File name: Pandora138s1_Milan-MIBI_20260327_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260327T233948.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260327_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260327T055922.4Z 9582.249565 150 1 49.17 2 82.75 93.66 109.60 346.35 0.00 1 0.00 1 0 25 4.567e-01 1.999e-02 2.151e-01 5.587e-03 1.269587e+00 3.267477e-03 1.350709e-02 -6.000000e+00 2.612080e-01 226.49 -2.00 3.61 -2.00 322.52 0.00e+00 -8.819011e-04 1.512740e-03 2.202474e-03 -6.000000e+00 1.058269e-02 274.20 -2.00 20.00 -2.00 322.17 0.00e+00 7.319 0.008 302.00 328.00 3 3.4658e-01 1.1145e-02 1.0080e-01 -6.0000e+00 6.5196e-01 1.6901e+00 1.5721e-02 6.9694e-02 -6.0000e+00 7.1090e-01 -2.1995e+00 1.6402e-02 4.0378e-02 -6.0000e+00 4.1820e-01 8.6205e-01 8.1179e-03 1.4678e-02 -6.0000e+00 1.7592e-01 6.7485e-05 -1.2211e-03 1.3546e-04 2.2087e-04 -6.0000e+00 1.2606e-02 8.3128e-03 0.0000e+00 12 9 8 11 8 0 -12.08 17.43 0.15 0.00831 -0.00086 139 31 4 8 0 353.680 15.00 17.43 13.91 20.96 20.67 22.6 949.35 900000 16609 -41166 -40223 -107157 -140603 -120112 -33286 -151570 -52851 -160219 -125240 46571 -69842 -22856 8246 10820 -6798 -4169 67420 -23143 15825 -58435 188363 12415 88072 -37202 52377 99151 -52730 -9603 88617 36850 -463 -18888 -31369 27186 50952 23149 88053 41068 36344 51080 60355 29818 48934 -3979 49113 38059 11489 27685 112033 91236 75342 53695 40532 53044 62396 22016 299 6068 8295 10130 42719 25043 32438 17880 24770 10053 38455 21683 27827 17715 17667 22745 2544 -774 -12258 8717 -8781 2852 10137 8954 4178 3597 6498 6726 5783 -796 5805 -940 3171 -3828 -6059 -3421 -274 -1344 -3470 -2119 -27 -3265 -2761 -1194 -3534 -4441 -3184 -4540 -2741 -2832 -2790 -1185 -1627 -1193 -1426 -156 175 -85 -434 583 294 876 2271 2295 2437 811 2323 1743 2407 997 258 723 279 682 -325 -38 -210 177 590 -9 -68 -321 -1025 -1545 900000 180 -776 -669 -2742 -4243 -2836 -350 -4954 -698 -5765 -3513 313 -1824 -474 152 214 -170 -103 820 -616 264 -1871 1026 221 766 -1025 558 622 -1477 -220 1002 797 -15 -695 -1182 595 984 674 1630 1326 1277 1586 1687 1058 1410 -187 1474 1357 571 1345 2782 3040 3172 2925 2577 3062 3222 1520 23 430 598 826 3019 2319 2899 1898 2658 1374 4612 3320 4201 2824 2585 2782 328 -97 -1794 1222 -1789 628 2452 2510 1305 1190 2187 2328 2021 -293 1942 -313 976 -1281 -2256 -1466 -139 -819 -2538 -1732 -22 -2709 -2047 -767 -2153 -2835 -2118 -3206 -2096 -2438 -2848 -1397 -2161 -1701 -2071 -225 247 -122 -647 891 457 1307 3115 2985 3088 1014 2837 2112 3109 1523 467 1498 637 1687 -867 -107 -620 527 1759 -27 -192 -844 -2488 -3533 SS 20260327T060518.2Z 9582.253683 153 1 49.26 2 81.71 94.73 109.83 347.70 0.00 1 0.00 1 0 25 6.280e-01 1.863e-02 1.639e-01 3.217e-03 1.177528e+00 1.830764e-03 1.265077e-02 -6.000000e+00 3.590699e-01 226.49 -2.00 3.61 -2.00 322.28 0.00e+00 7.432421e-03 8.400102e-04 1.946414e-03 -6.000000e+00 1.450942e-02 274.20 -2.00 20.00 -2.00 321.94 0.00e+00 6.521 0.005 302.00 328.00 3 3.5655e-01 6.1111e-03 9.1789e-02 -6.0000e+00 8.9620e-01 1.1151e+00 9.9114e-03 6.6304e-02 -6.0000e+00 9.7673e-01 -1.4871e+00 1.1684e-02 3.9547e-02 -6.0000e+00 5.7491e-01 6.0079e-01 5.4789e-03 1.4344e-02 -6.0000e+00 2.4008e-01 1.6317e-04 -1.3255e-03 7.7866e-05 1.9421e-04 -6.0000e+00 1.7210e-02 8.4433e-03 0.0000e+00 12 8 8 10 0 0 1.95 17.43 0.16 0.00844 -0.00152 231 51 4 8 0 213.230 15.00 17.43 14.47 20.96 20.67 22.7 952.29 -45216 -124099 -102683 -184142 -201024 -213810 -224608 -145584 -253924 -184316 -249141 -188374 -118433 -102042 -86547 -89665 -21109 -74847 12259 -37950 -26247 -9913 -73059 3282 -22701 -8860 -92644 -25473 -14759 -64347 -47623 106445 14227 6271 -25423 -28493 8138 10196 13297 41269 33657 21881 25932 27332 28333 41526 8403 66754 37980 21019 22319 -51764 48250 53772 54352 34572 46072 41567 28393 13760 17797 -15981 18019 26460 26555 25551 17604 20295 13320 23463 17335 18881 13767 14451 13961 4707 3432 -4175 2697 543 4413 5913 5202 3951 2352 3625 3086 2601 -443 2729 741 2542 -2757 -3543 -3280 -2605 -1063 -2042 -1000 -833 -1758 -2240 -526 -1479 -3572 -2739 -3680 -1746 -2540 -1936 -996 -687 -1212 -891 -283 -53 -267 -255 285 212 925 1638 2189 1650 879 1517 1448 2352 447 362 760 479 248 15 39 -148 148 365 -3 -168 -370 -815 -1475 -142 -1026 -732 -2836 -3153 -3354 -3780 -1121 -5939 -2208 -5827 -2686 -1115 -1135 -1111 -1509 -211 -1430 115 -541 -322 -106 -1292 31 -285 -97 -2114 -312 -157 -1138 -924 635 259 125 -674 -723 161 221 300 919 835 655 777 819 832 1078 314 1634 1235 899 1076 -5508 2298 2669 2883 2317 2799 2585 1887 989 1208 -1641 1537 2475 2817 2857 2030 2457 1922 3533 3096 3460 2592 2475 2113 680 468 -648 461 119 1145 1801 1821 1505 887 1421 1261 1089 -190 1093 306 978 -1121 -1577 -1590 -1539 -753 -1754 -903 -781 -1585 -1945 -387 -1023 -2623 -2104 -3018 -1540 -2393 -2150 -1301 -1015 -1790 -1336 -415 -80 -384 -383 446 338 1406 2456 3068 2241 1165 1951 1831 3140 724 661 1605 1068 604 38 104 -418 424 1046 -9 -449 -956 -1916 -3251 SS 20260327T062152.1Z 9582.265186 159 1 49.21 2 78.83 97.73 110.37 351.49 0.00 1 0.00 1 0 17 8.541e-01 1.039e-02 5.379e-02 1.131e-03 9.517676e-01 6.086300e-04 1.050391e-02 -6.000000e+00 4.884227e-01 226.49 -2.00 3.61 -2.00 321.52 0.00e+00 6.955955e-03 2.495846e-04 1.139027e-03 -6.000000e+00 1.973514e-02 274.20 -2.00 20.00 -2.00 321.21 0.00e+00 4.983 0.002 302.00 328.00 3 3.6615e-01 1.8643e-03 7.1462e-02 -6.0000e+00 1.2191e+00 2.8693e-01 3.0044e-03 5.3096e-02 -6.0000e+00 1.3286e+00 -3.6188e-01 3.7675e-03 3.1099e-02 -6.0000e+00 7.8200e-01 1.4629e-01 1.8017e-03 1.0748e-02 -6.0000e+00 3.2659e-01 9.3159e-04 -6.5022e-04 2.7847e-05 1.2484e-04 -6.0000e+00 2.3408e-02 7.9429e-03 0.0000e+00 12 8 8 10 0 0 12.98 17.44 0.15 0.00794 0.00306 588 129 2 8 0 83.680 15.00 17.44 15.65 20.96 20.67 22.6 958.43 -290057 -245581 -269039 -231678 -292623 -264846 -274865 -254022 -255942 -259539 -234471 -246511 -180987 -184576 -113487 -125120 -96608 -101982 -80723 -57260 -86056 -67200 -86083 -51414 -70155 -52511 -72198 -57850 -60142 -63389 -40143 -26261 -7587 -26921 -16031 -28619 -14582 -12584 -7103 3654 1572 5518 1161 12673 841 9427 4708 8169 10530 6858 13117 10459 15522 9796 11884 8494 8220 5736 3413 3110 2579 3528 5417 9347 6047 6898 4254 3947 4606 4123 3954 2996 1965 892 935 -1809 -1923 -3178 -1627 -767 -267 234 -1692 -1001 -1322 -529 -110 308 575 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