File name: Pandora256s1_MiamiFL-FIU_20260105_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20260106T053220.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20260105_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20260105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260105T124031.0Z 9501.528137 255 1 55.27 2 84.51 118.33 72.40 282.62 0.00 1 0.00 1 0 25 6.488e-01 5.004e-02 2.711e-01 1.380e-02 9.573489e-01 7.807645e-03 1.285637e-02 -6.000000e+00 3.753961e-01 224.40 -2.00 3.16 -2.00 322.08 0.00e+00 -4.949014e-02 3.697156e-03 1.553296e-03 -6.000000e+00 1.832707e-02 288.10 -2.00 20.00 -2.00 321.44 0.00e+00 9.148 0.007 302.00 328.00 3 5.8177e-01 2.9525e-02 1.1546e-01 -6.0000e+00 9.2771e-01 1.4749e+00 3.7560e-02 1.0783e-01 -6.0000e+00 1.0190e+00 -1.9275e+00 2.4063e-02 2.3388e-02 -6.0000e+00 6.0373e-01 7.4238e-01 1.1765e-02 4.1366e-02 -6.0000e+00 2.5492e-01 1.4966e-05 -2.1493e-03 3.6787e-04 5.4427e-04 -6.0000e+00 1.8591e-02 1.9859e-02 -1.6049e-05 12 9 8 11 32 0 65.13 26.03 1.32 0.01986 0.00371 29 3 1 5 0 1905.780 34.75 19.99 26.03 25.38 6.9 917.03 151644 29311 104165 900000 -48402 900000 -30475 -9611 20260 43755 203327 48956 31673 -26912 71979 900000 26799 18287 900000 900000 -43067 -52108 -30692 900000 73192 11783 900000 -18417 147908 1757 900000 325716 171489 81208 900000 900000 71593 900000 213928 80079 36304 234943 900000 900000 47558 69532 86460 112718 133427 58009 13198 59387 125805 52601 85378 12868 128433 67899 -71767 136781 4994 8996 911 3510 -1296 39312 26549 14886 31585 9452 62209 15505 7937 10092 78 7501 13356 -19531 -24495 -905 46021 -6709 18624 8362 215 7500 7009 221 -1890 8338 1869 -2096 9157 2163 -11450 10708 -1177 908 -1914 -10139 5170 -6760 -12228 11379 -10208 -662 8785 5449 9844 -2907 -7770 8574 -975 4631 -5176 1988 523 1825 -475 -1187 1449 -4949 7059 1927 63 3970 -2631 -796 2448 -4811 -116 372 -838 -2919 407 195 3067 2312 -337 231 351 -630 -2466 2405 1466 2161 900000 -3012 900000 -1859 -633 1261 2509 2729 2748 2009 -2889 2810 900000 1569 1116 900000 900000 -4099 -5213 -2771 900000 3840 1265 900000 -2022 2346 103 900000 4371 2302 2725 900000 900000 2498 900000 2871 5159 4142 3784 900000 900000 3574 3733 3597 3479 3402 3348 1329 4224 5065 4871 6302 2159 7240 6926 -26777 5507 684 1195 143 594 -240 4749 3670 2477 5044 2182 9351 3871 2088 2397 18 1409 2187 -4509 -6608 -227 8524 -2458 5949 3187 95 3271 3189 109 -931 3514 782 -875 3441 943 -6592 5763 -826 716 -1701 -9838 4045 -5353 -9289 6842 -8206 -513 6556 4563 8878 -3146 -10163 10471 -1364 6125 -7325 2542 684 2453 -687 -1772 2048 -7076 8621 2420 79 5110 -3559 -1034 3602 -8863 -230 805 -1978 -6997 1022 519 8065 6183 -912 587 894 -1494 -5739 SS 20260105T125210.5Z 9501.536233 258 1 54.42 2 82.22 119.74 74.89 283.62 0.00 1 0.00 1 0 17 6.037e-01 1.543e-02 1.007e-01 2.612e-03 7.681365e-01 1.376180e-03 8.065562e-03 -6.000000e+00 3.397821e-01 224.40 -2.00 3.16 -2.00 321.29 0.00e+00 4.771727e-04 7.150666e-04 4.361852e-03 -6.000000e+00 1.555756e-02 288.10 -2.00 20.00 -2.00 320.68 0.00e+00 6.876 0.003 302.00 328.00 3 5.1246e-01 4.9109e-03 7.9967e-02 -6.0000e+00 8.3601e-01 2.7586e-01 6.8459e-03 4.7069e-02 -6.0000e+00 9.0997e-01 -4.1767e-01 6.5799e-03 2.1169e-02 -6.0000e+00 5.4535e-01 1.6745e-01 3.0850e-03 5.4916e-03 -6.0000e+00 2.3341e-01 1.7659e-04 -6.5767e-04 6.7374e-05 8.8470e-05 -6.0000e+00 1.6291e-02 1.8275e-02 2.8330e-05 12 8 8 10 0 0 12.45 26.03 0.68 0.01827 0.01333 137 14 1 5 0 397.150 34.75 20.00 26.03 26.08 6.8 921.25 -143836 -186366 -179305 -64848 -234484 -206142 -201461 -154910 -202973 -184971 -157706 -154147 -139994 -148076 -96621 -10697 -85656 -67414 -34984 -51516 -83916 -96612 -85365 64390 -61151 -67864 16361 -54129 -47034 -26110 -12807 2004 12420 -3394 21679 34762 -1237 15803 22870 3960 12990 31072 17669 39158 7711 9432 15072 20643 16224 9261 7093 15788 15858 10468 12371 8794 13123 6395 -13218 12723 1717 6046 7037 7466 6564 6840 4014 4090 3896 3399 4732 3816 2720 1235 1282 -964 -340 -4333 -5268 -1837 -1349 -1459 -705 -1505 -486 -339 547 395 515 1347 511 -151 -885 -1213 -1233 -642 -828 221 -1212 -1306 -844 -2435 -2195 -605 -2408 -2148 -1220 -487 731 -45 -453 900 -133 262 -539 196 -77 293 369 562 440 1515 1503 1179 239 943 94 863 382 -124 255 -109 -335 -68 112 -207 603 539 23 -196 -465 -824 -850 -966 -2244 -2159 -240 -4290 -3046 -3079 -1697 -4084 -3392 -2330 -2513 -2532 -3772 -1870 -106 -2051 -1494 -606 -1102 -2522 -3273 -2718 508 -1854 -2334 246 -1586 -1258 -619 -323 53 348 -120 574 797 -45 576 961 243 827 1781 1215 2214 601 738 1144 1551 1356 904 799 1846 2052 1571 1951 1510 2230 1155 -2798 2022 313 1169 1552 1873 1772 1828 1109 1081 1156 1174 1782 1511 1071 462 434 -299 -99 -1365 -1921 -781 -676 -846 -411 -944 -323 -240 402 299 387 966 345 -97 -563 -820 -955 -538 -814 249 -1402 -1513 -911 -2575 -2111 -577 -2517 -2373 -1418 -565 936 -62 -702 1381 -210 426 -843 295 -118 470 587 920 706 2455 2349 1791 354 1343 132 1287 618 -231 492 -227 -704 -153 254 -497 1462 1327 56 -458 -1076 -1793 -1800 SS 20260105T130930.8Z 9501.548273 263 1 54.45 2 78.87 121.96 78.58 285.14 0.00 1 0.00 1 0 17 2.664e-01 8.677e-03 1.450e-02 7.954e-04 5.893078e-01 4.029696e-04 6.184757e-03 -6.000000e+00 1.499588e-01 224.40 -2.00 3.16 -2.00 319.87 0.00e+00 1.290405e-03 1.333964e-04 1.268255e-03 -6.000000e+00 6.864770e-03 288.10 -2.00 20.00 -2.00 319.12 0.00e+00 4.996 0.001 302.00 328.00 3 3.5717e-01 1.1815e-03 5.6481e-02 -6.0000e+00 3.6896e-01 3.1580e-02 1.4407e-03 2.7859e-02 -6.0000e+00 4.0158e-01 -6.8857e-02 1.2139e-03 1.3863e-02 -6.0000e+00 2.4067e-01 2.3513e-02 6.2969e-04 3.9794e-03 -6.0000e+00 1.0303e-01 1.4498e-03 -1.5038e-04 2.1262e-05 4.8228e-05 -6.0000e+00 7.1882e-03 1.7472e-02 4.7531e-05 11 8 0 10 0 0 46.05 26.01 0.47 0.01747 0.01634 429 44 1 5 0 126.910 34.50 20.00 26.01 27.19 6.9 928.89 -86826 -88662 -70199 -93094 -97071 -91397 -99352 -94519 -79107 -79504 -71582 -61011 -48057 -48119 -31516 -20261 -20841 -19504 -16410 -17237 -15792 -17392 -17922 -8794 -13149 -10692 -8372 -13333 -12760 -11634 -5763 -2277 -303 -2958 -6539 -4540 -4494 -1582 1826 1943 2228 1877 2516 3195 2655 2500 2672 695 2177 742 2313 2973 3013 2869 2533 2121 2234 1241 -715 1212 912 2188 2560 3093 1622 1167 241 77 1139 1229 1285 1058 505 313 -389 -963 -1611 -2558 -2372 -1622 -1380 -1771 -2228 -1894 -1130 -655 -32 367 596 667 741 21 -238 -327 -568 -135 266 512 79 -268 -576 -1116 -903 -495 -1112 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