File name: Pandora138s1_Milan-MIBI_20260206_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260210T114137.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260206_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260206T081053.8Z 9533.340901 282 1 15.83 2 76.82 129.18 88.26 256.63 0.00 1 0.00 1 0 25 4.366e-01 1.147e-02 2.694e-01 6.438e-03 6.892816e-01 3.329391e-03 7.991314e-03 -6.000000e+00 2.477038e-01 224.11 -2.00 3.61 -2.00 320.73 0.00e+00 3.155186e-03 1.174833e-03 5.762670e-04 -6.000000e+00 1.008926e-02 270.63 -2.00 20.00 -2.00 320.43 0.00e+00 4.278 0.001 302.00 328.00 3 3.6702e+00 9.6436e-03 5.5558e-02 -6.0000e+00 6.1497e-01 7.1967e-02 1.2805e-02 3.6900e-02 -6.0000e+00 6.7113e-01 -1.0778e-01 1.4606e-02 2.0264e-02 -6.0000e+00 3.9571e-01 4.4436e-02 7.4675e-03 6.6287e-03 -6.0000e+00 1.6625e-01 9.3910e-05 -5.6717e-04 1.7504e-04 7.6892e-05 -6.0000e+00 1.1957e-02 1.1030e-03 0.0000e+00 12 9 9 12 1 1 -1.27 17.55 0.07 0.00110 -0.00316 8 6 2 8 0 1758.770 15.00 17.55 13.63 21.06 20.77 22.0 942.39 77937 -64617 -118936 -146195 -94390 -208175 -187143 -119064 52470 -81420 -141715 -167742 -32631 -46485 110073 -22178 149507 -38524 -4804 -1081 -29871 -46586 -27043 46576 -10186 7123 -6523 -20247 22555 -38149 1484 48498 -17960 -22510 -15193 16420 21569 16733 17450 -8725 84 -3812 -782 20439 9493 3712 -2865 11530 435 -1822 -22 21437 4410 2422 4928 3614 6081 3632 2825 -922 1921 -1607 1533 3868 2170 3653 1198 -634 -677 1918 -330 1377 -3005 -932 3264 -1621 -1307 -2306 -497 -1087 -2053 -924 -1828 -1733 -2710 -1735 838 318 -247 1248 1949 1680 -13 -371 -72 771 -390 580 729 1667 -889 -566 -504 -961 -2332 -1959 -825 -855 -263 965 476 203 122 297 146 1079 -383 -451 282 -668 -522 -300 469 777 304 590 -391 1695 720 108 594 -25 -700 -39 152 -563 -227 461 122 14 -24 -523 -119 489 -406 -1140 -1849 -700 -4164 -3259 -1236 329 -753 -2406 -3927 -277 -572 691 -341 939 -886 -89 -21 -776 -1418 -706 673 -268 170 -183 -643 476 -1470 46 1182 -937 -1375 -868 680 905 843 1049 -806 8 -420 -89 1983 1038 438 -369 1351 59 -269 -4 3161 837 511 1086 840 1428 882 678 -224 459 -428 444 1243 763 1266 422 -232 -265 829 -161 698 -1589 -466 1462 -691 -516 -913 -210 -533 -1175 -590 -1293 -1291 -2145 -1438 709 278 -219 1070 1578 1286 -10 -281 -59 705 -404 667 909 2092 -1099 -650 -535 -1000 -2562 -2254 -976 -1068 -349 1373 738 333 202 484 231 1633 -583 -705 455 -1117 -875 -489 742 1195 455 862 -562 2432 1128 186 1087 -49 -1410 -82 328 -1272 -519 1063 282 33 -53 -1099 -242 SS 20260206T081616.7Z 9533.344638 284 1 49.42 2 76.10 130.29 89.17 257.56 0.00 1 0.00 1 0 25 3.363e-01 7.535e-03 2.096e-01 2.897e-03 6.676993e-01 1.495149e-03 7.774895e-03 -6.000000e+00 1.908186e-01 224.11 -2.00 3.61 -2.00 320.63 0.00e+00 3.478222e-03 5.177576e-04 5.383529e-04 -6.000000e+00 7.772251e-03 270.63 -2.00 20.00 -2.00 320.33 0.00e+00 4.070 0.001 302.00 328.00 3 3.5521e+00 4.2953e-03 5.3279e-02 -6.0000e+00 4.7374e-01 1.5040e-02 5.6914e-03 3.5744e-02 -6.0000e+00 5.1701e-01 -1.0440e-02 6.5751e-03 1.9622e-02 -6.0000e+00 3.0484e-01 -1.7141e-04 3.3804e-03 6.4057e-03 -6.0000e+00 1.2807e-01 1.3115e-04 -6.1734e-04 7.8854e-05 7.2522e-05 -6.0000e+00 9.2114e-03 1.1034e-03 0.0000e+00 11 9 0 11 8 0 99.30 17.55 0.01 0.00110 -0.00354 43 9 2 8 0 1149.200 15.00 17.55 13.77 21.06 20.77 22.0 943.30 238158 87471 -44318 -101646 109315 -147473 -35268 -81940 -59739 22284 -114099 -59966 15027 57154 -18188 35462 -15145 -28315 -34270 42463 -11405 -9515 -3708 14805 24983 -12590 13771 -7947 34562 -32065 -5361 24053 -316 -2688 -20907 11807 11725 6760 5955 -3801 1764 -1859 -9 4475 5347 3474 430 3194 4470 4035 -322 -19335 4783 3488 3090 1492 591 1993 -2093 -834 1015 1993 3120 3627 972 2040 2025 -107 96 2136 -477 812 -1517 291 -337 -32 -1930 -1006 -1083 -1292 -1734 -1213 -656 -1689 -1523 -826 399 -438 396 1791 432 1216 -519 293 -84 276 744 1069 686 384 -80 -1029 -90 -112 -688 -1433 -1292 -986 119 490 107 485 459 501 266 237 341 -227 -12 -326 -645 -34 -75 -98 -129 253 201 938 574 213 -31 -103 -112 97 -393 -417 -126 123 -150 -16 58 148 240 673 247 -214 -833 309 -1653 -157 -609 -410 83 -1491 -534 85 287 -221 329 -253 -591 -831 560 -252 -210 -80 292 486 -365 331 -232 681 -1205 -184 759 -14 -141 -1290 527 561 387 414 -349 176 -209 -1 527 637 433 57 424 617 593 -54 -4316 947 763 722 371 153 513 -548 -212 259 542 940 1227 363 753 739 -40 39 959 -242 432 -825 150 -163 -14 -804 -413 -479 -660 -1027 -805 -474 -1301 -1232 -698 350 -397 359 1576 365 963 -403 227 -70 258 778 1247 865 493 -99 -1199 -96 -117 -761 -1663 -1556 -1248 158 705 167 793 759 816 418 360 513 -352 -19 -545 -1080 -56 -119 -152 -194 369 287 1351 895 362 -57 -197 -222 199 -844 -929 -284 280 -345 -36 125 306 482 SS 20260206T094754.0Z 9533.408264 331 1 49.35 2 65.89 151.01 104.90 273.13 0.00 1 0.00 1 0 25 3.176e-02 5.769e-03 8.676e-03 1.131e-03 4.093041e-01 5.645380e-04 5.041291e-03 -6.000000e+00 1.802103e-02 224.12 -2.00 3.61 -2.00 318.53 0.00e+00 8.183011e-04 1.067293e-04 1.445996e-04 -6.000000e+00 7.338956e-04 270.63 -2.00 20.00 -2.00 318.23 0.00e+00 2.431 0.000 302.00 328.00 3 3.7285e+00 1.5090e-03 3.2034e-02 -6.0000e+00 4.4741e-02 3.9665e-03 1.7075e-03 2.1284e-02 -6.0000e+00 4.8824e-02 1.2105e-02 1.2398e-03 1.0833e-02 -6.0000e+00 2.8788e-02 -9.7516e-03 6.6850e-04 3.2178e-03 -6.0000e+00 1.2097e-02 6.8930e-04 -2.8435e-04 3.2216e-05 3.5429e-05 -6.0000e+00 8.6979e-04 3.8234e-05 0.0000e+00 11 1 0 11 8 0 94.07 17.60 0.07 0.00004 -0.00210 96 21 2 8 0 514.060 15.00 17.60 16.40 21.17 20.77 22.1 958.88 -2708 -3693 -5987 -11586 -8487 -18955 -11802 -13623 -7503 -5635 -11018 -7937 -6088 -2043 -615 -803 -1827 -2527 -603 2329 -1096 -189 666 1229 -1134 -42 -1491 -1676 170 -2104 46 1036 605 -929 -3555 -2262 -2260 -1242 -696 -692 -1043 -651 -289 -246 61 199 -219 546 -467 -165 663 2919 1271 1455 793 828 754 422 364 104 850 1427 1926 1843 505 191 456 -240 961 664 -104 284 -328 149 -278 -497 -595 -727 -111 -773 -1105 -1037 -1949 -1420 -1032 -806 -86 -277 180 264 311 766 211 726 730 101 509 787 -62 -291 -343 -768 -134 -21 -961 -1299 -920 -418 -11 462 298 258 371 421 182 581 216 69 132 -325 -574 -310 233 326 364 268 331 1224 589 222 174 34 -108 96 -43 -288 -269 321 -235 -136 -179 -379 -73 -88 -140 -252 -514 -337 -781 -470 -615 -357 -289 -612 -447 -381 -146 -51 -77 -194 -287 -72 282 -142 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