File name: Pandora138s1_Milan-MIBI_20260228_L2Fit_fwvt1c22d20250714p1-8.txt File generation date: 20260228T234352.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260228_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1629 1778 Nominal wavelengths inside fitting window [nm]: 492.1148 492.2359 492.3571 492.4782 492.5993 492.7204 492.8415 492.9625 493.0836 493.2046 493.3256 493.4466 493.5676 493.6885 493.8095 493.9304 494.0513 494.1722 494.2931 494.4139 494.5347 494.6556 494.7764 494.8972 495.0179 495.1387 495.2594 495.3801 495.5008 495.6215 495.7422 495.8629 495.9835 496.1041 496.2247 496.3453 496.4659 496.5864 496.7070 496.8275 496.9480 497.0685 497.1889 497.3094 497.4298 497.5502 497.6706 497.7910 497.9114 498.0317 498.1520 498.2724 498.3927 498.5129 498.6332 498.7534 498.8737 498.9939 499.1141 499.2343 499.3544 499.4746 499.5947 499.7148 499.8349 499.9550 500.0750 500.1951 500.3151 500.4351 500.5551 500.6751 500.7950 500.9150 501.0349 501.1548 501.2747 501.3946 501.5144 501.6343 501.7541 501.8739 501.9937 502.1134 502.2332 502.3529 502.4726 502.5923 502.7120 502.8317 502.9514 503.0710 503.1906 503.3102 503.4298 503.5493 503.6689 503.7884 503.9079 504.0274 504.1469 504.2664 504.3858 504.5052 504.6247 504.7440 504.8634 504.9828 505.1021 505.2215 505.3408 505.4600 505.5793 505.6986 505.8178 505.9370 506.0562 506.1754 506.2946 506.4138 506.5329 506.6520 506.7711 506.8902 507.0093 507.1283 507.2473 507.3664 507.4854 507.6043 507.7233 507.8422 507.9612 508.0801 508.1990 508.3179 508.4367 508.5556 508.6744 508.7932 508.9120 509.0308 509.1495 509.2683 509.3870 509.5057 509.6244 509.7430 509.8617 509.9803 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260228T100953.0Z 9555.423530 336 1 7.90 2 56.75 154.33 110.81 15.51 0.00 1 0.00 1 0 15 2.034e-03 2.038e-03 4.541e-04 4.535e-04 1.500573e+03 2.702957e+01 1.116304e+02 -6.000000e+00 1.158192e+02 271.70 -2.00 20.00 -2.00 505.27 0.00e+00 5.940662e-04 1.249936e-05 3.535010e-05 -6.000000e+00 5.719573e-05 271.70 -2.00 20.00 -2.00 500.52 0.00e+00 2.281603e-02 9.253961e-03 1.386288e-02 -6.000000e+00 4.175135e-02 225.01 -2.00 3.61 -2.00 502.10 0.00e+00 1.818 0.000 489.00 513.00 1 4.9895e+00 7.1029e-04 2.9230e-03 -6.0000e+00 3.2059e-03 1.0591e-02 1.7938e-04 3.4072e-04 -6.0000e+00 8.1132e-04 1.0242e-02 1.1782e-05 5.6545e-05 2.1006e-05 -6.0000e+00 2.6064e-04 -2.7761e-03 2.2691e-05 12 1 1 12 1 1 71.75 18.23 0.57 -0.00278 -0.00269 39 55 1 2 0 197.330 15.00 18.23 21.60 21.58 21.27 22.9 992.77 364 273 333 31 -94 94 104 254 41 113 268 75 -36 150 317 206 65 15 -141 -298 16 194 161 261 121 -132 -81 -134 -286 102 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-147 9 340 95 73 260 -158 -284 -76 15 -19 168 112 -49 -92 -65 -35 87 163 -23 SQ 20260228T102538.4Z 9555.434472 343 1 43.19 2 55.65 158.83 110.06 19.12 0.00 1 0.00 1 0 15 1.990e-03 1.990e-03 4.036e-04 4.030e-04 1.578132e+03 2.406431e+01 1.152134e+02 -6.000000e+00 1.132833e+02 271.70 -2.00 20.00 -2.00 505.26 0.00e+00 5.000681e-04 1.112750e-05 3.099602e-05 -6.000000e+00 5.594472e-05 271.70 -2.00 20.00 -2.00 500.48 0.00e+00 1.954276e-02 8.230370e-03 1.445186e-02 -6.000000e+00 4.085602e-02 225.01 -2.00 3.61 -2.00 502.07 0.00e+00 1.767 0.000 489.00 513.00 1 6.4718e+00 6.3197e-04 2.8523e-03 -6.0000e+00 3.1369e-03 1.2579e-02 1.5954e-04 3.5383e-04 -6.0000e+00 7.9440e-04 2.3461e-03 8.2319e-04 5.0105e-05 1.9464e-05 -6.0000e+00 2.5496e-04 1.5208e-03 -4.4659e-05 10 0 0 10 0 0 99.94 18.26 0.55 0.00152 0.00723 64 16 1 2 0 674.770 14.98 18.26 22.33 21.69 21.27 22.8 995.55 259 330 227 -31 -71 149 247 110 111 75 205 83 -39 76 296 107 -80 62 -114 -261 2 125 90 257 25 -85 -54 -131 -332 124 461 93 20 6 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-17 189 -84 -328 -71 94 -2 132 40 -48 -138 -98 -125 110 212 29 SQ 20260228T103542.0Z 9555.441459 348 1 43.10 2 55.06 161.77 109.51 21.40 0.00 1 0.00 1 0 15 1.978e-03 1.981e-03 3.915e-04 3.909e-04 1.514556e+03 2.331498e+01 1.111257e+02 -6.000000e+00 1.125996e+02 271.70 -2.00 20.00 -2.00 505.27 0.00e+00 5.101868e-04 1.076623e-05 3.099158e-05 -6.000000e+00 5.560672e-05 271.70 -2.00 20.00 -2.00 500.50 0.00e+00 2.761760e-02 7.984448e-03 1.390700e-02 -6.000000e+00 4.060580e-02 225.01 -2.00 3.61 -2.00 502.09 0.00e+00 1.741 0.000 489.00 513.00 1 6.4097e+00 6.1301e-04 2.8013e-03 -6.0000e+00 3.1177e-03 9.9380e-03 1.5481e-04 3.4126e-04 -6.0000e+00 7.8945e-04 2.5042e-03 5.6058e-04 4.8757e-05 1.9307e-05 -6.0000e+00 2.5342e-04 7.9646e-04 -3.2922e-05 10 0 0 10 0 0 99.65 18.25 0.56 0.00080 0.00468 82 21 1 2 0 525.560 15.00 18.25 22.93 21.69 21.27 23.2 1002.02 319 270 233 -91 -78 87 240 213 1 176 212 50 -47 165 357 43 6 2 -165 -254 28 119 93 230 84 -127 -123 -163 -334 209 513 155 -47 39 -406 -510 -155 61 22 150 230 81 77 52 -57 -129 -158 -80 -126 -210 -25 94 -20 12 -136 -352 -407 -202 125 32 227 104 -2 0 28 -28 24 94 -59 -52 49 -89 -290 -180 -341 -454 -138 38 -5 -105 16 -130 -282 -108 -86 -272 -168 -40 104 89 81 169 -44 -242 -154 114 -6 -183 -24 35 -33 -306 -360 -352 -728 -306 -61 163 236 299 12 38 127 146 187 289 227 134 112 414 336 233 390 182 -45 166 61 90 107 114 -214 95 230 55 33 291 -71 -328 -5 51 0 76 145 -82 -31 -104 -137 37 91 -29 309 266 236 -92 -80 92 248 220 1 185 219 52 -48 165 358 44 6 2 -171 -266 29 125 98 242 88 -133 -128 -167 -344 211 513 157 -48 40 -425 -536 -161 63 22 152 234 83 79 54 -60 -135 -164 -82 -126 -211 -24 91 -19 12 -136 -351 -412 -205 127 32 231 107 -2 0 28 -28 24 94 -58 -51 48 -88 -287 -179 -340 -450 -134 37 -4 -100 16 -126 -276 -106 -86 -265 -164 -39 102 88 81 169 -45 -244 -154 112 -6 -177 -23 33 -32 -297 -349 -348 -730 -306 -61 160 231 295 12 37 126 147 189 292 229 135 112 405 335 231 385 180 -44 164 60 89 105 111 -207 91 218 52 31 279 -70 -317 -5 51 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