File name: Pandora138s1_Milan-MIBI_20251219_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20251219T232520.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20251219_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20251219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251219T100507.2Z 9484.420222 141 1 48.84 2 71.02 161.77 75.05 170.26 0.00 1 0.00 1 0 17 4.190e-02 6.652e-03 1.970e-02 2.335e-03 4.056255e-01 1.156689e-03 4.954750e-03 -6.000000e+00 2.358438e-02 221.99 -2.00 3.61 -2.00 318.79 0.00e+00 1.471481e-03 2.350633e-04 1.567135e-04 -6.000000e+00 9.683041e-04 272.32 -2.00 20.00 -2.00 318.49 0.00e+00 3.039 0.001 302.00 328.00 3 4.4378e+00 3.0945e-03 3.6260e-02 -6.0000e+00 5.8283e-02 7.9018e-02 3.5220e-03 2.0894e-02 -6.0000e+00 6.3697e-02 -1.3221e-02 2.6553e-03 1.0703e-02 -6.0000e+00 3.7614e-02 -5.7463e-03 1.4400e-03 3.2359e-03 -6.0000e+00 1.5874e-02 1.8957e-04 -1.3202e-04 6.7075e-05 3.5427e-05 -6.0000e+00 1.1471e-03 8.0034e-04 0.0000e+00 11 9 0 11 8 0 99.93 17.70 0.06 0.00080 -0.00019 36 8 1 8 0 1356.470 15.00 17.70 18.59 21.17 20.87 21.9 966.05 5798 -2153 898 -15784 -5235 -20840 -12617 -15711 -18134 1185 -24724 177 -1929 461 181 2518 4008 -5096 1345 1454 938 -116 2760 3265 2489 551 -4909 434 3140 272 -421 7480 -463 -1360 -3740 167 245 -2253 1556 -1043 -527 -2049 -519 77 644 1395 -810 563 -734 -863 1095 -4714 1903 1635 1684 1009 1140 115 70 -755 677 979 2205 2000 612 -81 493 -1085 -103 2264 -276 713 -338 -91 246 -1339 -1239 -970 -552 -1340 -1761 -1309 -1761 -877 -1267 -251 251 471 181 1539 177 1443 -441 -15 11 448 701 602 614 46 -45 -931 -118 44 -944 -1244 -803 -524 -219 700 113 269 -24 93 148 230 164 -112 621 -195 29 42 409 101 -185 186 -339 988 503 -16 -50 -369 -174 -128 -87 -145 -207 445 -107 -185 266 -306 31 164 -76 33 -674 -187 -806 -468 -661 -868 52 -1415 8 -105 29 14 214 368 -541 144 161 108 -14 319 396 325 77 -737 61 407 36 -61 1118 -82 -262 -720 30 46 -493 388 -312 -175 -734 -190 29 241 525 -311 213 -283 -339 446 -2167 881 803 866 535 618 63 38 -405 364 554 1338 1314 421 -54 314 -694 -68 1605 -217 582 -281 -73 187 -962 -823 -619 -363 -978 -1433 -1162 -1673 -862 -1308 -270 281 540 209 1733 191 1456 -430 -14 11 478 813 759 820 62 -58 -1155 -137 50 -1155 -1594 -1063 -718 -312 1045 177 436 -39 146 220 328 231 -162 933 -306 45 67 632 154 -272 266 -470 1354 730 -25 -82 -618 -297 -223 -158 -273 -398 862 -209 -357 496 -557 55 SS 20251219T102457.5Z 9484.433999 150 1 14.38 2 70.07 166.49 74.62 174.63 0.00 1 0.00 1 0 17 4.109e-02 7.223e-03 2.427e-02 3.423e-03 3.898529e-01 1.693906e-03 4.791233e-03 -6.000000e+00 2.312445e-02 221.99 -2.00 3.61 -2.00 318.50 0.00e+00 1.500865e-03 3.172059e-04 1.358716e-04 -6.000000e+00 9.495285e-04 272.32 -2.00 20.00 -2.00 318.20 0.00e+00 2.903 0.000 302.00 328.00 3 4.1293e+00 4.5038e-03 3.4705e-02 -6.0000e+00 5.7146e-02 7.8817e-02 5.1016e-03 2.0065e-02 -6.0000e+00 6.2457e-02 -2.0012e-02 3.6579e-03 1.0234e-02 -6.0000e+00 3.6881e-02 -2.8519e-03 1.9707e-03 3.0698e-03 -6.0000e+00 1.5563e-02 3.0029e-04 -1.0965e-04 9.8271e-05 3.3829e-05 -6.0000e+00 1.1248e-03 1.6329e-03 0.0000e+00 12 9 1 12 1 1 99.98 17.62 0.17 0.00163 0.00081 13 11 1 8 0 1026.710 15.00 17.62 19.32 21.17 20.87 22.0 970.48 13918 7243 -6369 2185 -19159 2761 -24236 -3091 -17573 -1252 -8289 -11030 3675 -7127 9458 -5218 7953 -1591 -161 -1042 -334 4160 -1634 6924 -2278 3697 -4163 189 -140 1216 -1786 -1370 5210 -2218 -2186 -3057 101 -4997 1489 -1899 -1788 -355 -1910 -208 -332 1613 -451 748 -801 -1448 1244 -1933 3226 740 2656 -249 2495 -81 94 -360 113 247 1775 2915 202 808 149 -491 890 1955 -495 706 588 368 315 -1875 480 -2264 803 -1752 -1557 -647 -1861 -1153 -1887 164 19 436 -162 864 206 578 65 -611 573 -322 529 340 -62 -49 -413 -828 -517 591 -904 -843 -985 -340 -53 585 682 422 196 -51 279 17 615 179 265 -354 -298 125 45 299 116 408 -78 1205 350 109 7 -409 46 -515 -167 -163 144 342 192 152 -144 -534 -288 459 293 -313 99 -969 107 -1240 -143 -1038 -69 -503 -704 232 -589 789 -574 842 -196 -21 -141 -46 554 -232 964 -365 586 -728 31 -22 186 -302 -255 1011 -492 -474 -642 22 -1268 419 -642 -672 -140 -787 -86 -139 669 -190 311 -339 -626 552 -943 1604 396 1460 -142 1429 -48 54 -206 66 151 1151 2018 147 567 100 -328 608 1453 -406 600 503 308 251 -1406 330 -1528 545 -1332 -1305 -587 -1809 -1161 -1988 179 22 507 -190 992 227 598 64 -594 572 -348 620 432 -83 -66 -541 -1026 -608 686 -1115 -1082 -1308 -466 -75 870 1062 676 312 -79 411 25 860 257 395 -549 -470 195 69 448 169 576 -108 1647 504 166 11 -673 77 -884 -296 -301 269 646 365 285 -263 -957 -506 SS 20251219T102948.9Z 9484.437372 152 1 47.03 2 69.88 167.66 74.55 175.71 0.00 1 0.00 1 0 17 4.810e-02 7.132e-03 1.515e-02 2.376e-03 3.818024e-01 1.175653e-03 4.691203e-03 -6.000000e+00 2.706600e-02 221.99 -2.00 3.61 -2.00 318.36 0.00e+00 1.289901e-03 2.113767e-04 1.271116e-04 -6.000000e+00 1.111372e-03 272.32 -2.00 20.00 -2.00 318.06 0.00e+00 2.877 0.000 302.00 328.00 3 4.6579e+00 3.1165e-03 3.4239e-02 -6.0000e+00 6.6887e-02 8.7141e-02 3.5249e-03 1.9618e-02 -6.0000e+00 7.3103e-02 -2.1452e-02 2.4714e-03 9.9894e-03 -6.0000e+00 4.3168e-02 -2.4040e-03 1.3238e-03 2.9902e-03 -6.0000e+00 1.8215e-02 1.8288e-04 -2.3864e-04 6.7971e-05 3.2821e-05 -6.0000e+00 1.3165e-03 1.6184e-03 0.0000e+00 12 9 1 12 1 1 99.87 17.60 0.15 0.00162 -0.00017 19 5 1 8 0 2351.490 15.00 17.60 19.41 21.17 20.77 22.0 971.12 23149 -3420 -4687 -14065 -7583 -17840 -23562 -7522 -19063 8007 -25348 -6198 526 -2600 -1371 -2696 2852 -1719 5555 610 2387 -1441 -839 4731 2177 -1176 -4413 -386 753 1829 -2745 6146 701 574 -5514 -1381 683 -2079 724 -1936 305 -1755 -879 391 1649 1391 -855 1432 -1219 1181 263 -1592 1974 1566 983 1157 1814 24 574 -1097 1501 514 1374 1944 630 374 -629 -502 -644 1410 45 1324 -337 396 208 -1437 -354 -1664 247 -1745 -776 -1779 -1809 -1011 -1397 -447 125 386 51 969 298 1156 -732 124 -181 -177 741 326 530 -26 -305 -1298 19 -41 -596 -1151 -835 -94 -448 776 171 356 -220 177 129 579 474 -116 888 -256 -82 60 514 213 -17 411 -219 1038 480 168 -206 -132 -391 -20 -51 -187 -240 350 -78 130 13 -540 -174 776 -168 -250 -811 -379 -919 -1316 -401 -1256 447 -1977 -416 37 -225 -137 -312 343 -228 732 88 348 -217 -128 722 360 -210 -830 -68 125 298 -498 1138 149 132 -1305 -302 154 -542 216 -689 118 -733 -377 170 709 603 -379 619 -541 518 122 -804 1027 859 564 677 1080 14 340 -653 888 323 921 1391 469 270 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