File name: Pandora138s1_Milan-MIBI_20251026_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20251026T231317.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20251026_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20251026 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251026T071340.0Z 9430.301157 79 1 45.50 2 78.25 121.91 125.54 96.86 0.00 1 0.00 1 0 25 4.183e-01 1.258e-02 1.898e-01 4.988e-03 6.046575e-01 2.601123e-03 7.085737e-03 -6.000000e+00 2.381769e-01 224.16 -2.00 3.61 -2.00 320.54 0.00e+00 3.335026e-03 8.692537e-04 4.635566e-04 -6.000000e+00 1.060602e-02 278.63 -2.00 20.00 -2.00 320.24 0.00e+00 4.757 0.002 302.00 328.00 3 3.7505e+00 7.4464e-03 5.6504e-02 -6.0000e+00 5.9252e-01 1.3225e-01 9.5152e-03 3.2413e-02 -6.0000e+00 6.4708e-01 -8.3117e-02 1.0429e-02 1.7586e-02 -6.0000e+00 3.8015e-01 2.4088e-02 5.4303e-03 5.7137e-03 -6.0000e+00 1.6178e-01 5.8890e-05 -6.3728e-04 1.4325e-04 6.5299e-05 -6.0000e+00 1.1775e-02 -9.3814e-03 0.0000e+00 12 9 9 12 1 1 99.72 19.10 0.14 -0.00938 -0.01417 18 5 2 8 0 2394.250 15.00 19.10 14.68 22.29 21.98 21.3 938.53 900000 203018 -80357 -81968 900000 -132071 208096 -97474 -133220 900000 -109200 900000 -68080 -26352 793 90908 -16954 -7260 46525 171611 5431 91321 -48942 -17280 37933 -32500 -43285 20463 37399 -18572 -7702 97377 12142 7196 -11365 24191 27734 -834 9543 -27100 8010 808 5195 6248 18030 8086 -3672 7176 4212 -2354 1751 -20880 6815 8102 8352 632 5192 3941 4360 -343 3978 -924 2206 245 2037 2788 -333 -1243 133 1353 1041 2842 -1010 2134 80 -2670 -450 709 -1967 -3755 -2289 -2527 -1168 -664 -3013 -856 243 -303 -467 3454 562 3566 -2849 1004 -343 25 1136 256 798 65 641 -826 2 -179 -1449 -1505 -1241 -995 -187 893 485 288 -965 8 -188 76 580 43 669 -585 -236 -87 617 256 -497 286 -232 1626 660 689 144 670 -734 301 -714 -349 -116 679 5 -125 8 -444 -142 900000 987 -913 -975 900000 -2209 1012 -1364 -2890 900000 -2216 900000 -1220 -406 12 721 -417 -180 773 947 146 1118 -2216 -625 890 -1541 -2368 621 947 -807 -344 1953 617 425 -800 1184 1384 -62 763 -3661 900 105 686 850 2245 1121 -582 1052 661 -410 319 -5210 1445 1836 2013 171 1383 1074 1165 -94 1053 -274 710 90 791 1069 -128 -486 55 615 527 1504 -558 1110 40 -1235 -189 288 -867 -1929 -1338 -1671 -834 -500 -2441 -719 212 -274 -428 3007 475 2772 -2231 759 -279 23 1151 291 984 81 778 -949 2 -183 -1576 -1728 -1476 -1245 -247 1264 744 465 -1592 12 -290 112 849 65 1048 -959 -390 -140 967 392 -742 414 -328 2280 998 1137 256 1245 -1429 601 -1503 -764 -257 1524 11 -278 18 -919 -284 SS 20251026T071902.0Z 9430.304884 81 1 43.92 2 77.46 122.98 124.65 97.71 0.00 1 0.00 1 0 17 2.029e-01 1.005e-02 1.573e-01 3.549e-03 5.752290e-01 1.818930e-03 6.789253e-03 -6.000000e+00 1.153480e-01 224.16 -2.00 3.61 -2.00 320.28 0.00e+00 2.839217e-03 5.708748e-04 3.975962e-04 -6.000000e+00 4.698915e-03 278.63 -2.00 20.00 -2.00 319.99 0.00e+00 4.478 0.002 302.00 328.00 3 3.4921e+00 5.1410e-03 5.3312e-02 -6.0000e+00 2.8643e-01 8.5868e-02 6.3913e-03 3.0620e-02 -6.0000e+00 3.1257e-01 -3.5538e-02 6.7602e-03 1.6394e-02 -6.0000e+00 1.8419e-01 4.3986e-03 3.5644e-03 5.2485e-03 -6.0000e+00 7.8086e-02 1.0341e-04 -4.4490e-04 1.0088e-04 5.8886e-05 -6.0000e+00 5.5953e-03 -1.0800e-02 0.0000e+00 12 8 8 10 0 0 84.77 19.10 0.10 -0.01080 -0.01414 27 7 2 8 0 1626.630 15.00 19.10 14.77 22.29 21.98 21.3 939.50 900000 49918 -112294 2881 3079 -3696 -36937 -65307 -52940 55436 -47981 -63534 89869 -29448 19276 -21280 23333 2204 18640 67231 -15600 27685 -38929 -1097 -3515 -7442 -25826 10081 18429 4193 -4152 41129 13371 -4917 5325 -3477 22250 769 5522 -15452 2269 5072 -5812 10232 9096 10164 -1504 6056 2847 -1719 2527 -18913 2682 1797 8285 -1713 2986 -607 1769 -646 1999 -5741 1076 3500 1052 3773 674 -512 -926 2940 121 366 336 556 1381 -1851 -7 -1637 308 -1059 -1983 -1946 -2394 -1391 -2352 -260 -250 135 -382 1821 366 1560 -350 394 713 -304 2116 312 1107 -243 150 -140 -553 511 -1185 -751 -1230 -45 -389 737 310 -77 -137 -277 407 -364 1014 8 462 -363 -561 -194 99 292 -480 435 -786 1297 638 81 -99 73 110 121 -435 -507 -47 279 -48 -92 153 -75 89 900000 187 -2098 19 19 -23 -332 -841 -685 292 -690 -1128 465 -570 296 -571 477 60 478 1176 -607 730 -1929 -41 -145 -339 -1455 405 667 178 -213 1640 790 -383 377 -258 1371 66 541 -2203 316 744 -996 1574 1438 1622 -274 1050 524 -345 529 -5305 674 493 2283 -537 923 -197 552 -202 620 -2026 395 1409 463 1611 287 -222 -424 1456 68 217 202 323 750 -946 -3 -755 147 -582 -1257 -1381 -1856 -1131 -2018 -232 -233 129 -372 1715 331 1321 -288 320 609 -291 2216 368 1401 -316 188 -165 -609 544 -1344 -891 -1523 -57 -529 1067 482 -126 -226 -450 629 -545 1487 11 728 -597 -932 -315 158 454 -727 637 -1131 1840 971 134 -174 135 210 239 -895 -1089 -102 615 -107 -201 323 -154 176 SS 20251026T072459.9Z 9430.309026 84 1 48.72 2 76.59 124.17 123.66 98.64 0.00 1 0.00 1 0 17 1.546e-01 7.486e-03 7.103e-02 2.931e-03 5.469176e-01 1.494642e-03 6.504261e-03 -6.000000e+00 8.785347e-02 224.16 -2.00 3.61 -2.00 320.08 0.00e+00 2.880846e-03 4.408905e-04 3.427770e-04 -6.000000e+00 3.578847e-03 278.63 -2.00 20.00 -2.00 319.79 0.00e+00 4.207 0.001 302.00 328.00 3 3.5070e+00 4.1790e-03 5.0251e-02 -6.0000e+00 2.1816e-01 8.3191e-02 5.0654e-03 2.8965e-02 -6.0000e+00 2.3806e-01 -3.6120e-02 5.0600e-03 1.5323e-02 -6.0000e+00 1.4028e-01 5.7569e-03 2.6962e-03 4.8365e-03 -6.0000e+00 5.9474e-02 1.3520e-04 -6.7945e-04 8.3410e-05 5.4057e-05 -6.0000e+00 4.2616e-03 -1.0872e-02 0.0000e+00 11 8 0 10 0 0 97.75 19.11 0.00 -0.01087 -0.01598 40 9 2 8 0 1217.900 15.00 19.11 14.92 22.29 21.98 21.3 940.29 900000 -5467 -74022 -11489 -8022 -48560 -56377 -74668 -62111 -11987 -29762 -54651 33007 -26070 -148 -5735 22703 -17449 -2057 45171 -15588 15281 -27242 11932 5431 -6152 -18006 -7900 6207 -11355 -4193 15454 3721 -4327 -4191 3244 12639 -1755 400 -10106 -3288 3369 -4041 6270 3365 5618 -2257 996 1000 -4739 3575 -5157 4044 2039 5352 -1529 2754 558 -888 -1119 -552 3444 1583 3438 350 2492 -32 -1481 469 1854 366 267 206 270 233 -1697 -76 -1195 -312 -1807 -2361 -1680 -1854 -312 -1360 -227 -126 -109 384 1577 929 1062 20 -647 415 -535 769 532 334 -219 -56 -847 -408 462 -1061 -978 -852 -405 -381 574 474 -201 246 0 192 403 632 301 166 -327 -650 105 358 -26 -149 127 -323 1137 443 394 33 36 -179 -96 -57 -322 -42 295 -179 -129 151 -311 72 900000 -49 -1349 -124 -79 -643 -829 -1417 -1177 -161 -488 -1187 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