File name: Pandora138s1_Milan-MIBI_20260414_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260414T233843.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260414_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260414 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260414T090154.8Z 9600.376329 206 1 41.60 2 47.09 128.73 52.42 183.52 0.00 1 0.00 1 0 17 1.628e-02 7.745e-03 5.476e-03 2.345e-03 2.602626e-01 1.194700e-03 3.215049e-03 -6.000000e+00 9.382479e-03 227.91 -2.00 3.61 -2.00 316.59 0.00e+00 2.433932e-04 1.315642e-04 4.655966e-05 -6.000000e+00 3.770382e-04 276.30 -2.00 20.00 -2.00 316.27 0.00e+00 1.466 0.000 302.00 328.00 3 6.0058e+00 3.1174e-03 2.0022e-02 -6.0000e+00 2.3497e-02 4.4790e-02 3.4760e-03 1.3586e-02 -6.0000e+00 2.5576e-02 -8.4729e-03 2.0529e-03 6.7493e-03 -6.0000e+00 1.5029e-02 -2.7645e-03 9.8283e-04 1.9256e-03 -6.0000e+00 6.3179e-03 2.1784e-04 -3.4368e-04 6.7247e-05 2.2476e-05 -6.0000e+00 4.4937e-04 -8.1116e-03 0.0000e+00 12 9 1 12 41 1 99.02 18.47 0.14 -0.00811 -0.01069 10 3 1 8 0 3781.530 15.00 18.47 22.16 21.79 21.48 23.0 996.47 900000 1575 -532 -2992 -2455 -8482 -4770 -3658 -4113 714 -7854 -1603 980 -284 -1287 37 689 1844 650 3599 513 523 2089 -59 1599 937 -453 858 1544 -334 878 3361 1541 -118 -3805 -1037 -2172 -891 79 -1495 -623 -844 -540 59 -92 -205 -1525 -606 -1128 -167 -401 3093 996 1202 925 689 734 -45 180 296 348 4929 1093 1942 254 -421 -410 -1279 -356 950 -370 247 -295 450 -41 -570 53 -1689 -68 -1929 -1036 -1225 -2130 -1371 -1124 -231 -96 246 -19 652 631 960 -534 -214 -175 -158 122 858 574 101 -264 -996 -63 -327 -679 -1104 -594 -461 -270 625 645 388 579 343 -51 537 159 -209 542 367 -123 458 323 171 -41 273 -228 630 324 55 5 -580 -363 -132 71 -190 103 346 173 86 -234 -485 -421 900000 246 -90 -506 -376 -1268 -701 -578 -720 129 -1561 -299 192 -63 -325 10 199 545 201 1118 168 171 677 -20 564 344 -171 312 525 -111 297 1182 584 -48 -1548 -393 -860 -388 39 -852 -384 -543 -356 40 -61 -136 -1016 -395 -726 -106 -262 2063 705 880 702 531 574 -35 141 228 271 3855 930 1730 233 -372 -344 -1045 -293 835 -352 245 -297 443 -39 -510 44 -1353 -54 -1659 -958 -1214 -2244 -1483 -1257 -269 -116 305 -23 800 744 1068 -568 -219 -182 -173 143 1065 749 133 -339 -1222 -73 -381 -832 -1416 -779 -622 -374 893 955 586 864 493 -70 703 206 -275 737 523 -179 665 464 241 -56 363 -294 801 425 76 7 -843 -534 -197 109 -303 167 569 287 141 -377 -769 -655 SS 20260414T090920.5Z 9600.381487 210 1 41.53 2 46.09 130.84 52.50 185.80 0.00 1 0.00 1 0 17 1.293e-02 6.557e-03 3.946e-03 1.823e-03 2.547786e-01 9.301367e-04 3.173793e-03 -6.000000e+00 7.452560e-03 227.91 -2.00 3.61 -2.00 316.38 0.00e+00 5.556974e-04 9.754152e-05 4.173886e-05 -6.000000e+00 2.995380e-04 276.30 -2.00 20.00 -2.00 316.07 0.00e+00 1.440 0.000 302.00 328.00 3 5.6124e+00 2.4219e-03 1.9660e-02 -6.0000e+00 1.8664e-02 4.3081e-02 2.6988e-03 1.3351e-02 -6.0000e+00 2.0316e-02 -9.0820e-03 1.5801e-03 6.6317e-03 -6.0000e+00 1.1938e-02 -2.8416e-03 7.4707e-04 1.8882e-03 -6.0000e+00 5.0177e-03 3.3452e-04 -4.8709e-04 5.2231e-05 2.2642e-05 -6.0000e+00 3.5700e-04 -6.8937e-03 0.0000e+00 12 9 1 12 1 1 43.53 18.49 0.14 -0.00689 -0.01055 14 4 1 8 0 2768.480 15.00 18.49 22.45 21.88 21.48 23.2 999.16 900000 -1169 -2029 -5232 -4894 -4315 -2077 -2962 -1353 133 -4844 -3395 -513 -1403 1254 -394 480 1036 830 2382 784 1677 1426 2535 -1437 970 -569 222 1038 109 2197 1930 2322 399 -2573 -1264 -781 -405 110 -11 -925 -511 39 -935 -28 135 -233 -68 -978 -328 729 -2208 1218 1510 1046 614 1211 21 302 115 853 1436 1207 1695 471 -406 -267 -823 -131 945 -244 286 -91 483 -117 -798 -279 -1308 -699 -917 -1343 -1074 -1952 -1511 -974 -511 128 -145 273 578 631 766 -101 -24 250 -111 569 886 492 214 -613 -611 -328 -87 -635 -1124 -695 -581 -245 498 342 376 285 180 189 240 311 103 503 228 -257 290 366 108 130 478 -201 1076 658 161 38 -316 -157 -116 -233 -168 -373 409 7 34 -261 -345 -344 900000 -209 -383 -1000 -848 -689 -330 -515 -254 27 -1020 -704 -111 -343 336 -118 150 332 275 805 275 581 499 910 -553 379 -229 87 378 38 782 729 928 169 -1096 -510 -323 -184 57 -7 -590 -339 26 -646 -20 92 -159 -46 -649 -215 485 -1571 883 1131 807 482 962 17 241 91 677 1178 1042 1535 437 -366 -227 -682 -109 840 -235 286 -92 479 -112 -724 -236 -1059 -566 -794 -1255 -1069 -2062 -1635 -1090 -596 155 -179 339 710 746 857 -108 -24 258 -121 661 1098 640 280 -783 -746 -383 -101 -778 -1434 -909 -780 -337 706 503 561 421 257 258 312 399 135 681 322 -372 417 522 151 177 630 -258 1354 855 220 53 -455 -228 -171 -355 -265 -599 662 12 55 -416 -540 -530 SS 20260414T091422.4Z 9600.384981 212 1 48.14 2 45.43 132.31 52.57 187.34 0.00 1 0.00 1 0 17 1.332e-02 7.237e-03 3.644e-03 1.680e-03 2.531479e-01 8.572686e-04 3.152541e-03 -6.000000e+00 7.677317e-03 227.91 -2.00 3.61 -2.00 316.38 0.00e+00 5.284165e-04 8.988631e-05 4.149934e-05 -6.000000e+00 3.085128e-04 276.30 -2.00 20.00 -2.00 316.07 0.00e+00 1.423 0.000 302.00 328.00 3 5.6699e+00 2.2325e-03 1.9478e-02 -6.0000e+00 1.9227e-02 4.5789e-02 2.4869e-03 1.3260e-02 -6.0000e+00 2.0928e-02 -8.5559e-03 1.4572e-03 6.5872e-03 -6.0000e+00 1.2297e-02 -3.0008e-03 6.8973e-04 1.8760e-03 -6.0000e+00 5.1698e-03 3.2136e-04 -4.8467e-04 4.8167e-05 2.2463e-05 -6.0000e+00 3.6770e-04 -8.1612e-03 0.0000e+00 11 8 0 10 0 0 94.45 18.51 0.09 -0.00816 -0.01180 18 4 1 8 0 2674.340 14.98 18.51 22.76 21.88 21.48 23.2 1001.08 900000 1497 -89 -4074 -1742 -5803 -3308 -566 -2720 -1243 -6633 -647 -360 556 499 795 497 163 524 2805 1131 76 949 2327 2336 866 -371 -561 649 653 381 2279 1252 0 -3917 -1522 -1381 -958 -46 -868 -674 -1025 -652 -986 452 -29 -1155 -1496 -880 -499 265 2277 561 1064 597 455 757 87 624 -176 694 4134 1310 1812 525 -503 -200 -583 229 857 -314 547 -506 755 153 -242 -511 -1221 -517 -1304 -987 -1442 -1797 -1513 -1120 -782 156 28 77 442 341 895 -235 -42 227 161 417 776 455 218 -361 -950 -188 -384 -591 -1151 -829 -700 -289 516 367 470 388 289 135 501 341 69 469 12 -162 -105 504 277 420 354 -57 859 602 38 -191 -33 -203 -314 -4 -208 -286 412 340 -226 -199 -499 -307 900000 261 -17 -771 -294 -944 -534 -96 -521 -252 -1421 -131 -78 134 135 236 156 53 174 942 394 27 332 834 870 339 -149 -219 237 230 137 859 504 0 -1679 -613 -572 -437 -24 -510 -430 -684 -443 -682 311 -20 -794 -1014 -584 -328 177 1568 408 800 463 359 603 70 496 -139 549 3320 1129 1635 486 -453 -170 -482 191 765 -302 545 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