File name: Pandora256s1_MiamiFL-FIU_20240828_L2Fit_fwvt1c2d20230424p1-8.txt File generation date: 20240829T053139.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240828_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.0837 492.2048 492.3259 492.4469 492.5680 492.6890 492.8100 492.9309 493.0519 493.1729 493.2938 493.4147 493.5356 493.6565 493.7773 493.8982 494.0190 494.1398 494.2606 494.3814 494.5022 494.6229 494.7436 494.8643 494.9850 495.1057 495.2264 495.3470 495.4676 495.5883 495.7088 495.8294 495.9500 496.0705 496.1910 496.3116 496.4320 496.5525 496.6730 496.7934 496.9138 497.0342 497.1546 497.2750 497.3954 497.5157 497.6360 497.7563 497.8766 497.9969 498.1171 498.2374 498.3576 498.4778 498.5980 498.7182 498.8383 498.9584 499.0786 499.1987 499.3187 499.4388 499.5589 499.6789 499.7989 499.9189 500.0389 500.1588 500.2788 500.3987 500.5186 500.6385 500.7584 500.8783 500.9981 501.1179 501.2378 501.3575 501.4773 501.5971 501.7168 501.8366 501.9563 502.0759 502.1956 502.3153 502.4349 502.5545 502.6741 502.7937 502.9133 503.0329 503.1524 503.2719 503.3914 503.5109 503.6304 503.7498 503.8693 503.9887 504.1081 504.2275 504.3468 504.4662 504.5855 504.7048 504.8241 504.9434 505.0626 505.1819 505.3011 505.4203 505.5395 505.6587 505.7778 505.8970 506.0161 506.1352 506.2543 506.3734 506.4924 506.6115 506.7305 506.8495 506.9685 507.0874 507.2064 507.3253 507.4442 507.5631 507.6820 507.8009 507.9197 508.0386 508.1574 508.2762 508.3950 508.5137 508.6325 508.7512 508.8699 508.9886 509.1073 509.2259 509.3446 509.4632 509.5818 509.7004 509.8189 509.9375 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240828T110942.1Z 9006.465070 197 1 54.37 2 88.79 80.10 24.75 77.04 0.00 1 0.00 1 0 29 9.728e-03 9.533e-03 5.031e-04 5.010e-04 4.295433e+04 4.230012e+01 2.679349e+03 -6.000000e+00 5.422450e+02 294.69 -2.00 20.00 -2.00 505.43 0.00e+00 4.354903e-03 1.411689e-05 2.748206e-04 -6.000000e+00 2.768969e-04 294.69 -2.00 20.00 -2.00 500.67 0.00e+00 2.074661e+00 9.667629e-03 1.812074e-01 -6.000000e+00 1.875292e-01 227.92 -2.00 3.16 -2.00 502.22 0.00e+00 17.934 0.052 489.00 513.00 1 3.7137e+00 7.4159e-04 3.1620e-02 -6.0000e+00 1.4415e-02 -3.3307e-02 1.8522e-04 5.1925e-03 -6.0000e+00 3.7695e-03 2.8304e-03 3.2713e-03 3.1965e-05 1.9733e-04 -6.0000e+00 8.4521e-04 -4.4967e-03 1.7253e-04 12 8 8 10 0 0 99.77 25.31 4.21 -0.00450 0.01819 65 7 1 4 0 836.380 33.75 20.00 25.31 32.91 5.8 975.97 -1269 -503 481 1279 1702 1996 2145 1902 1540 1001 587 0 -445 -772 -668 -400 31 359 617 494 426 319 494 759 928 965 718 -274 -1202 -1756 -1901 -1531 -668 85 235 -2 -498 -816 -918 -896 -736 -162 144 517 690 805 565 165 -530 -1278 -1844 -2298 -2018 -1351 -397 45 1062 478 395 366 535 751 641 496 139 -200 -422 -632 -1037 -1148 -985 -638 -264 -72 -21 -135 -556 -688 -699 -483 -70 43 -182 -148 -225 -337 -622 -671 -27 405 1149 1620 1600 1352 1041 709 317 -606 -1835 -2399 -2438 -2080 -1164 -209 421 409 -191 -735 -756 -698 -755 -446 -208 92 755 1526 1700 983 260 -686 -1028 -908 241 900 1358 1643 1255 769 638 -253 -724 -762 -989 -950 -545 -276 127 660 742 474 568 683 1029 1433 1490 1023 171 -786 -1012 -739 -1176 -478 465 1250 1668 1996 2146 1916 1542 992 577 0 -436 -754 -654 -395 31 360 630 500 432 325 504 781 947 986 733 -282 -1201 -1744 -1892 -1541 -679 88 245 -2 -515 -838 -936 -914 -758 -168 150 543 731 852 595 173 -545 -1304 -1867 -2299 -2016 -1354 -409 47 1100 500 412 382 561 793 670 518 146 -206 -436 -648 -1051 -1149 -986 -642 -268 -74 -21 -135 -557 -676 -685 -467 -68 42 -179 -146 -222 -334 -611 -654 -27 390 1111 1575 1534 1254 933 615 267 -513 -1560 -2008 -2090 -1822 -1063 -199 407 405 -190 -725 -749 -695 -751 -446 -206 91 734 1509 1727 1006 268 -704 -1035 -897 233 874 1330 1625 1241 763 634 -253 -711 -748 -967 -939 -540 -277 129 676 766 497 598 725 1089 1500 1567 1071 178 -822 -1063 -771 SQ 20240828T111456.8Z 9006.468713 205 1 52.17 2 87.62 80.67 23.63 77.01 0.00 1 0.00 1 0 22 2.873e-02 3.504e-02 8.664e-04 8.627e-04 3.335500e+04 6.995145e+01 2.132201e+03 -6.000000e+00 1.601812e+03 294.69 -2.00 20.00 -2.00 505.37 0.00e+00 4.565362e-03 2.420639e-05 2.958067e-04 -6.000000e+00 8.176460e-04 294.69 -2.00 20.00 -2.00 500.53 0.00e+00 2.086468e+00 1.671892e-02 1.439834e-01 -6.000000e+00 5.534829e-01 227.92 -2.00 3.16 -2.00 502.10 0.00e+00 14.947 0.030 489.00 513.00 1 5.0953e+00 1.2821e-03 2.6030e-02 -6.0000e+00 4.2549e-02 -8.3815e-03 3.2289e-04 4.0588e-03 -6.0000e+00 1.1118e-02 1.0960e-03 3.5678e-03 5.9161e-05 1.7881e-04 -6.0000e+00 2.4954e-03 1.1419e-02 1.1603e-04 12 9 9 12 1 1 99.32 25.31 2.02 0.01142 0.03617 14 2 1 4 0 3477.620 33.50 20.00 25.31 33.02 5.8 976.73 -278 432 1206 1461 1612 1879 1886 1404 809 903 385 -137 -388 -444 -304 -143 222 414 483 208 -101 -37 144 320 605 776 588 -549 -1013 -1186 -1025 -870 179 552 328 -153 -506 -621 -386 -402 270 677 1054 1244 1519 1463 1476 1060 383 15 -152 -461 214 963 1635 1354 -32715 1861 1532 1623 1992 2119 1851 1499 1622 1070 857 825 300 457 597 1075 1017 1113 760 525 367 192 158 228 505 285 245 475 83 -299 -506 -711 -523 169 509 1134 692 490 386 45 -5 -714 -1541 -1456 -1348 -1320 -740 -603 -632 -904 -1372 -1493 -1133 -993 -875 -739 -478 0 400 1490 1284 755 230 -669 -921 -597 338 835 1076 1454 1188 896 988 64 -54 153 -67 133 419 421 533 776 946 620 632 681 750 942 766 343 -371 -627 -731 -325 -266 417 1184 1453 1637 1911 1949 1436 837 919 389 -137 -390 -442 -304 -142 224 422 502 213 -104 -38 149 334 635 813 614 -569 -1030 -1198 -1035 -874 182 572 347 -161 -528 -643 -395 -412 278 704 1110 1305 1603 1543 1542 1096 396 16 -152 -462 214 962 1656 1393 -40598 1938 1595 1686 2077 2224 1920 1552 1680 1094 880 837 301 452 590 1067 1022 1131 761 525 364 187 152 222 491 275 238 468 82 -296 -496 -698 -506 163 494 1106 671 464 351 41 -4 -613 -1317 -1237 -1169 -1163 -685 -577 -619 -884 -1336 -1463 -1113 -978 -872 -734 -471 0 390 1471 1294 767 233 -668 -906 -579 324 804 1045 1421 1152 870 958 62 -52 146 -64 129 404 418 529 778 952 630 651 706 778 970 784 348 -374 -635 -741 -327 SQ 20240828T115803.2Z 9006.498648 228 1 31.02 2 77.99 85.22 14.42 74.80 0.00 1 0.00 1 0 22 3.915e-03 3.888e-03 3.097e-04 3.090e-04 1.219813e+04 2.156671e+01 8.083564e+02 -6.000000e+00 2.182614e+02 294.69 -2.00 20.00 -2.00 505.28 0.00e+00 1.096152e-03 8.645042e-06 7.381444e-05 -6.000000e+00 1.114326e-04 294.69 -2.00 20.00 -2.00 500.42 0.00e+00 5.155153e-01 5.987177e-03 6.346236e-02 -6.000000e+00 7.545377e-02 227.92 -2.00 3.16 -2.00 502.01 0.00e+00 4.659 0.001 489.00 513.00 1 4.3059e+00 4.6008e-04 8.7729e-03 -6.0000e+00 5.8001e-03 3.1975e-03 1.1815e-04 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