File name: Pandora138s1_Milan-MIBI_20260304_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260304T234723.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260304_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260304T081554.3Z 9559.344379 276 1 48.09 2 68.24 125.24 111.36 293.98 0.00 1 0.00 1 0 17 9.922e-02 8.176e-03 3.229e-02 2.751e-03 4.490503e-01 1.381191e-03 5.454983e-03 -6.000000e+00 5.653294e-02 225.16 -2.00 3.61 -2.00 318.94 0.00e+00 1.530494e-03 2.932115e-04 1.841238e-04 -6.000000e+00 2.292598e-03 272.00 -2.00 20.00 -2.00 318.64 0.00e+00 2.674 0.000 302.00 328.00 3 5.0241e+00 3.7259e-03 3.5323e-02 -6.0000e+00 1.4068e-01 8.3142e-02 4.2500e-03 2.3448e-02 -6.0000e+00 1.5340e-01 -1.6727e-02 3.3216e-03 1.1971e-02 -6.0000e+00 9.0379e-02 -4.3091e-03 1.8018e-03 3.5814e-03 -6.0000e+00 3.7905e-02 1.3637e-04 -3.3386e-04 7.7944e-05 3.8774e-05 -6.0000e+00 2.7178e-03 -1.8238e-03 0.0000e+00 11 8 0 10 0 0 99.74 18.24 0.18 -0.00182 -0.00433 19 4 1 8 0 2531.060 15.00 18.24 19.12 21.69 21.27 22.8 977.97 69187 -11532 -3278 -19681 -1576 -46062 -22005 -19764 -42036 -16234 -45017 -15445 -2069 -2601 -4435 839 -3933 -7299 1224 6232 -2733 826 1140 9456 6441 3398 863 6560 4219 -615 -1740 12215 -2390 3456 -10083 -950 -445 409 3949 -1599 -428 -2144 1229 -284 2913 890 -642 2767 807 595 -1007 -2641 1908 2387 1462 869 780 783 169 -1668 1011 -5289 2298 2359 1568 38 -246 -446 5 1541 -513 833 -1568 979 -197 -235 -697 -1820 200 -2025 -388 -1211 -1138 -1311 -1067 -439 -44 -20 271 1143 660 1862 -282 285 -180 176 1134 422 781 253 -713 -1275 542 -173 -1043 -1411 -730 -442 -284 689 472 376 -83 -75 60 192 184 101 346 20 -243 -11 512 -35 -264 401 -89 1153 308 174 -150 -479 -161 -100 13 -101 -299 394 172 -189 -64 -140 -94 812 -332 -95 -671 -42 -1736 -692 -668 -1958 -652 -2443 -666 -90 -137 -284 60 -324 -670 111 563 -278 82 114 930 699 398 107 756 475 -72 -224 1565 -390 581 -1875 -156 -77 79 882 -442 -131 -714 414 -99 999 312 -230 964 289 217 -397 -1135 847 1124 725 444 409 413 88 -870 521 -3036 1343 1493 1039 25 -155 -279 3 1082 -399 673 -1293 773 -149 -164 -454 -1153 129 -1477 -311 -1065 -1070 -1287 -1091 -469 -49 -23 311 1281 709 1870 -273 270 -178 188 1312 535 1046 345 -943 -1596 632 -201 -1274 -1802 -958 -602 -403 1023 741 611 -134 -118 90 277 262 148 524 31 -389 -18 791 -54 -387 571 -124 1585 448 270 -244 -807 -277 -177 24 -192 -576 768 337 -365 -119 -255 -168 SS 20260304T082732.9Z 9559.352464 282 1 48.56 2 66.60 127.82 113.18 296.29 0.00 1 0.00 1 0 17 8.273e-02 1.698e-02 2.668e-02 2.944e-03 4.193161e-01 1.475222e-03 5.127699e-03 -6.000000e+00 4.713365e-02 225.16 -2.00 3.61 -2.00 318.75 0.00e+00 4.279845e-03 2.945577e-04 1.575530e-04 -6.000000e+00 1.911555e-03 272.00 -2.00 20.00 -2.00 318.46 0.00e+00 2.499 0.000 302.00 328.00 3 5.3179e+00 3.9574e-03 3.3010e-02 -6.0000e+00 1.1729e-01 1.0185e-01 4.4893e-03 2.1898e-02 -6.0000e+00 1.2789e-01 -3.5639e-02 3.3757e-03 1.1140e-02 -6.0000e+00 7.5353e-02 4.8078e-03 1.8271e-03 3.3142e-03 -6.0000e+00 3.1602e-02 1.2299e-04 -1.6602e-04 8.3999e-05 3.6109e-05 -6.0000e+00 2.2661e-03 -1.4308e-03 0.0000e+00 12 8 8 10 0 0 99.67 18.22 0.00 -0.00143 -0.00268 19 4 1 8 0 2555.510 15.01 18.22 20.14 21.58 21.27 23.0 985.46 41761 31003 5270 -14947 -5996 -47538 -1078 1740 -21618 -7725 -34769 -11701 -4773 449 3926 6721 2960 5583 6258 13098 3189 8778 5363 11827 6349 -1538 -3197 3277 9140 -8860 4226 14507 4315 3888 -5181 4026 2721 6141 1475 172 -783 -2274 -1622 1427 2633 3344 571 1576 1590 1805 1369 -29317 3885 2440 2130 1722 308 723 -417 -1021 620 3766 2014 3530 1564 1945 1228 -145 429 2051 404 457 -1139 454 -289 -1222 -656 -2010 -272 -886 -1636 -747 -1382 -791 -967 -248 432 376 80 1008 845 2189 -724 201 -580 388 1119 884 897 1172 28 -790 151 -223 -386 -1515 -974 -1084 -44 591 387 209 -232 -181 -423 202 -161 -292 130 -50 -535 -177 117 -232 -248 476 -384 1102 542 204 209 -165 -255 0 -141 -388 -64 937 212 69 -226 -334 -103 867 828 192 -656 -223 -2425 -37 62 -1055 -356 -2111 -595 -261 28 287 559 280 553 658 1349 372 971 617 1336 790 -214 -464 439 1112 -1279 591 2077 754 737 -1043 711 510 1261 369 51 -261 -812 -603 530 976 1254 221 602 615 705 567 -16785 1809 1217 1108 915 169 397 -226 -551 335 2104 1239 2319 1086 1302 792 -94 285 1472 320 378 -959 368 -224 -880 -436 -1303 -180 -651 -1342 -667 -1324 -785 -1001 -269 485 432 93 1143 914 2219 -710 191 -576 414 1300 1122 1205 1583 37 -988 177 -259 -470 -1945 -1289 -1491 -63 880 609 340 -375 -283 -632 288 -228 -424 195 -78 -850 -278 181 -350 -362 673 -530 1504 781 312 335 -275 -433 0 -255 -726 -122 1793 411 132 -419 -605 -182 SS 20260304T090556.7Z 9559.379128 306 1 48.74 2 61.62 136.88 118.90 304.39 0.00 1 0.00 1 0 17 2.571e-02 6.904e-03 8.425e-03 1.863e-03 3.561682e-01 9.367144e-04 4.388928e-03 -6.000000e+00 1.465462e-02 225.16 -2.00 3.61 -2.00 317.81 0.00e+00 3.653083e-04 1.437910e-04 9.961043e-05 -6.000000e+00 5.953877e-04 272.01 -2.00 20.00 -2.00 317.51 0.00e+00 2.094 0.000 302.00 328.00 3 5.0664e+00 2.4734e-03 2.7771e-02 -6.0000e+00 3.6470e-02 6.1541e-02 2.7771e-03 1.8482e-02 -6.0000e+00 3.9783e-02 1.9499e-04 1.8164e-03 9.3154e-03 -6.0000e+00 2.3425e-02 -9.1676e-03 9.4911e-04 2.7258e-03 -6.0000e+00 9.8991e-03 2.6194e-04 -3.1084e-04 5.3268e-05 2.9978e-05 -6.0000e+00 7.0911e-04 -3.6067e-03 0.0000e+00 11 8 0 10 0 0 99.70 18.24 -0.00 -0.00361 -0.00594 23 5 1 8 0 2119.160 15.01 18.24 21.97 21.58 21.27 22.9 994.05 900000 2515 -578 -5708 -5614 -12935 -12522 5238 -10144 3487 -12741 -2384 2466 -2630 -154 -1520 1777 -1563 1614 1881 890 -1152 324 2921 1799 1148 -2396 830 2473 -182 -144 4218 1888 -44 -5154 -2766 -1173 -307 -536 -977 -421 -1529 -472 -463 -267 -1 -1454 181 -1226 180 -408 3725 1511 855 773 490 1138 65 292 -324 1029 2775 1552 1841 484 -246 -542 -608 -14 1521 -321 375 -803 651 6 -1010 -540 -1407 32 -1424 -860 -1646 -1869 -1470 -1130 -346 -187 102 40 862 464 1275 -27 516 320 246 533 661 211 56 -345 -672 -26 221 -572 -1271 -868 -385 -262 789 -118 217 -8 358 200 471 539 -207 611 -125 -201 -278 262 71 180 451 -357 1276 560 -96 -247 -177 -180 -55 -172 -107 -52 393 77 -8 -7 -668 -67 900000 164 -42 -428 -383 -887 -880 345 -858 284 -1237 -214 235 -305 -20 -231 283 -270 283 344 170 -223 63 581 384 258 -569 187 518 -38 -32 980 490 -12 -1480 -745 -328 -95 -193 -410 -194 -749 -237 -236 -137 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