File name: Pandora138s1_Milan-MIBI_20260312_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260312T233931.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260312_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260312T074740.5Z 9567.324774 189 1 48.61 2 69.68 117.63 77.83 201.55 0.00 1 0.00 1 0 17 7.592e-02 6.984e-03 2.204e-02 1.860e-03 4.738127e-01 9.356707e-04 5.735086e-03 -6.000000e+00 4.331653e-02 225.47 -2.00 3.61 -2.00 319.10 0.00e+00 2.148677e-03 2.078517e-04 2.056270e-04 -6.000000e+00 1.754304e-03 272.61 -2.00 20.00 -2.00 318.80 0.00e+00 2.851 0.000 302.00 328.00 3 4.1412e+00 2.5358e-03 3.7526e-02 -6.0000e+00 1.0787e-01 6.0296e-02 2.9023e-03 2.4800e-02 -6.0000e+00 1.1759e-01 -2.8508e-02 2.3458e-03 1.2686e-02 -6.0000e+00 6.9265e-02 2.1299e-03 1.2748e-03 3.8076e-03 -6.0000e+00 2.9035e-02 2.7469e-04 -4.7128e-04 5.2385e-05 4.1239e-05 -6.0000e+00 2.0799e-03 -2.7263e-03 0.0000e+00 11 8 0 10 0 0 92.67 18.24 0.02 -0.00273 -0.00627 39 9 2 8 0 1246.320 14.99 18.24 19.18 21.58 21.27 22.8 978.51 10805 1900 -26983 -21762 -25096 -40500 -33466 -3063 -27513 -7450 -34885 -19600 -6401 -11797 1788 -9715 65 -3204 -1019 9916 -524 -356 -1250 4581 2156 3074 -3487 3308 -76 -992 -2220 8405 1249 -1368 -5206 -2086 2202 674 593 -1239 37 -2680 -750 296 1147 1208 129 1833 -7 -46 658 -7610 2183 2428 1842 951 1264 -271 894 -846 687 2642 1490 2499 1159 548 -18 95 357 1480 6 640 -791 -92 207 -1321 92 -1101 -212 -1497 -1109 -1032 -1789 -1571 -1292 -657 -389 143 224 862 623 1102 -298 465 502 171 470 429 541 301 -294 -604 57 83 -1109 -1134 -931 -524 -214 612 307 97 50 -174 277 299 351 148 388 -197 -387 122 294 115 16 284 -285 1081 667 11 93 -209 -109 -44 -40 -130 -207 421 -165 -252 46 -312 6 183 41 -828 -638 -704 -1230 -996 -76 -947 -234 -1455 -747 -249 -586 94 -670 5 -250 -83 771 -47 -32 -114 420 215 320 -398 351 -8 -105 -261 1019 182 -221 -860 -321 344 121 126 -314 11 -827 -238 95 372 396 43 606 -3 -16 243 -3247 921 1086 867 464 631 -138 444 -419 340 1361 840 1520 743 345 -11 57 225 1012 4 502 -631 -71 153 -911 58 -682 -135 -1068 -880 -896 -1665 -1518 -1302 -694 -424 160 252 948 658 1100 -286 436 491 182 544 539 721 405 -386 -752 66 96 -1348 -1440 -1218 -710 -303 905 482 157 81 -275 418 435 505 218 591 -313 -621 193 457 175 23 410 -400 1509 981 17 153 -357 -189 -78 -74 -251 -405 830 -328 -493 88 -578 10 SS 20260312T080551.7Z 9567.337404 198 1 49.21 2 66.91 121.50 79.05 205.30 0.00 1 0.00 1 0 17 2.879e-02 5.473e-03 3.935e-03 5.607e-04 4.204514e-01 2.809820e-04 5.132488e-03 -6.000000e+00 1.642552e-02 225.47 -2.00 3.61 -2.00 318.39 0.00e+00 1.164178e-03 5.069779e-05 1.434363e-04 -6.000000e+00 6.652080e-04 272.61 -2.00 20.00 -2.00 318.09 0.00e+00 2.530 0.000 302.00 328.00 3 2.2529e+00 7.5030e-04 3.3240e-02 -6.0000e+00 4.0904e-02 4.5263e-02 8.4642e-04 2.1871e-02 -6.0000e+00 4.4588e-02 -2.2272e-02 6.0131e-04 1.1075e-02 -6.0000e+00 2.6265e-02 1.4189e-03 3.2266e-04 3.2743e-03 -6.0000e+00 1.1010e-02 2.6581e-03 -4.1709e-04 1.5847e-05 3.5230e-05 -6.0000e+00 7.8867e-04 -2.8723e-03 0.0000e+00 10 0 0 10 0 0 90.31 18.23 0.12 -0.00287 -0.00601 311 68 4 8 0 158.230 15.01 18.23 20.79 21.58 21.27 23.2 989.70 -9015 -4889 -7771 -7735 -10303 -13288 -10802 -10443 -7794 -8476 -8896 -8035 -4917 -2710 -717 -59 -668 612 411 1576 126 600 1500 1255 -206 -528 -1746 -2117 -1171 -1350 -234 642 1573 -536 -2912 -2098 -2140 -1014 -256 -394 -1196 -736 -408 -421 239 112 -161 2 -368 121 1079 784 1362 1363 1066 866 735 22 239 266 1040 1351 1831 1900 488 -140 225 -220 924 832 86 293 -54 174 -188 -510 -337 -713 -446 -725 -1092 -1150 -1980 -1549 -1135 -824 -180 -50 277 407 458 506 267 504 590 49 413 789 -15 -315 -440 -634 -147 242 -755 -1218 -687 -569 -130 362 229 175 181 285 72 443 372 363 249 -91 -499 28 276 265 359 227 116 1128 459 -6 -27 -323 -12 73 -86 -187 -102 450 -100 -154 -162 -384 -229 -341 -208 -369 -367 -457 -566 -463 -494 -406 -487 -532 -492 -333 -216 -67 -6 -74 72 52 205 17 82 205 184 -33 -89 -306 -362 -187 -214 -40 122 331 -126 -684 -466 -502 -249 -75 -139 -449 -295 -170 -181 102 48 -70 1 -160 53 502 400 694 744 617 518 451 14 145 159 623 861 1201 1370 353 -104 157 -152 656 628 73 250 -46 145 -156 -381 -241 -487 -315 -547 -950 -1066 -1920 -1579 -1223 -902 -207 -57 317 476 499 535 263 503 587 54 493 1008 -20 -428 -570 -792 -176 284 -914 -1579 -884 -773 -187 535 352 282 288 433 106 636 525 528 368 -137 -773 42 423 391 526 319 163 1560 657 -9 -41 -529 -21 122 -152 -340 -191 852 -185 -289 -289 -682 -392 SS 20260312T081328.6Z 9567.342692 202 1 49.24 2 65.78 123.17 79.62 206.85 0.00 1 0.00 1 0 17 2.214e-02 5.403e-03 2.309e-03 3.837e-04 4.007751e-01 1.920216e-04 4.910654e-03 -6.000000e+00 1.263466e-02 225.47 -2.00 3.61 -2.00 318.19 0.00e+00 1.007123e-03 3.274408e-05 1.263573e-04 -6.000000e+00 5.116599e-04 272.61 -2.00 20.00 -2.00 317.89 0.00e+00 2.420 0.000 302.00 328.00 3 1.6335e+00 5.0993e-04 3.1745e-02 -6.0000e+00 3.1463e-02 4.1762e-02 5.7409e-04 2.0847e-02 -6.0000e+00 3.4297e-02 -2.1299e-02 3.9381e-04 1.0531e-02 -6.0000e+00 2.0203e-02 1.5978e-03 2.0967e-04 3.0941e-03 -6.0000e+00 8.4693e-03 5.6389e-03 -3.8364e-04 1.0866e-05 3.3607e-05 -6.0000e+00 6.0663e-04 -3.1147e-03 0.0000e+00 11 1 0 11 8 0 80.50 18.25 0.15 -0.00311 -0.00600 652 143 2 8 0 75.510 14.99 18.25 21.63 21.69 21.27 23.3 995.29 -6255 -3680 -3973 -6214 -7133 -10012 -6924 -7884 -5635 -7233 -6960 -7649 -4468 -2655 -423 148 -299 764 307 2031 825 735 1205 936 356 -773 -1079 -2233 -1566 -1373 540 427 1584 -501 -2577 -1835 -2126 -1086 -451 -311 -1059 -461 -473 -441 207 169 -185 -22 17 -115 1092 708 1153 1242 840 942 841 272 112 404 941 1492 1672 1751 416 -216 209 -334 1076 787 135 268 -118 236 -260 -408 -403 -711 -369 -737 -1095 -1148 -1999 -1551 -1025 -769 -204 -94 275 286 466 491 209 584 521 138 371 789 -33 -355 -378 -626 -221 333 -763 -1155 -711 -547 -38 311 270 165 227 218 88 500 366 394 334 -58 -494 48 213 259 411 171 137 1078 426 -10 -56 -344 -51 46 -19 -171 -139 417 -166 -162 -116 -325 -189 -281 -188 -220 -351 -370 -497 -343 -437 -344 -492 -487 -555 -356 -248 -46 19 -38 103 44 301 128 114 189 156 64 -147 -213 -433 -284 -245 102 90 369 -129 -664 -446 -547 -292 -144 -111 -433 -201 -215 -206 96 79 -87 -10 8 -55 543 360 627 722 517 558 512 168 68 255 599 942 1159 1253 316 -159 153 -240 793 617 113 237 -105 203 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