File name: Pandora138s1_Milan-MIBI_20250804_L2Fit_fwvt1c22d20250714p1-8.txt File generation date: 20250910T094429.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20250804_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20250804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1629 1778 Nominal wavelengths inside fitting window [nm]: 492.1148 492.2359 492.3571 492.4782 492.5993 492.7204 492.8415 492.9625 493.0836 493.2046 493.3256 493.4466 493.5676 493.6885 493.8095 493.9304 494.0513 494.1722 494.2931 494.4139 494.5347 494.6556 494.7764 494.8972 495.0179 495.1387 495.2594 495.3801 495.5008 495.6215 495.7422 495.8629 495.9835 496.1041 496.2247 496.3453 496.4659 496.5864 496.7070 496.8275 496.9480 497.0685 497.1889 497.3094 497.4298 497.5502 497.6706 497.7910 497.9114 498.0317 498.1520 498.2724 498.3927 498.5129 498.6332 498.7534 498.8737 498.9939 499.1141 499.2343 499.3544 499.4746 499.5947 499.7148 499.8349 499.9550 500.0750 500.1951 500.3151 500.4351 500.5551 500.6751 500.7950 500.9150 501.0349 501.1548 501.2747 501.3946 501.5144 501.6343 501.7541 501.8739 501.9937 502.1134 502.2332 502.3529 502.4726 502.5923 502.7120 502.8317 502.9514 503.0710 503.1906 503.3102 503.4298 503.5493 503.6689 503.7884 503.9079 504.0274 504.1469 504.2664 504.3858 504.5052 504.6247 504.7440 504.8634 504.9828 505.1021 505.2215 505.3408 505.4600 505.5793 505.6986 505.8178 505.9370 506.0562 506.1754 506.2946 506.4138 506.5329 506.6520 506.7711 506.8902 507.0093 507.1283 507.2473 507.3664 507.4854 507.6043 507.7233 507.8422 507.9612 508.0801 508.1990 508.3179 508.4367 508.5556 508.6744 508.7932 508.9120 509.0308 509.1495 509.2683 509.3870 509.5057 509.6244 509.7430 509.8617 509.9803 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250804T042039.0Z 9347.181007 34 1 16.48 2 89.26 65.91 143.01 284.76 0.00 1 0.00 1 0 22 5.805e-03 5.748e-03 5.680e-04 5.659e-04 2.895318e+04 4.765905e+01 1.804880e+03 -6.000000e+00 3.500606e+02 286.29 -2.00 20.00 -2.00 505.46 0.00e+00 5.005619e-03 1.649486e-05 2.881268e-04 -6.000000e+00 1.690040e-04 286.29 -2.00 20.00 -2.00 501.00 0.00e+00 1.648496e+00 1.138760e-02 1.781265e-01 -6.000000e+00 1.191353e-01 232.49 -2.00 3.61 -2.00 502.50 0.00e+00 19.099 0.140 489.00 513.00 1 3.4450e+00 8.7544e-04 3.7244e-02 -6.0000e+00 9.1911e-03 -4.9446e-02 2.1134e-04 4.7646e-03 -6.0000e+00 2.3195e-03 3.3877e-03 2.2100e-03 5.6720e-05 1.6900e-04 -6.0000e+00 7.4488e-04 -5.5795e-03 2.9584e-05 12 9 9 12 1 1 -40.42 17.51 2.74 -0.00558 0.00975 42 28 4 2 0 383.060 14.99 17.51 24.31 20.77 21.69 21.8 1001.16 -1317 -759 -226 100 411 827 971 801 494 245 48 -374 -638 -614 -374 -330 -168 185 293 118 418 486 412 781 587 380 164 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-754 -653 -403 -601 -349 -371 -378 -202 100 -72 34 534 1163 1377 1445 1559 709 24 -33 157 262 617 760 705 618 402 -1 36 -58 -727 -592 -311 -629 -554 -97 -162 11 326 473 256 364 368 379 387 -59 -378 -660 -766 -716 SQ 20250804T042528.3Z 9347.184356 40 1 43.28 2 88.49 66.77 143.79 285.86 0.00 1 0.00 1 0 22 4.320e-03 4.277e-03 2.721e-04 2.713e-04 2.584470e+04 2.248851e+01 1.609240e+03 -6.000000e+00 2.605120e+02 286.29 -2.00 20.00 -2.00 505.45 0.00e+00 4.127092e-03 7.898488e-06 2.459086e-04 -6.000000e+00 1.257549e-04 286.29 -2.00 20.00 -2.00 500.97 0.00e+00 1.521869e+00 5.461572e-03 1.638739e-01 -6.000000e+00 8.859077e-02 232.49 -2.00 3.61 -2.00 502.48 0.00e+00 17.244 0.103 489.00 513.00 1 3.2562e+00 4.2021e-04 3.2024e-02 -6.0000e+00 6.8354e-03 -4.4088e-02 1.0148e-04 4.2989e-03 -6.0000e+00 1.7234e-03 5.4474e-03 3.4908e-04 2.7969e-05 1.4674e-04 -6.0000e+00 5.5412e-04 -1.2647e-03 5.9299e-05 11 8 0 10 0 0 98.29 17.51 1.95 -0.00126 0.00116 201 50 4 2 0 215.320 14.99 17.51 24.41 20.77 21.69 21.8 1001.57 -780 -424 -47 173 357 663 791 665 434 211 153 -215 -509 -409 -244 -247 -151 124 140 10 278 397 384 581 416 201 24 -263 -699 -528 -146 -275 -135 189 -65 -320 -49 36 -48 48 220 328 369 458 442 288 80 39 -292 -585 -713 -550 -515 -293 -7 -8 91 252 434 561 682 586 390 328 158 -6 -93 -205 -489 -530 -350 -395 -409 -331 -441 -717 -671 -472 -497 -512 -238 -131 -294 -217 -193 -401 -345 -31 326 576 593 597 489 242 407 395 -10 -290 -728 -1072 -852 -602 -517 -508 -625 -443 -345 -262 -29 149 -47 -81 452 874 954 1105 1039 525 -10 23 99 236 572 647 459 474 262 -53 35 -1 -552 -437 -263 -484 -458 0 -98 -16 331 265 146 269 297 339 259 46 -186 -417 -406 -479 -702 -389 -44 162 343 629 760 643 419 203 144 -209 -489 -391 -233 -232 -144 120 139 10 271 388 378 574 413 200 23 -258 -674 -516 -142 -271 -131 188 -66 -319 -49 36 -49 49 218 328 374 470 456 298 83 40 -293 -576 -710 -542 -509 -294 -7 -8 92 256 442 573 699 603 402 337 161 -6 -95 -208 -493 -531 -350 -397 -415 -337 -448 -725 -670 -464 -483 -496 -231 -127 -289 -215 -193 -403 -346 -30 322 568 587 590 479 233 388 363 -9 -260 -647 -959 -777 -552 -497 -496 -613 -442 -346 -264 -29 151 -47 -82 454 880 969 1135 1083 540 -10 24 102 240 576 652 466 484 269 -55 36 -1 -565 -445 -267 -495 -475 0 -102 -18 348 283 158 293 317 370 282 50 -199 -445 -434 -517 SQ 20250804T043611.0Z 9347.191794 52 1 42.95 2 86.75 68.65 145.51 288.43 0.00 1 0.00 1 0 22 2.686e-03 2.675e-03 5.601e-04 5.592e-04 1.822459e+04 4.397966e+01 1.160703e+03 -6.000000e+00 1.619665e+02 286.29 -2.00 20.00 -2.00 505.38 0.00e+00 2.710522e-03 1.616118e-05 1.666479e-04 -6.000000e+00 7.819234e-05 286.29 -2.00 20.00 -2.00 500.79 0.00e+00 1.194662e+00 1.132260e-02 1.186022e-01 -6.000000e+00 5.510454e-02 232.49 -2.00 3.61 -2.00 502.33 0.00e+00 12.926 0.043 489.00 513.00 1 5.3528e+00 8.7152e-04 2.2008e-02 -6.0000e+00 4.2514e-03 -2.0469e-02 2.1321e-04 3.0580e-03 -6.0000e+00 1.0725e-03 1.2956e-03 4.2215e-04 6.1704e-05 1.0793e-04 -6.0000e+00 3.4460e-04 4.1197e-03 -5.5625e-06 10 0 0 10 0 0 95.92 17.51 0.90 0.00412 0.00705 32 8 1 2 0 1342.080 15.00 17.51 24.78 20.77 21.69 21.5 1002.52 -62 -36 252 81 152 306 394 343 240 213 231 17 -183 -191 140 -26 -26 78 -138 -14 242 285 148 424 136 27 -13 -284 -604 -191 210 -92 -189 107 -79 -365 -108 100 -33 99 289 120 94 100 176 -28 -44 -16 -339 -391 -382 -163 -222 -163 -72 -209 -89 55 194 302 396 256 202 162 138 -2 -23 3 -240 -253 -155 -166 -379 -222 -408 -610 -325 -102 -193 -391 -224 -275 -299 -224 -108 -328 -260 51 174 354 318 393 70 4 77 256 72 -69 -297 -468 -493 -507 -559 -469 -693 -397 -274 -75 41 318 70 59 224 612 669 700 580 367 -51 170 322 227 477 320 211 155 66 32 -18 33 -384 -120 103 -221 -202 186 -155 -96 151 258 20 189 231 71 121 -101 -164 -113 -80 -173 -57 -34 242 78 151 300 391 342 239 210 225 17 -180 -186 136 -26 -26 78 -140 -14 241 286 150 428 138 27 -13 -282 -606 -188 205 -92 -187 108 -81 -377 -111 102 -33 101 293 123 95 103 181 -29 -45 -16 -345 -390 -373 -162 -221 -160 -72 -209 -91 56 200 311 409 266 210 168 142 -2 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