File name: Pandora256s1_MiamiFL-FIU_20241019_L2Fit_fwvt1c6d20240708p1-8.txt File generation date: 20260123T111729.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v6d20240708.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20241019_L1_smca1c6d20240708p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20241019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0019 492.1230 492.2441 492.3653 492.4863 492.6074 492.7285 492.8495 492.9706 493.0916 493.2126 493.3335 493.4545 493.5755 493.6964 493.8173 493.9382 494.0591 494.1799 494.3008 494.4216 494.5424 494.6632 494.7840 494.9047 495.0255 495.1462 495.2669 495.3876 495.5083 495.6289 495.7496 495.8702 495.9908 496.1114 496.2320 496.3525 496.4731 496.5936 496.7141 496.8346 496.9551 497.0755 497.1960 497.3164 497.4368 497.5572 497.6775 497.7979 497.9182 498.0385 498.1588 498.2791 498.3994 498.5197 498.6399 498.7601 498.8803 499.0005 499.1207 499.2408 499.3609 499.4811 499.6012 499.7212 499.8413 499.9613 500.0814 500.2014 500.3214 500.4414 500.5613 500.6813 500.8012 500.9211 501.0410 501.1609 501.2807 501.4006 501.5204 501.6402 501.7600 501.8798 501.9995 502.1193 502.2390 502.3587 502.4784 502.5981 502.7177 502.8374 502.9570 503.0766 503.1962 503.3157 503.4353 503.5548 503.6744 503.7939 503.9133 504.0328 504.1523 504.2717 504.3911 504.5105 504.6299 504.7492 504.8686 504.9879 505.1072 505.2265 505.3458 505.4651 505.5843 505.7035 505.8227 505.9419 506.0611 506.1803 506.2994 506.4185 506.5376 506.6567 506.7758 506.8948 507.0139 507.1329 507.2519 507.3709 507.4898 507.6088 507.7277 507.8466 507.9655 508.0844 508.2033 508.3221 508.4410 508.5598 508.6786 508.7973 508.9161 509.0348 509.1536 509.2723 509.3910 509.5096 509.6283 509.7469 509.8656 509.9842 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241019T134055.8Z 9058.570090 306 1 54.40 2 61.59 119.10 90.02 295.32 0.00 1 0.00 1 0 15 3.302e-03 3.290e-03 3.491e-04 3.481e-04 5.900202e+03 2.249159e+01 4.023613e+02 -6.000000e+00 1.834460e+02 292.48 -2.00 20.00 -2.00 505.26 0.00e+00 6.709265e-04 9.673105e-06 4.331651e-05 -6.000000e+00 9.359323e-05 292.48 -2.00 20.00 -2.00 500.38 0.00e+00 1.410663e-01 6.749654e-03 3.533523e-02 -6.000000e+00 6.367194e-02 226.80 -2.00 3.16 -2.00 501.98 0.00e+00 2.092 0.000 489.00 513.00 1 5.6263e+00 5.1845e-04 4.3610e-03 -6.0000e+00 4.8930e-03 1.1887e-02 1.3406e-04 8.7143e-04 -6.0000e+00 1.2757e-03 5.0957e-03 1.0699e-03 2.9467e-05 4.0419e-05 -6.0000e+00 2.9193e-04 3.4262e-03 -5.5991e-05 10 0 0 10 0 0 100.00 25.15 2.01 0.00343 0.01085 505 52 1 4 0 107.720 33.50 19.99 25.15 31.87 5.9 966.87 900000 -966 -598 -321 -44 353 452 554 430 277 334 19 -165 -322 -387 -418 -299 18 121 83 230 212 214 543 410 480 441 543 -198 -309 -535 -596 -498 78 -35 111 196 2 -128 -160 -95 -302 -79 205 355 423 478 348 218 -24 -272 -635 -778 -642 -338 -153 41 301 85 245 96 222 203 218 183 57 13 -90 -286 -426 -279 -198 -77 194 193 234 66 -35 -235 -445 -348 -432 -368 -270 -40 -87 -74 3 -101 -163 -12 271 414 286 410 454 190 -53 -354 -607 -783 -462 -219 155 -76 145 -91 -395 -272 -273 -355 -216 101 120 271 495 574 459 212 315 224 50 121 192 46 303 265 182 254 534 -41 -50 -91 -323 -494 -278 -246 -129 198 260 148 272 351 228 327 96 -132 -381 -447 -554 -322 900000 -959 -596 -326 -46 369 482 588 459 293 354 20 -171 -333 -397 -429 -309 18 126 89 246 226 229 579 432 508 465 578 -208 -318 -537 -608 -504 81 -37 118 207 2 -135 -166 -98 -314 -83 213 372 446 502 362 223 -25 -275 -623 -765 -629 -331 -152 42 307 87 249 98 226 208 224 187 58 14 -90 -282 -422 -272 -193 -75 190 192 231 65 -34 -226 -425 -332 -417 -358 -264 -39 -86 -73 3 -99 -160 -11 265 412 286 405 445 183 -51 -328 -563 -721 -429 -205 149 -75 144 -90 -386 -261 -262 -346 -214 100 118 269 492 574 456 211 313 219 49 116 185 45 295 258 177 246 516 -40 -48 -86 -304 -463 -262 -234 -124 191 254 144 265 343 224 322 94 -127 -366 -427 -525 -307 SQ 20241019T134517.1Z 9058.573115 309 1 3.81 2 60.74 119.84 90.87 295.78 0.00 1 0.00 1 0 15 3.312e-03 3.302e-03 3.539e-04 3.531e-04 5.673472e+03 2.264030e+01 3.867464e+02 -6.000000e+00 1.840362e+02 292.48 -2.00 20.00 -2.00 505.26 0.00e+00 6.418698e-04 9.805802e-06 4.217748e-05 -6.000000e+00 9.389308e-05 292.48 -2.00 20.00 -2.00 500.41 0.00e+00 1.264041e-01 6.828417e-03 3.445096e-02 -6.000000e+00 6.386310e-02 226.80 -2.00 3.16 -2.00 502.00 0.00e+00 2.037 0.000 489.00 513.00 1 3.0469e+00 5.2449e-04 4.2453e-03 -6.0000e+00 4.9079e-03 9.6002e-03 1.3568e-04 8.4676e-04 -6.0000e+00 1.2793e-03 6.7871e-02 7.5269e-04 2.9886e-05 3.9029e-05 -6.0000e+00 2.9282e-04 3.4467e-03 -4.2412e-05 12 1 1 12 1 1 94.24 25.15 1.95 0.00345 0.00867 71 55 1 4 0 52.940 33.50 20.00 25.15 32.03 5.9 968.12 900000 -929 -561 -368 -59 302 467 567 484 305 320 113 -192 -363 -408 -477 -304 0 93 100 256 252 289 569 387 502 405 497 -177 -324 -469 -564 -458 74 -48 82 212 16 -97 -177 -119 -262 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285 329 153 321 428 72 62 -7 -333 -427 -268 -299 -121 141 176 163 328 372 236 263 105 -235 -393 -394 -477 -301 SQ 20241019T134942.7Z 9058.576188 312 1 9.13 2 59.88 120.61 91.72 296.25 0.00 1 0.00 1 0 15 3.296e-03 3.286e-03 1.598e-04 1.594e-04 5.484671e+03 1.018064e+01 3.743577e+02 -6.000000e+00 1.831426e+02 292.48 -2.00 20.00 -2.00 505.26 0.00e+00 6.167575e-04 4.427669e-06 4.042044e-05 -6.000000e+00 9.343724e-05 292.48 -2.00 20.00 -2.00 500.42 0.00e+00 1.178246e-01 3.082980e-03 3.343262e-02 -6.000000e+00 6.355369e-02 226.80 -2.00 3.16 -2.00 502.01 0.00e+00 1.984 0.000 489.00 513.00 1 2.3499e+00 2.3676e-04 4.1246e-03 -6.0000e+00 4.8841e-03 7.7273e-03 6.1286e-05 8.2106e-04 -6.0000e+00 1.2731e-03 1.3746e-01 8.0102e-04 1.3507e-05 3.8020e-05 -6.0000e+00 2.9140e-04 2.4475e-03 -3.6845e-05 12 1 1 12 1 1 91.42 25.15 1.96 0.00245 0.00800 342 56 1 4 0 26.590 33.50 20.00 25.15 32.26 5.9 969.55 900000 -954 -584 -342 -58 349 441 575 425 282 305 131 -126 -348 -387 -432 -315 -16 78 115 255 264 233 564 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