File name: Pandora138s1_Milan-MIBI_20251129_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20251129T231517.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20251129_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20251129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251129T074902.9Z 9464.325728 86 1 17.88 2 81.27 133.33 133.59 34.01 0.00 1 0.00 1 0 25 4.411e-01 2.009e-02 2.179e-01 7.932e-03 6.862287e-01 4.126648e-03 7.891720e-03 -6.000000e+00 2.481881e-01 222.04 -2.00 3.61 -2.00 321.18 0.00e+00 6.853860e-03 1.552859e-03 6.614391e-04 -6.000000e+00 1.019174e-02 274.44 -2.00 20.00 -2.00 320.85 0.00e+00 6.229 0.005 302.00 328.00 3 2.1511e+00 1.2285e-02 7.0725e-02 -6.0000e+00 6.1340e-01 3.8958e-01 1.5984e-02 3.6692e-02 -6.0000e+00 6.7046e-01 -5.1466e-01 1.6956e-02 2.0072e-02 -6.0000e+00 3.9589e-01 2.1768e-01 8.6261e-03 6.6780e-03 -6.0000e+00 1.6698e-01 6.8987e-05 -9.8100e-04 2.2236e-04 8.4476e-05 -6.0000e+00 1.2075e-02 3.8750e-03 0.0000e+00 12 9 9 12 1 1 -42.95 17.43 0.21 0.00388 -0.00350 16 10 4 8 0 1051.300 15.00 17.43 11.11 21.06 20.67 21.2 920.24 84388 -105521 61664 -150403 -99308 -169710 -138711 -127900 -171510 -30591 -193963 -92875 -62627 -6361 -69825 -20456 26335 -40691 23450 -1097 -14158 -49621 4765 4460 29272 -9166 -22522 24719 8378 42627 -49396 166253 -7787 3723 -28826 41972 20002 16938 15873 1783 32124 3095 17407 20715 26008 20281 9146 31855 4561 19600 1052 99376 17852 18017 15682 12446 11966 6122 14602 3691 8658 -2277 8619 9126 11499 6774 5560 1275 -862 11166 535 3836 -250 4154 -2210 -3895 -194 -4753 3362 -4847 -1501 -3500 331 -2368 -2491 -3246 -1242 -977 -2546 3774 -1210 3036 -2956 -2092 -3167 -3233 -404 -1553 1572 -444 -1181 -1145 -83 -717 -712 -2185 -1490 -357 -1890 1401 -879 1050 124 148 -7 315 322 -867 1279 -459 421 668 1449 1210 -299 778 1385 2127 890 1479 -200 -483 -256 464 20 -503 230 182 91 -340 -144 -788 -947 653 -1961 477 -4581 -1718 -5218 -3205 -2801 -6096 -305 -9131 -1839 -1130 -88 -2202 -489 465 -1469 507 -31 -460 -2185 126 123 667 -308 -880 605 234 899 -2875 1528 -422 202 -2066 1480 908 888 987 151 2306 312 1601 1907 2327 1935 999 2894 555 2198 152 6473 2667 2915 2763 2309 2280 1234 2650 726 1642 -515 1982 2355 3146 1914 1579 381 -283 3707 216 1585 -108 1644 -854 -1385 -62 -1573 1125 -2042 -716 -1943 195 -1509 -1690 -2345 -927 -745 -1988 2727 -870 1973 -1951 -1387 -2318 -2694 -375 -1652 1790 -523 -1350 -1215 -80 -673 -712 -2312 -1650 -415 -2393 1888 -1335 1657 201 235 -11 467 476 -1333 2039 -765 703 1084 2272 1857 -447 1125 1946 3037 1401 2583 -383 -975 -538 1014 45 -1215 559 451 226 -826 -333 -1755 -2056 SS 20251129T080606.8Z 9464.337579 91 1 49.27 2 79.16 136.74 131.81 39.02 0.00 1 0.00 1 0 17 2.252e-01 1.189e-02 6.877e-02 2.424e-03 5.905319e-01 1.244748e-03 6.902036e-03 -6.000000e+00 1.267434e-01 222.04 -2.00 3.61 -2.00 320.62 0.00e+00 6.687870e-03 4.206480e-04 4.658938e-04 -6.000000e+00 5.217658e-03 274.43 -2.00 20.00 -2.00 320.31 0.00e+00 5.124 0.003 302.00 328.00 3 2.1860e+00 3.5661e-03 5.8734e-02 -6.0000e+00 3.1326e-01 1.2289e-01 4.5236e-03 3.1322e-02 -6.0000e+00 3.4257e-01 -1.1495e-01 4.9214e-03 1.7015e-02 -6.0000e+00 2.0218e-01 3.9394e-02 2.5664e-03 5.5708e-03 -6.0000e+00 8.5912e-02 2.0963e-04 -3.9825e-04 6.9763e-05 6.5789e-05 -6.0000e+00 6.2089e-03 4.1930e-03 0.0000e+00 12 8 8 10 0 0 15.55 17.46 0.17 0.00419 0.00120 109 24 4 8 0 451.970 15.00 17.46 12.21 21.06 20.67 21.5 927.59 900000 -90164 -40227 -70309 -66707 -89680 -93600 -80331 -92844 -47467 -93197 -24933 -39591 -12843 -8237 1053 15554 -23705 14638 1350 5697 4794 4642 676 9566 -16573 -12157 -4577 -12984 901 1884 17086 890 1679 -2902 2734 7022 4860 3655 -1603 6757 771 4417 2576 6157 4120 3169 7117 5606 5074 4450 -37111 6892 6887 4601 2782 2480 -955 1283 -1386 2207 1459 3167 4143 2515 2801 2331 900 1139 3079 503 2478 -118 770 189 -1416 -235 -919 -113 -2059 -1086 -851 -1201 -1448 -1285 -990 -444 -78 254 1773 763 1747 -751 -431 -592 -476 532 483 606 412 16 -359 201 -98 -1052 -1657 -1406 -604 -257 499 175 -15 44 -153 -259 141 140 172 452 -266 -524 18 381 70 -54 398 184 1264 652 240 222 -23 6 -9 -11 -191 -202 352 -216 -211 -122 -80 -75 900000 -1143 -346 -831 -702 -1118 -1247 -1019 -1476 -520 -1682 -246 -562 -182 -143 21 304 -764 352 39 165 140 138 22 302 -653 -517 -179 -541 34 83 778 51 106 -190 163 426 347 317 -176 781 103 601 373 879 618 493 1096 912 807 779 -10986 1439 1560 1135 723 663 -265 341 -371 584 423 1021 1498 993 1089 885 351 473 1330 250 1278 -63 388 89 -651 -98 -380 -50 -1017 -623 -558 -874 -1121 -988 -812 -383 -69 228 1524 619 1396 -583 -334 -501 -431 551 540 747 518 19 -394 212 -102 -1173 -1853 -1649 -750 -345 694 270 -25 73 -247 -394 202 212 254 708 -442 -876 28 592 105 -83 587 262 1811 1042 407 413 -44 12 -18 -23 -426 -461 815 -507 -478 -261 -171 -153 SS 20251129T082715.6Z 9464.352263 101 1 49.31 2 76.73 141.11 129.36 44.84 0.00 1 0.00 1 0 17 9.026e-02 5.146e-03 1.431e-02 8.069e-04 5.004142e-01 4.042798e-04 5.998508e-03 -6.000000e+00 5.079677e-02 222.04 -2.00 3.61 -2.00 319.77 0.00e+00 1.953280e-03 1.095151e-04 2.766945e-04 -6.000000e+00 2.085795e-03 274.43 -2.00 20.00 -2.00 319.47 0.00e+00 4.249 0.001 302.00 328.00 3 1.0944e+00 1.1124e-03 4.8869e-02 -6.0000e+00 1.2555e-01 5.3791e-02 1.3160e-03 2.6116e-02 -6.0000e+00 1.3722e-01 -2.7158e-02 1.2219e-03 1.3686e-02 -6.0000e+00 8.1025e-02 4.2648e-04 6.5887e-04 4.2809e-03 -6.0000e+00 3.4177e-02 1.5879e-03 -3.0663e-04 2.3072e-05 4.7692e-05 -6.0000e+00 2.4710e-03 3.2709e-03 0.0000e+00 10 0 0 10 0 0 55.56 17.51 0.16 0.00327 0.00097 527 116 2 8 0 93.370 15.00 17.51 13.63 21.06 20.77 21.6 936.79 -27339 -26017 -22771 -29100 -29881 -39586 -34176 -34180 -31799 -17918 -29682 -20727 -18367 -13766 -9126 -5105 -1655 -2506 332 1879 1454 -1512 152 -1879 -1813 -5601 -5672 -3566 -4426 -2265 -1905 980 -18 -209 -3412 -3758 -2036 -1348 484 -539 -9 -762 70 -724 171 593 28 806 169 896 1406 2161 1554 1814 985 951 770 -457 62 -134 904 912 1722 1981 578 188 365 -17 1128 1012 139 643 -245 -49 -346 -750 -505 -1197 -430 -1136 -919 -1273 -1969 -1474 -918 -639 -138 206 434 677 728 748 241 571 257 -48 566 887 61 -390 -237 -663 71 296 -932 -1326 -699 -444 37 400 272 84 201 255 61 489 295 338 198 -281 -586 57 191 117 242 -54 51 1089 285 -60 -89 -285 -124 97 -142 -227 -60 444 -127 -147 -7 -247 103 -374 -420 -391 -536 -510 -704 -602 -672 -693 -375 -731 -496 -462 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