File name: Pandora256s1_MiamiFL-FIU_20251219_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20251220T052206.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20251219_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20251219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251219T124441.3Z 9484.531034 56 1 54.08 2 82.53 120.55 81.00 127.96 0.00 1 0.00 1 0 17 6.069e-01 2.077e-02 2.009e-01 5.470e-03 7.031377e-01 2.920993e-03 7.135526e-03 -6.000000e+00 3.428381e-01 224.50 -2.00 3.16 -2.00 321.41 0.00e+00 -1.081952e-02 1.558177e-03 5.674871e-03 -6.000000e+00 1.625195e-02 288.69 -2.00 20.00 -2.00 320.78 0.00e+00 7.121 0.003 302.00 328.00 3 1.5867e+00 1.0757e-02 8.7290e-02 -6.0000e+00 8.4401e-01 2.8437e-01 1.5101e-02 6.6788e-02 -6.0000e+00 9.1916e-01 -4.7770e-01 1.3991e-02 1.8273e-02 -6.0000e+00 5.5199e-01 1.9620e-01 6.4637e-03 1.4271e-02 -6.0000e+00 2.3744e-01 5.4041e-05 -5.0574e-04 1.5284e-04 9.1560e-05 -6.0000e+00 1.6671e-02 1.7267e-02 7.0908e-05 12 8 8 10 0 0 63.28 26.27 0.70 0.01727 0.01347 46 5 1 5 0 1175.460 34.75 20.00 26.27 29.11 6.8 941.26 -121072 -99518 900000 900000 -173529 -96533 -120585 -147096 -186261 -129603 -59490 -98487 -87440 -155184 -45871 900000 -12915 -59086 26011 47905 -60417 -79958 -34808 900000 -75763 -30439 55553 -45237 13893 -17089 53358 30674 182988 44296 56157 423803 42861 45322 77197 20109 15992 56772 60722 98177 12343 -889 27980 19376 33757 10788 8644 18699 25357 14511 12825 5557 32740 23371 -31507 29422 5818 979 10402 4055 3387 7169 4707 1998 8527 56 8940 7033 786 827 -1008 -1865 2814 -6750 -3032 -2877 1809 -4817 2377 -303 -612 106 182 1487 -1933 2694 1066 -540 -1545 -1107 -3160 1025 -1841 -1334 -1668 -4105 280 -2475 -3488 595 -3465 -1856 276 1113 1582 -116 65 1908 126 1104 -1771 247 701 1067 182 199 557 1782 1351 89 -181 1505 -232 46 772 -914 -148 189 -516 -1051 44 -21 968 1021 418 177 -465 -1037 -992 -1232 -916 900000 900000 -2943 -748 -1344 -2566 -5686 -2512 -666 -1785 -1678 -7031 -831 900000 -213 -1669 333 511 -1932 -3111 -928 900000 -3998 -1103 859 -1784 281 -483 853 719 1073 1110 1197 2259 1142 1425 2222 1254 1185 2996 3172 3506 1020 -83 1969 1518 2393 1035 949 2093 2933 2057 1996 989 4642 3637 -8145 3968 1002 192 2101 981 868 1735 1162 530 2373 20 3183 2673 315 312 -353 -589 793 -2134 -1038 -1168 824 -2455 1246 -174 -380 70 126 1044 -1399 1790 673 -327 -922 -690 -2275 823 -1764 -1336 -1823 -4597 282 -2520 -3304 549 -3605 -2015 285 1230 1925 -162 93 2876 195 1646 -2587 369 1056 1553 283 322 885 2696 1988 140 -275 2172 -333 70 1220 -1668 -296 374 -1089 -2383 106 -51 2322 2490 1019 415 -1098 -2321 -2165 SS 20251219T125506.7Z 9484.538272 59 1 54.23 2 80.52 121.87 79.23 129.33 0.00 1 0.00 1 0 17 3.301e-01 9.155e-03 4.679e-02 1.833e-03 5.946510e-01 9.385133e-04 6.273818e-03 -6.000000e+00 1.858784e-01 224.50 -2.00 3.16 -2.00 320.41 0.00e+00 1.062353e-03 3.724739e-04 2.079563e-03 -6.000000e+00 8.527277e-03 288.69 -2.00 20.00 -2.00 319.68 0.00e+00 5.782 0.002 302.00 328.00 3 1.1667e+00 2.9420e-03 6.4028e-02 -6.0000e+00 4.5735e-01 3.9963e-02 3.7547e-03 3.0502e-02 -6.0000e+00 4.9770e-01 -8.5147e-02 3.3531e-03 1.4719e-02 -6.0000e+00 2.9836e-01 2.7196e-02 1.6784e-03 3.9947e-03 -6.0000e+00 1.2777e-01 3.1439e-04 -3.4391e-04 5.0086e-05 5.4336e-05 -6.0000e+00 8.9073e-03 1.7225e-02 3.0782e-05 11 8 0 10 0 0 96.70 26.27 0.58 0.01723 0.01464 132 14 1 5 0 410.770 34.75 20.00 26.27 29.82 6.8 944.73 -126153 -96948 -68402 -79806 -113175 -80794 -130034 -106738 -112189 -104062 -90037 -97761 -59688 -84639 -45312 -26728 -31280 -31539 -17477 -27877 -28750 -42043 -31504 -2160 -26335 -24195 993 -24383 -13225 -18640 5243 -2409 1112 -4614 -1954 -1514 -2768 -2095 4976 3256 300 6869 3847 10925 716 1887 5680 1941 3254 1302 1544 4898 3800 3460 1602 2132 4614 2225 -5329 3864 411 1850 2477 3727 1663 2505 117 -717 1324 1449 1982 1338 617 191 -643 -1127 -1190 -2417 -2855 -1500 -1385 -2068 -1529 -1263 -1020 -488 156 470 203 797 702 -325 -447 -571 -558 74 268 514 -485 -568 -255 -1448 -984 -141 -1341 -1373 -602 -125 485 590 486 832 300 129 -452 59 170 282 266 92 60 842 751 278 427 153 -258 439 302 -167 -308 -342 -243 -234 -52 -46 355 526 133 -105 -112 -471 -394 -1646 -1109 -636 -813 -1477 -751 -2162 -1622 -2066 -1935 -1529 -2010 -1046 -2421 -1094 -640 -883 -987 -515 -967 -1038 -1744 -1239 -70 -1186 -1138 37 -1138 -539 -856 223 -131 68 -320 -127 -97 -200 -180 492 395 42 979 595 1615 119 316 935 342 590 234 308 1057 910 906 455 630 1375 679 -1709 1115 127 623 941 1437 685 995 47 -298 597 753 1133 805 370 109 -340 -538 -531 -1105 -1466 -899 -893 -1531 -1144 -1002 -867 -441 147 457 198 743 611 -267 -353 -466 -510 72 302 618 -599 -698 -311 -1615 -1078 -156 -1525 -1654 -761 -159 670 859 779 1323 477 208 -692 86 251 438 415 151 97 1314 1200 431 635 220 -383 642 497 -294 -561 -660 -468 -479 -109 -102 761 1146 290 -230 -232 -976 -798 SS 20251219T130347.2Z 9484.544297 64 1 54.44 2 78.88 123.00 77.78 130.51 0.00 1 0.00 1 0 17 1.874e-01 7.673e-03 1.735e-02 1.071e-03 5.253352e-01 5.395079e-04 5.533955e-03 -6.000000e+00 1.055202e-01 224.50 -2.00 3.16 -2.00 319.69 0.00e+00 1.468593e-03 1.654491e-04 9.359329e-04 -6.000000e+00 4.840803e-03 288.69 -2.00 20.00 -2.00 318.90 0.00e+00 4.999 0.001 302.00 328.00 3 1.0105e+00 1.5581e-03 5.5057e-02 -6.0000e+00 2.5963e-01 6.6992e-03 1.8782e-03 2.4702e-02 -6.0000e+00 2.8253e-01 -4.3169e-02 1.5299e-03 1.2291e-02 -6.0000e+00 1.6937e-01 1.1545e-02 7.9868e-04 3.6236e-03 -6.0000e+00 7.2534e-02 8.2169e-04 -2.7687e-04 2.9610e-05 4.2661e-05 -6.0000e+00 5.0565e-03 1.7184e-02 2.9213e-05 11 8 0 10 0 0 93.16 26.26 0.50 0.01718 0.01510 238 24 1 5 0 228.700 34.75 20.00 26.26 30.33 6.8 949.23 -70864 -59268 -55030 -39426 -73350 -71767 -65745 -58239 -57718 -54545 -53597 -49374 -35016 -35132 -20917 -13665 -15000 -13189 -5618 -11785 -9257 -15356 -11632 -3095 -9500 -11863 -1115 -10655 -8498 -7261 -2392 -441 1935 -2280 -2323 -3343 -3703 -996 2157 519 -157 2847 2048 3213 929 1429 1730 834 1082 566 1052 2165 2239 2168 1639 1897 2528 1170 -1295 1501 687 2127 2867 2637 1579 740 66 -309 662 1077 912 789 193 138 -372 -606 -1798 -2391 -1974 -1537 -1437 -1720 -1933 -1774 -1202 -702 94 532 536 756 488 73 -370 -490 -65 107 489 655 133 -356 -594 -1098 -697 -161 -1184 -1079 -757 -384 109 535 680 591 346 98 -144 -25 186 124 138 97 41 507 555 410 379 320 106 706 190 119 -156 -218 -220 -119 -105 -145 362 300 25 -115 -262 -398 -388 -1244 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