File name: Pandora138s1_Milan-MIBI_20260215_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260215T234313.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260215_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260215T081004.5Z 9542.340329 93 1 43.71 2 74.52 127.27 73.74 154.17 0.00 1 0.00 1 0 17 1.628e-01 7.189e-03 8.913e-02 2.519e-03 5.978407e-01 1.286575e-03 7.066502e-03 -6.000000e+00 9.262343e-02 224.50 -2.00 3.61 -2.00 320.06 0.00e+00 2.598471e-03 3.819920e-04 3.809936e-04 -6.000000e+00 3.771255e-03 270.71 -2.00 20.00 -2.00 319.77 0.00e+00 3.680 0.001 302.00 328.00 3 3.6230e+00 3.5866e-03 4.7866e-02 -6.0000e+00 2.3017e-01 8.5278e-02 4.3836e-03 3.1541e-02 -6.0000e+00 2.5118e-01 -2.7524e-02 4.4985e-03 1.6748e-02 -6.0000e+00 1.4797e-01 2.0903e-03 2.3953e-03 5.2817e-03 -6.0000e+00 6.2634e-02 1.8263e-04 -6.0780e-04 6.9541e-05 5.8029e-05 -6.0000e+00 4.4911e-03 -5.3417e-03 0.0000e+00 11 8 0 10 0 0 99.90 18.11 0.03 -0.00534 -0.00991 39 10 2 8 0 1120.560 15.00 18.11 13.53 21.48 21.17 22.2 943.51 900000 45998 -11527 -78095 10026 -82699 9844 -105156 -28097 -11354 -42841 -14427 -38948 3790 -23738 19344 -8991 2902 -4214 33944 -18311 -2510 -2944 6638 23780 -15641 7469 -3998 12657 -16528 1118 18714 -2684 -472 -9906 15053 3006 3923 1501 -1666 -724 -825 -274 -428 4605 662 600 1277 1757 302 1874 -11302 3184 2185 1742 1161 739 93 -600 -240 -882 970 2530 3161 2030 1257 1264 -2162 1144 1665 -265 677 -755 492 -631 -608 -1011 -932 -1242 -1233 -1581 -956 -1355 -1756 -1280 -622 216 -55 104 831 938 1354 -334 469 -5 167 704 834 491 385 206 -851 -141 247 -512 -1385 -1054 -723 38 625 581 52 -150 39 -143 600 503 139 297 -272 -267 -81 158 137 123 -149 -238 851 578 -62 -18 -480 -454 -158 -290 -20 -341 608 51 263 -232 -78 125 900000 202 -94 -1174 65 -1165 64 -2085 -316 -121 -641 -179 -716 60 -591 396 -270 87 -146 883 -798 -96 -115 257 846 -844 341 -201 532 -932 61 1019 -205 -39 -899 1051 248 365 171 -234 -115 -142 -49 -80 841 127 118 255 362 66 437 -3279 884 663 562 390 258 33 -209 -82 -306 353 1006 1387 961 594 582 -1039 562 905 -162 433 -491 306 -373 -330 -511 -460 -650 -734 -1071 -717 -1105 -1512 -1147 -584 210 -54 105 816 878 1199 -287 398 -5 167 773 1009 639 510 265 -1032 -159 271 -590 -1680 -1324 -945 52 914 909 85 -247 64 -223 897 746 211 468 -446 -440 -131 249 211 184 -216 -339 1205 874 -102 -31 -877 -854 -305 -586 -41 -725 1298 109 554 -474 -154 240 SS 20260215T082653.4Z 9542.352006 104 1 9.12 2 72.23 130.83 72.54 157.89 0.00 1 0.00 1 0 17 9.673e-02 6.336e-03 4.700e-02 3.074e-03 5.262992e-01 1.552248e-03 6.332524e-03 -6.000000e+00 5.502152e-02 224.50 -2.00 3.61 -2.00 319.41 0.00e+00 2.097191e-03 3.821247e-04 2.590136e-04 -6.000000e+00 2.240085e-03 270.71 -2.00 20.00 -2.00 319.12 0.00e+00 3.233 0.001 302.00 328.00 3 3.0239e+00 4.2329e-03 4.2009e-02 -6.0000e+00 1.3673e-01 7.8389e-02 4.9218e-03 2.7507e-02 -6.0000e+00 1.4920e-01 -3.2078e-02 4.3131e-03 1.4242e-02 -6.0000e+00 8.7899e-02 5.8184e-03 2.3438e-03 4.3481e-03 -6.0000e+00 3.7209e-02 5.5208e-04 -4.9550e-04 8.5610e-05 4.7214e-05 -6.0000e+00 2.6677e-03 -5.8145e-03 0.0000e+00 12 1 1 12 1 1 99.88 18.13 0.05 -0.00581 -0.00954 17 21 1 8 0 506.250 15.00 18.13 14.12 21.58 21.17 22.1 945.71 900000 -5327 -1689 -44125 -28201 -45822 -7225 -45483 -15652 -40777 -38454 -27071 -20685 -13854 -11035 3337 -12006 -3199 -9866 4152 -7772 2338 -5517 949 1577 -7572 1753 -11903 341 -8550 -685 -1358 1829 1823 -4896 -1017 -2825 1776 -441 992 -1778 966 -1682 -113 986 292 893 1172 479 943 1239 1605 2227 1027 1454 1074 762 1298 -80 1442 262 1999 1780 2139 981 386 479 -1301 975 1266 -197 -132 -919 608 113 -565 -1083 -393 -1398 -814 -1764 -814 -1904 -1465 -1146 -1091 77 -431 158 230 772 639 404 357 860 486 188 743 50 671 -563 -428 -259 74 -946 -824 -603 -752 20 604 322 -151 -57 285 12 554 551 469 144 -142 -673 85 15 -74 343 404 125 748 693 47 -11 -215 -92 -130 -161 -172 -615 752 -169 142 -219 -196 -20 900000 -80 -27 -1057 -542 -977 -113 -1114 -329 -1173 -1134 -762 -639 -494 -470 148 -687 -183 -650 254 -553 152 -392 68 121 -662 146 -1111 27 -753 -62 -144 213 233 -659 -127 -380 260 -78 205 -428 243 -454 -31 271 82 253 334 141 284 398 561 830 416 615 470 344 588 -36 628 117 931 906 1187 580 225 271 -747 572 817 -140 -99 -693 443 78 -364 -650 -229 -856 -550 -1344 -677 -1715 -1376 -1118 -1113 81 -466 172 247 787 617 375 328 823 509 215 927 66 900 -738 -529 -302 84 -1133 -1032 -776 -1007 28 889 503 -245 -92 453 18 813 803 698 221 -228 -1091 135 23 -113 508 583 176 1052 1028 75 -18 -374 -164 -239 -305 -338 -1228 1510 -344 282 -423 -370 -36 SS 20260215T083239.5Z 9542.356013 107 1 49.20 2 71.47 132.07 72.17 159.18 0.00 1 0.00 1 0 17 7.194e-02 5.558e-03 3.751e-03 3.065e-04 5.086297e-01 1.541931e-04 6.136457e-03 -6.000000e+00 4.092155e-02 224.50 -2.00 3.61 -2.00 319.20 0.00e+00 1.704978e-03 3.561772e-05 2.315661e-04 -6.000000e+00 1.665985e-03 270.71 -2.00 20.00 -2.00 318.90 0.00e+00 3.108 0.001 302.00 328.00 3 3.7657e-01 4.1849e-04 4.0450e-02 -6.0000e+00 1.0169e-01 5.6363e-02 4.8220e-04 2.6499e-02 -6.0000e+00 1.1097e-01 -3.1951e-02 4.0356e-04 1.3639e-02 -6.0000e+00 6.5373e-02 5.7056e-03 2.1967e-04 4.1309e-03 -6.0000e+00 2.7674e-02 9.0856e-03 -5.9428e-04 8.5234e-06 4.4558e-05 -6.0000e+00 1.9840e-03 -5.9996e-03 0.0000e+00 10 0 0 10 0 0 98.64 18.15 0.16 -0.00600 -0.01047 1499 329 2 8 0 32.820 15.00 18.15 14.44 21.58 21.17 22.3 948.68 900000 -23683 -17350 -23053 -26377 -30231 -28005 -24747 -24562 -18179 -25728 -19451 -17472 -8982 -5497 -3713 -2108 -1102 532 119 403 -1972 370 -1243 -1893 -2892 -4086 -4061 -4997 -3084 -2292 -230 673 -572 -3084 -3262 -2815 -2055 -558 -523 -566 -697 -133 -247 640 798 358 617 94 502 1419 1218 1439 1862 950 1042 864 -50 129 0 928 1357 1975 2187 957 154 357 -115 914 930 84 502 -63 275 -254 -549 -556 -1201 -586 -935 -1049 -1099 -1914 -1727 -1035 -803 -148 50 375 458 513 665 149 434 440 27 360 805 99 -237 -348 -716 -185 217 -800 -1302 -834 -540 -120 397 285 209 185 253 84 440 349 321 239 -136 -472 48 331 198 363 159 55 1103 411 7 -72 -269 -66 -18 -110 -199 -139 455 -96 -150 -80 -288 -120 900000 -536 -407 -580 -633 -706 -664 -631 -709 -545 -872 -653 -613 -358 -261 -207 -131 -74 38 9 32 -160 30 -109 -180 -295 -437 -427 -506 -308 -253 -29 87 -83 -455 -461 -418 -348 -112 -127 -146 -195 -39 -75 194 245 112 194 30 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