File name: Pandora138s1_Milan-MIBI_20260619_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260619T233802.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260619_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260619T044403.8Z 9666.197266 77 1 49.05 2 80.18 66.46 118.35 22.90 0.00 1 0.00 1 0 25 1.283e+00 4.952e-02 3.988e-01 6.121e-03 7.467981e-01 3.409631e-03 8.585062e-03 -6.000000e+00 7.550114e-01 233.01 -2.00 3.61 -2.00 321.59 0.00e+00 4.028477e-02 1.369304e-03 8.142584e-04 -6.000000e+00 3.102739e-02 283.53 -2.00 20.00 -2.00 321.26 0.00e+00 5.599 0.003 302.00 328.00 3 2.7712e+00 1.0408e-02 6.9664e-02 -6.0000e+00 1.9194e+00 9.1535e-01 1.4434e-02 4.2514e-02 -6.0000e+00 2.0830e+00 -1.2902e+00 1.7840e-02 2.3074e-02 -6.0000e+00 1.2166e+00 5.5043e-01 8.9051e-03 7.5742e-03 -6.0000e+00 5.0110e-01 4.8917e-05 -3.2404e-03 1.7590e-04 1.0126e-04 -6.0000e+00 3.5739e-02 -2.6315e-03 0.0000e+00 12 9 8 11 8 0 42.24 19.05 0.24 -0.00263 -0.02698 47 10 4 8 0 1043.470 15.00 19.05 33.58 22.29 21.88 24.4 1061.53 186982 644833 323035 221788 189930 100558 187626 117545 146431 900000 56863 199647 168416 900000 223004 211513 267311 189054 197578 900000 172479 280308 222515 291512 222244 71883 626610 395062 900000 45078 100205 193449 136749 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794 1990 337 -547 170 1996 1568 -625 -658 586 270 -62 2947 1803 2099 -1281 -3551 -2637 -2524 50 -1041 1376 2658 4124 2934 905 322 -2346 -3191 -5064 -3953 -3583 -1043 -2974 -1802 -2815 -3309 -2790 -3396 -1975 -2755 -402 -806 1044 2800 1737 1968 1539 1785 1508 2616 2225 4239 3590 3756 4267 2094 462 -905 -818 -85 -1880 -661 -1322 -2408 -2837 SS 20260619T045212.4Z 9666.202922 81 1 49.26 2 78.86 67.81 117.83 24.96 0.00 1 0.00 1 0 17 5.189e-01 1.233e-02 1.621e-01 3.657e-03 6.982161e-01 1.999323e-03 7.905026e-03 -6.000000e+00 3.050202e-01 233.01 -2.00 3.61 -2.00 321.27 0.00e+00 7.494991e-03 7.591958e-04 6.913765e-04 -6.000000e+00 1.250624e-02 283.53 -2.00 20.00 -2.00 320.94 0.00e+00 4.994 0.002 302.00 328.00 3 2.8297e+00 6.0610e-03 6.2999e-02 -6.0000e+00 7.7447e-01 1.1887e-01 8.3711e-03 3.9531e-02 -6.0000e+00 8.4037e-01 -2.7063e-01 9.7027e-03 2.1529e-02 -6.0000e+00 4.9057e-01 1.1632e-01 4.8166e-03 6.9856e-03 -6.0000e+00 2.0425e-01 1.1213e-04 -1.2978e-03 1.0570e-04 8.3248e-05 -6.0000e+00 1.4585e-02 -3.6176e-03 0.0000e+00 12 8 8 10 0 0 -16.24 19.05 0.29 -0.00362 -0.01337 79 17 4 8 0 623.460 15.00 19.05 34.15 22.29 21.88 24.4 1064.30 900000 -226323 -69069 -226809 900000 -199783 -118814 -154663 -177270 900000 -199162 236830 -116998 -21208 -63341 -17512 -19343 -41319 47062 2787 61639 -49583 14413 -29770 59052 1058 -2315 -19406 -34094 5171 -26895 75361 -10702 3203 -12407 19279 9064 -4609 17231 -22585 18215 -5633 15903 7027 18219 11175 5456 9986 4869 12482 2652 19929 3302 10805 10926 7280 4025 2093 3148 1711 4186 -2609 3927 6213 5034 3884 4556 466 1059 6937 400 4431 -427 1755 -350 -2255 -3058 -2747 -2320 -3520 -665 -2948 -121 -2239 -309 -1547 155 27 -179 2861 473 1748 -1730 -587 -1715 -1277 435 -457 452 -494 200 -1225 204 -725 -1149 -2226 -854 -1185 -813 578 -54 419 -475 585 -266 188 394 -190 275 -244 175 11 976 346 860 427 396 1526 149 437 175 112 0 332 -47 -233 -241 472 -242 -382 -217 -567 61 900000 -4572 -358 -5390 900000 -3431 -924 -1854 -2930 900000 -4647 844 -1630 -151 -903 -199 -263 -790 412 41 519 -1269 196 -666 574 19 -45 -447 -895 97 -828 1026 -409 120 -547 594 326 -218 787 -1704 1151 -452 1096 555 1321 896 480 872 471 1194 309 2202 477 1582 1717 1235 727 389 566 305 742 -536 860 1524 1370 1075 1232 134 300 2125 148 1679 -171 661 -124 -733 -996 -880 -807 -1356 -296 -1555 -69 -1407 -203 -1103 107 19 -131 1982 340 1156 -1128 -380 -1234 -986 386 -475 523 -557 229 -1305 192 -665 -1123 -2349 -935 -1396 -971 761 -81 673 -739 941 -412 275 573 -289 440 -388 298 19 1532 529 1253 604 542 2093 231 770 321 222 -1 696 -105 -559 -594 1177 -611 -937 -500 -1234 135 SS 20260619T050021.6Z 9666.208583 85 1 49.22 2 77.54 69.16 117.26 27.00 0.00 1 0.00 1 0 17 3.431e-01 7.165e-03 1.257e-01 2.340e-03 6.446962e-01 1.249339e-03 7.353642e-03 -6.000000e+00 2.013244e-01 233.01 -2.00 3.61 -2.00 320.90 0.00e+00 4.845140e-03 4.431971e-04 5.536258e-04 -6.000000e+00 7.946466e-03 283.53 -2.00 20.00 -2.00 320.58 0.00e+00 4.501 0.002 302.00 328.00 3 2.5956e+00 3.6862e-03 5.7156e-02 -6.0000e+00 5.1039e-01 -3.7939e-03 4.8799e-03 3.6089e-02 -6.0000e+00 5.5353e-01 -7.4714e-02 5.5445e-03 1.9402e-02 -6.0000e+00 3.2394e-01 2.8919e-02 2.8118e-03 6.1901e-03 -6.0000e+00 1.3463e-01 2.4016e-04 -7.9235e-04 6.7143e-05 7.0121e-05 -6.0000e+00 9.4819e-03 -3.6788e-03 0.0000e+00 11 8 0 10 0 0 16.54 19.05 0.09 -0.00368 -0.00963 124 27 4 8 0 396.900 15.00 19.05 34.50 22.29 21.88 24.3 1065.66 900000 -147581 -11311 -160865 -20477 -165098 -110757 -140367 -99808 24007 -137163 1288 -85978 -23635 -56527 -59061 -42818 -6930 -22264 -2453 -3881 -21183 -5618 -32791 2796 -22933 -4166 -15909 -2684 -26362 -25440 24520 -8385 2278 -13017 6235 -10354 -7991 4861 -5555 4863 2442 3378 -763 6036 2056 2097 1147 3909 2661 2445 1094 1113 4707 5092 1890 1526 175 93 -1298 2614 -398 2473 3224 3270 1688 2609 403 1503 2987 -18 1245 -329 1033 -970 -1141 -2066 -1015 -1494 -1128 -2012 -1845 -1002 -1636 -693 -1045 320 -65 769 1018 1027 1061 -637 389 -292 65 142 611 76 -246 -76 -503 24 -152 -1194 -1741 -883 -976 -27 456 171 330 -120 397 -281 378 241 12 348 -334 -311 173 161 117 588 18 320 1012 493 83 51 30 -55 58 -203 -120 -197 360 -114 -170 -58 -287 38 900000 -1590 -39 -2304 -74 -2230 -944 -1736 -955 79 -2153 6 -1108 -223 -910 -1201 -868 -113 -459 -45 -76 -495 -117 -936 62 -679 -108 -459 -67 -858 -950 701 -374 103 -680 266 -550 -475 305 -460 421 234 343 -85 640 234 246 139 487 353 354 179 201 898 1030 413 343 40 21 -296 584 -98 671 978 1066 559 836 134 531 1180 -8 585 -159 478 -429 -460 -779 -376 -594 -515 -1072 -1108 -659 -1146 -508 -818 259 -55 652 843 814 791 -463 280 -228 57 139 670 91 -303 -90 -563 25 -153 -1279 -1965 -1029 -1206 -35 641 261 533 -197 636 -436 563 356 18 556 -556 -523 282 257 184 885 27 461 1465 768 142 93 59 -110 122 -445 -273 -460 843 -271 -395 -129 -623 80 SS 20260619T050545.7Z 9666.212334 87 1 49.33 2 76.65 70.04 116.86 28.34 0.00 1 0.00 1 0 17 2.392e-01 6.382e-03 7.141e-02 1.814e-03 6.085122e-01 9.606074e-04 6.989728e-03 -6.000000e+00 1.403638e-01 233.01 -2.00 3.61 -2.00 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