File name: Pandora256s1_MiamiFL-FIU_20251013_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20251014T051501.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20251013_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20251013 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251013T114816.2Z 9417.491855 245 1 54.29 2 84.45 101.63 9.08 279.36 0.00 1 0.00 1 0 17 6.469e-01 3.127e-02 3.252e-01 1.052e-02 8.590363e-01 5.785090e-03 8.761377e-03 -6.000000e+00 3.685761e-01 227.10 -2.00 3.16 -2.00 322.06 0.00e+00 -2.379616e-02 3.383161e-03 2.739117e-03 -6.000000e+00 1.709172e-02 292.92 -2.00 20.00 -2.00 321.48 0.00e+00 9.051 0.007 302.00 328.00 3 3.9366e-01 2.4221e-02 1.0434e-01 -6.0000e+00 9.1175e-01 1.0620e+00 3.2317e-02 7.1028e-02 -6.0000e+00 9.9111e-01 -1.4238e+00 2.3581e-02 2.0497e-02 -6.0000e+00 5.9307e-01 5.5816e-01 1.0853e-02 2.0789e-02 -6.0000e+00 2.5331e-01 2.2876e-05 -5.3919e-04 2.8092e-04 2.5162e-04 -6.0000e+00 1.7476e-02 1.7826e-02 4.9420e-05 12 8 8 10 0 0 -22.07 24.68 1.30 0.01783 0.01377 38 4 1 5 0 1428.460 33.00 20.00 24.68 30.64 6.6 951.43 -28835 -33987 102879 283221 -87388 65772 -99145 -73291 -78952 -43069 -53368 -7611 81770 -43813 5113 56428 -23925 13929 60957 -30652 -36353 -70779 -46494 900000 -8926 -30786 150318 17505 77161 -7153 94911 121071 78682 77322 153146 900000 249172 149530 249633 87312 54012 138254 93595 261845 30092 36057 45249 61937 114081 13563 28351 38312 55617 2721 42362 44875 101809 59110 -54999 86139 1379 15717 6537 7357 -2728 27524 13716 6562 36751 15286 43180 13161 9321 14837 13949 9781 -5071 -8115 -8876 -9230 10191 -658 3842 4736 522 -1007 1786 824 -3170 5524 6125 825 849 572 -5007 1498 -2929 -3574 -2265 -6470 1156 -6369 -4820 3092 -4844 -6282 2170 2985 743 -1343 -86 2586 -1912 1451 -4064 447 -616 491 -996 304 1763 3117 3682 1543 -994 3671 -1080 613 707 -1733 -439 118 202 -1796 820 607 2150 1775 -780 -357 50 -1537 -2297 -726 -919 1055 2904 -2770 674 -3790 -2596 -3459 -1445 -2040 -192 915 -1879 148 1052 -1026 416 1137 -1400 -1694 -4487 -2471 900000 -441 -2009 1696 646 1345 -279 1460 1614 1775 1824 1570 900000 2555 1993 2560 3313 3212 3686 3839 2685 2037 2182 2413 2795 3159 1099 2210 3025 4049 368 4170 4602 6160 5395 -14607 5123 185 1934 985 1230 -529 3867 2222 1211 5653 3370 7926 3387 2437 3408 2889 1866 -1050 -1781 -2221 -2764 2968 -248 1537 2011 248 -516 930 442 -1749 2668 2745 371 381 276 -2937 966 -2303 -2965 -2027 -6055 1035 -5525 -3766 2258 -4133 -5765 1945 2884 748 -1593 -115 3636 -2887 2093 -5970 611 -864 714 -1558 483 2699 4498 5108 2131 -1368 4698 -1427 859 1149 -3332 -854 247 455 -4452 2138 1670 5946 4991 -2224 -960 124 -3623 -5300 SS 20251013T115926.4Z 9417.499611 248 1 54.33 2 81.99 102.91 11.50 278.33 0.00 1 0.00 1 0 17 5.389e-01 1.248e-02 5.310e-02 2.047e-03 6.948376e-01 1.076485e-03 7.322860e-03 -6.000000e+00 3.064210e-01 227.10 -2.00 3.16 -2.00 320.95 0.00e+00 5.848213e-04 5.102988e-04 3.268847e-03 -6.000000e+00 1.417654e-02 292.92 -2.00 20.00 -2.00 320.23 0.00e+00 6.701 0.003 302.00 328.00 3 3.3219e-01 3.6807e-03 7.5364e-02 -6.0000e+00 7.5730e-01 1.6484e-01 4.9429e-03 3.9293e-02 -6.0000e+00 8.2199e-01 -2.5288e-01 4.5147e-03 1.7377e-02 -6.0000e+00 4.9306e-01 9.8393e-02 2.1810e-03 4.7122e-03 -6.0000e+00 2.1090e-01 2.7486e-04 -3.6458e-04 5.3919e-05 6.7451e-05 -6.0000e+00 1.4553e-02 1.7951e-02 2.5759e-05 12 8 8 10 0 0 67.17 24.68 0.51 0.01795 0.01521 167 17 1 5 0 325.290 33.00 20.00 24.68 31.18 6.6 954.92 -172476 -159651 -182830 -175368 -185697 -156731 -184658 -171741 -170823 -157311 -145912 -142162 -120659 -89844 -78118 -31961 -47695 -56859 -27921 -63687 -58428 -58260 -44991 -4838 -45343 -35967 -8740 -38027 -28922 -28156 -19026 -3167 4217 307 413 -767 -3567 39 8883 9619 7297 13754 9662 14951 5247 4842 6178 6682 5868 3679 3734 9924 6160 7731 7644 6485 8931 3281 -5657 5084 -703 2662 4667 4091 3915 2456 1954 1576 3370 2639 4650 1620 1833 1491 -634 -95 -3406 -3309 -2844 -2082 -1657 -1714 -1815 -1298 -1219 -189 446 767 657 1367 68 -253 -1188 -1449 -1331 -469 132 -174 -596 -752 -647 -1647 -1339 -507 -1761 -1608 -1234 -552 -18 677 572 595 178 532 -531 -8 -148 55 471 156 551 915 1064 566 623 406 -22 945 605 -2 -91 -128 -376 -188 55 -316 490 477 -1 -61 -366 -631 -614 -1847 -1944 -3029 -2626 -2817 -1752 -2986 -2811 -3171 -2795 -2447 -2611 -2264 -1596 -1559 -485 -962 -1396 -557 -1920 -1715 -1710 -1221 -98 -1503 -1156 -218 -1230 -837 -877 -649 -111 161 13 17 -32 -168 2 550 714 629 1200 924 1388 543 514 664 743 695 482 549 1549 1103 1494 1581 1425 1983 699 -1278 1113 -153 621 1222 1220 1237 775 617 522 1225 1120 2139 735 894 688 -272 -36 -1271 -1268 -1233 -1072 -917 -1091 -1272 -891 -897 -147 363 640 548 1089 51 -180 -900 -1065 -1108 -452 137 -194 -725 -915 -736 -1826 -1361 -519 -1970 -1776 -1440 -690 -23 982 869 959 290 836 -801 -12 -218 84 771 266 920 1464 1644 850 958 605 -32 1451 1000 -4 -169 -254 -753 -400 120 -725 1139 1128 -3 -138 -819 -1334 -1269 SS 20251013T121426.3Z 9417.510026 253 1 54.37 2 78.71 104.68 14.77 277.80 0.00 1 0.00 1 0 17 1.837e-01 7.957e-03 1.053e-02 6.917e-04 5.399448e-01 3.509152e-04 5.665420e-03 -6.000000e+00 1.044492e-01 227.09 -2.00 3.16 -2.00 319.56 0.00e+00 1.209975e-03 1.039833e-04 9.930922e-04 -6.000000e+00 4.831521e-03 292.92 -2.00 20.00 -2.00 318.69 0.00e+00 4.930 0.001 302.00 328.00 3 1.8665e-01 1.0117e-03 5.4849e-02 -6.0000e+00 2.5814e-01 2.4256e-02 1.2142e-03 2.5623e-02 -6.0000e+00 2.8018e-01 -4.9914e-02 9.5484e-04 1.2503e-02 -6.0000e+00 1.6806e-01 1.5419e-02 5.0105e-04 3.4888e-03 -6.0000e+00 7.1899e-02 1.9457e-03 -1.6748e-04 1.8834e-05 3.9658e-05 -6.0000e+00 4.9597e-03 1.7057e-02 3.4186e-05 11 8 0 10 0 0 28.66 24.66 0.45 0.01706 0.01580 497 51 1 5 0 109.390 32.75 19.99 24.66 32.22 6.6 962.18 -67712 -51761 -61637 -55659 -71381 -69323 -69011 -60858 -51275 -47249 -49545 -46214 -36576 -24170 -19204 -13184 -11265 -12068 -8831 -10140 -9182 -11808 -9218 -8701 -7419 -6422 -5207 -8081 -10173 -7614 -4574 -1001 127 -1867 -3747 -5942 -4574 -2937 734 1229 963 2692 1704 2316 1537 1638 1109 702 1044 1205 1589 1624 2588 2158 2403 1874 1880 1004 -283 1112 1134 2146 2776 2933 1462 1131 68 -319 854 1231 1107 678 367 336 -347 -859 -1748 -2234 -2150 -1660 -1568 -1844 -2339 -1859 -1322 -611 -36 382 581 824 462 32 -439 -422 -236 44 466 584 -25 -208 -626 -1080 -631 -391 -1062 -1087 -785 -367 280 548 661 481 374 153 -145 175 172 297 200 -40 60 396 556 517 487 138 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