127 -34510 -26871 -27504 -21405 -19364 -13652 -5576 -8104 -5412 -3574 -6032 -6339 -5024 -3587 -3115 -1770 -4476 -2333 -3882 -5675 -1380 -1968 187 521 -1806 -2788 -4996 -3148 -2131 775 35 550 1435 1463 1813 726 931 1326 1544 577 901 1895 2086 2282 1764 1543 1554 1263 230 755 1026 1131 1770 2378 2009 917 967 -47 -103 659 602 273 114 204 389 -248 -654 -1164 -1819 -1120 -1661 -1235 -1705 -2022 -1657 -1392 -684 10 89 325 551 366 345 49 -48 -200 68 454 579 -79 -413 -727 -907 -519 -108 -1070 -1034 -776 -361 162 502 414 496 357 159 -95 262 203 470 345 4 82 457 574 461 338 79 204 892 349 58 -89 -235 -212 -62 -95 -160 364 324 -54 -110 -511 -406 -411 -1006 -635 -872 -646 -1407 -901 -1086 -1165 -1206 -1277 -955 -1075 -951 -1044 -849 -375 -619 -437 -305 -557 -605 -475 -349 -328 -181 -498 -258 -421 -605 -147 -240 26 82 -308 -462 -837 -570 -454 180 10 158 438 467 590 241 314 449 530 205 335 764 862 1023 801 741 775 650 120 381 511 583 991 1389 1223 582 590 -30 -66 432 428 214 89 158 302 -178 -449 -744 -1162 -778 -1277 -1034 -1538 -1892 -1637 -1403 -733 11 98 357 581 376 344 46 -46 -202 75 543 721 -106 -553 -914 -1080 -598 -126 -1313 -1291 -1019 -484 225 738 638 794 564 247 -139 377 293 687 537 6 130 702 883 683 497 112 288 1299 527 94 -150 -404 -368 -113 -179 -309 717 631 -106 -214 -973 -735 -751 SS 20240826T120819.9Z 9004.505786 247 1 54.45 2 75.53 85.58 13.35 272.11 0.00 1 0.00 1 0 17 7.615e-02 6.941e-03 3.445e-03 4.070e-04 4.705715e-01 2.067053e-04 4.940593e-03 -6.000000e+00 4.367387e-02 227.93 -2.00 3.16 -2.00 318.72 0.00e+00 9.413904e-04 4.702401e-05 5.631260e-04 -6.000000e+00 2.027374e-03 294.72 -2.00 20.00 -2.00 317.77 0.00e+00 3.916 0.001 302.00 328.00 3 2.9340e-01 5.7015e-04 4.4443e-02 -6.0000e+00 1.0808e-01 1.0753e-02 6.6200e-04 2.1933e-02 -6.0000e+00 1.1715e-01 -2.4295e-02 4.5354e-04 1.0687e-02 -6.0000e+00 7.0315e-02 5.3058e-03 2.3858e-04 3.0342e-03 -6.0000e+00 3.0071e-02 4.8528e-03 6.4055e-04 1.1307e-05 3.2728e-05 -6.0000e+00 2.0812e-03 -3.1204e-04 0.0000e+00 11 8 0 10 0 0 5.89 25.31 0.42 -0.00031 0.00450 822 84 1 5 0 66.230 33.75 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