File name: Pandora256s1_MiamiFL-FIU_20240917_L2Fit_fout2c6d20240708p1-8.txt File generation date: 20260123T111310.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v6d20240708.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240917_L1_smca1c6d20240708p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0470 305.1880 305.3290 305.4700 305.6110 305.7520 305.8929 306.0339 306.1749 306.3158 306.4567 306.5976 306.7385 306.8794 307.0203 307.1612 307.3020 307.4429 307.5837 307.7245 307.8653 308.0061 308.1469 308.2877 308.4284 308.5692 308.7099 308.8507 308.9914 309.1321 309.2728 309.4135 309.5542 309.6948 309.8355 309.9761 310.1167 310.2574 310.3980 310.5386 310.6791 310.8197 310.9603 311.1008 311.2414 311.3819 311.5224 311.6629 311.8034 311.9439 312.0844 312.2248 312.3653 312.5057 312.6461 312.7865 312.9269 313.0673 313.2077 313.3481 313.4884 313.6288 313.7691 313.9094 314.0497 314.1900 314.3303 314.4706 314.6109 314.7511 314.8914 315.0316 315.1718 315.3120 315.4522 315.5924 315.7326 315.8727 316.0129 316.1530 316.2931 316.4332 316.5733 316.7134 316.8535 316.9936 317.1336 317.2737 317.4137 317.5537 317.6938 317.8338 317.9737 318.1137 318.2537 318.3936 318.5336 318.6735 318.8134 318.9533 319.0932 319.2331 319.3730 319.5128 319.6527 319.7925 319.9324 320.0722 320.2120 320.3518 320.4915 320.6313 320.7711 320.9108 321.0505 321.1903 321.3300 321.4697 321.6094 321.7490 321.8887 322.0283 322.1680 322.3076 322.4472 322.5868 322.7264 322.8660 323.0056 323.1451 323.2847 323.4242 323.5637 323.7032 323.8427 323.9822 324.1217 324.2612 324.4006 324.5400 324.6795 324.8189 324.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240917T145058.8Z 9026.618737 351 1 52.50 2 42.20 118.50 145.55 298.66 0.00 1 0.00 1 0 17 8.159e-03 6.521e-03 2.039e-03 1.412e-03 1.676045e-01 7.244841e-04 1.827207e-03 -6.000000e+00 4.674980e-03 227.72 -2.00 3.16 -2.00 314.88 0.00e+00 3.728979e-04 6.390027e-05 3.701931e-05 -6.000000e+00 2.167493e-04 294.21 -2.00 20.00 -2.00 314.13 0.00e+00 1.348 0.000 302.00 328.00 3 5.5070e+00 1.8520e-03 1.5418e-02 -6.0000e+00 1.1566e-02 1.7561e-02 2.0606e-03 7.7393e-03 -6.0000e+00 1.2540e-02 3.8182e-03 1.1803e-03 3.7675e-03 -6.0000e+00 7.5253e-03 -7.1134e-03 5.2158e-04 1.0574e-03 -6.0000e+00 3.2172e-03 4.8308e-04 6.0622e-04 4.0269e-05 1.4010e-05 -6.0000e+00 2.2299e-04 1.0515e-03 0.0000e+00 12 9 1 12 9 1 99.49 25.18 0.48 0.00105 0.00561 16 2 1 5 0 3087.690 33.50 19.99 25.18 35.82 5.7 993.34 -632 -88 184 -1555 -2793 -909 -1102 -199 274 -826 -1253 -716 -805 -553 142 319 500 379 670 1233 352 715 392 1531 915 483 380 -688 329 486 1434 1771 1718 -806 -2237 -1647 -2306 -1186 -611 -657 -852 -378 -86 -79 -556 -374 -584 -427 -349 -13 229 515 1134 933 636 779 873 546 192 446 1073 828 1681 1324 186 -268 -491 -788 658 255 517 653 192 328 -97 -368 -572 -1414 -1033 -1190 -1002 -1585 -1923 -1652 -1077 -676 108 333 383 518 402 -114 -151 244 -204 351 614 741 225 -249 -397 -885 -521 129 -1192 -811 -497 -309 179 535 759 372 163 136 -167 31 29 494 391 136 96 282 538 208 604 91 328 858 492 -186 -132 -251 -40 -97 82 -229 242 348 -180 -3 -328 -594 -642 -213 -32 67 -537 -859 -281 -326 -65 99 -313 -465 -264 -322 -228 65 157 252 195 352 616 180 360 200 805 506 276 216 -369 173 246 738 960 920 -449 -1180 -902 -1276 -752 -429 -500 -664 -305 -70 -65 -458 -306 -465 -347 -273 -10 183 410 939 808 565 701 795 496 172 397 980 764 1653 1300 181 -253 -449 -695 604 250 521 686 203 335 -98 -335 -495 -1232 -869 -1114 -985 -1624 -2097 -1785 -1239 -792 132 420 484 629 474 -128 -155 252 -208 390 714 899 288 -313 -470 -1021 -574 147 -1425 -1021 -651 -402 241 725 1067 524 220 176 -208 38 36 598 510 182 132 385 713 277 758 114 391 1018 618 -238 -175 -340 -53 -131 117 -330 357 524 -263 -5 -475 -836 -931 SS 20240917T145620.1Z 9026.622455 354 1 54.78 2 41.15 119.75 146.54 300.09 0.00 1 0.00 1 0 17 7.845e-03 6.502e-03 1.330e-03 9.698e-04 1.657810e-01 4.992191e-04 1.815923e-03 -6.000000e+00 4.495090e-03 227.72 -2.00 3.16 -2.00 314.62 0.00e+00 3.885866e-04 4.187082e-05 2.042632e-05 -6.000000e+00 2.084057e-04 294.21 -2.00 20.00 -2.00 313.91 0.00e+00 1.327 0.000 302.00 328.00 3 4.9473e+00 1.2725e-03 1.5199e-02 -6.0000e+00 1.1121e-02 1.7210e-02 1.4132e-03 7.6731e-03 -6.0000e+00 1.2058e-02 9.9040e-04 8.1125e-04 3.7326e-03 -6.0000e+00 7.2357e-03 -6.2944e-03 3.5585e-04 1.0550e-03 -6.0000e+00 3.0934e-03 8.6780e-04 5.3973e-04 2.7582e-05 1.4281e-05 -6.0000e+00 2.1441e-04 9.3618e-04 0.0000e+00 11 8 0 10 0 0 99.00 25.19 0.45 0.00094 0.00499 31 3 1 5 0 1766.820 33.50 20.00 25.19 36.19 5.7 996.14 -195 -206 -674 -1760 -1946 -850 -377 347 180 -573 -903 -954 -446 -588 352 7 291 416 657 1362 225 426 1367 1326 1028 624 54 -255 182 506 1125 1443 1647 -1025 -2133 -2290 -2046 -937 -238 -820 -881 -515 -376 -510 -257 -195 -603 -137 -492 -136 765 622 1333 822 531 628 590 262 439 643 810 984 1762 1245 -80 -155 -528 -459 698 433 605 270 565 362 56 -134 -706 -982 -982 -1334 -979 -1780 -2040 -1654 -984 -645 -258 299 377 451 243 30 -82 283 215 212 596 807 164 -222 -431 -771 -494 10 -1008 -657 -583 -526 98 580 586 346 341 64 -66 124 278 345 225 -8 12 319 285 449 475 229 318 915 600 79 -65 -287 72 24 158 -110 74 320 -207 -166 -366 -625 -653 -73 -83 -276 -677 -660 -290 -123 125 72 -240 -370 -389 -183 -269 166 4 152 221 358 757 128 239 769 729 592 372 32 -142 99 264 599 809 917 -596 -1246 -1299 -1172 -615 -164 -624 -728 -418 -312 -427 -213 -160 -509 -111 -385 -105 606 522 1107 715 475 568 541 240 394 574 744 918 1753 1247 -80 -148 -485 -404 641 427 620 277 579 376 55 -123 -614 -845 -870 -1252 -970 -1856 -2164 -1829 -1109 -777 -313 374 471 541 281 33 -85 294 222 230 679 965 207 -276 -524 -872 -556 12 -1238 -816 -756 -682 131 786 827 488 458 83 -81 148 331 429 290 -11 17 432 377 590 590 283 371 1109 738 99 -85 -383 93 33 216 -158 106 465 -305 -239 -532 -882 -907 SS 20240917T150635.3Z 9026.629575 357 1 54.51 2 39.17 122.27 148.38 303.02 0.00 1 0.00 1 0 17 7.772e-03 6.430e-03 3.984e-04 3.113e-04 1.602256e-01 1.609746e-04 1.763810e-03 -6.000000e+00 4.453035e-03 227.72 -2.00 3.16 -2.00 314.21 0.00e+00 3.744299e-04 1.255158e-05 1.154296e-05 -6.000000e+00 2.064547e-04 294.21 -2.00 20.00 -2.00 313.55 0.00e+00 1.289 0.000 302.00 328.00 3 2.7987e+00 4.0884e-04 1.4753e-02 -6.0000e+00 1.1017e-02 1.0313e-02 4.5353e-04 7.4352e-03 -6.0000e+00 1.1945e-02 1.0473e-03 2.6091e-04 3.6170e-03 -6.0000e+00 7.1680e-03 -5.8345e-03 1.1296e-04 1.0278e-03 -6.0000e+00 3.0645e-03 7.8296e-03 5.6720e-04 8.8037e-06 1.4168e-05 -6.0000e+00 2.1240e-04 8.9758e-04 0.0000e+00 11 8 0 10 0 0 98.08 25.19 0.44 0.00090 0.00516 279 29 1 5 0 195.370 33.50 20.00 25.19 37.34 5.7 1004.41 24 -130 -566 -1845 -2016 -1196 -254 651 767 -324 -1273 -910 -788 -149 465 23 90 540 989 1088 767 750 1339 863 964 758 195 -181 4 989 1183 1449 1248 -989 -2117 -2004 -2134 -1122 -504 -625 -928 -686 -544 -645 -255 -293 -528 -379 -581 70 582 472 917 817 620 977 653 365 376 516 858 1251 1576 1198 219 -167 -440 -408 652 472 284 305 295 353 54 -212 -625 -768 -572 -999 -1157 -1648 -2126 -1552 -986 -659 -187 162 347 325 357 83 1 426 355 244 629 715 39 -218 -377 -690 -264 56 -905 -845 -710 -464 83 480 508 275 246 -2 -15 272 207 357 370 52 -119 208 227 433 568 215 521 930 462 181 -81 -242 -112 172 54 -148 221 230 -149 -133 -430 -568 -652 10 -59 -262 -803 -816 -477 -99 278 343 -153 -591 -418 -372 -74 245 13 50 305 571 644 462 446 800 517 603 489 126 -109 3 568 695 856 784 -618 -1301 -1192 -1316 -761 -375 -501 -783 -580 -470 -560 -219 -250 -454 -313 -477 57 485 403 790 734 554 880 598 333 338 461 787 1184 1551 1205 218 -162 -402 -370 595 457 293 319 308 367 54 -204 -558 -665 -509 -928 -1127 -1714 -2290 -1692 -1114 -776 -226 196 420 388 414 90 1 433 365 268 716 869 48 -268 -447 -779 -292 65 -1084 -1042 -891 -590 110 648 696 378 330 -3 -18 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