File name: Pandora138s1_Milan-MIBI_20260621_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260621T235409.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260621_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260621T045230.7Z 9668.203133 83 1 49.17 2 78.87 67.78 133.33 0.49 0.00 1 0.00 1 0 17 5.306e-01 1.193e-02 2.494e-01 5.078e-03 7.230130e-01 2.779587e-03 8.116088e-03 -6.000000e+00 3.125721e-01 233.03 -2.00 3.61 -2.00 321.34 0.00e+00 8.927735e-03 1.074399e-03 7.462514e-04 -6.000000e+00 1.282641e-02 283.71 -2.00 20.00 -2.00 321.00 0.00e+00 4.998 0.002 302.00 328.00 3 3.3453e+00 8.4452e-03 6.3943e-02 -6.0000e+00 7.9385e-01 1.4095e-01 1.1948e-02 4.0976e-02 -6.0000e+00 8.6099e-01 -2.3533e-01 1.4202e-02 2.2541e-02 -6.0000e+00 5.0249e-01 9.2287e-02 7.0031e-03 7.3884e-03 -6.0000e+00 2.0729e-01 6.2425e-05 -1.0836e-03 1.4562e-04 8.7377e-05 -6.0000e+00 1.4972e-02 -1.5799e-03 0.0000e+00 12 8 8 10 0 0 -30.52 19.03 0.25 -0.00158 -0.00972 44 10 4 8 0 1117.330 15.00 19.03 32.32 22.29 21.88 24.4 1053.06 -65806 -143967 -172618 -217148 900000 -227024 -165861 -212921 900000 -180042 -147651 -91142 900000 -59836 -50212 69121 -53926 -54286 -54036 146707 -58646 -32518 -23718 -35399 55157 -29434 122030 -30997 47885 -63713 -48903 39770 11292 -13192 -36512 44380 -5817 7812 9251 -13667 2407 10873 14191 11221 23151 16012 5532 5090 13330 4143 10852 -4376 3956 7047 11295 -777 6330 -692 -1934 2870 -1901 43004 4071 6213 300 4071 6039 -1681 1178 6449 2309 -82 -829 747 2120 -2959 -4736 1512 -5392 -1596 -3494 -1875 -1421 630 -1898 -723 1005 -52 730 2476 2270 -536 -2711 -1425 -1243 -1480 644 473 919 -161 -510 -244 -928 1010 -1663 -1982 -1589 -1369 -261 565 373 329 -182 -355 -192 774 634 -331 97 -198 -400 852 271 713 72 449 908 839 130 39 341 133 43 -89 -128 -177 -358 618 -139 -199 -17 -682 154 -326 -1007 -1819 -3632 900000 -3678 -1552 -3354 900000 -2451 -1542 -608 900000 -506 -508 342 -848 -964 -1067 726 -1360 -587 -400 -701 486 -604 611 -671 490 -2007 -1606 699 309 -511 -1754 975 -214 291 404 -879 152 690 931 798 1522 1160 458 443 1132 409 1111 -579 533 1008 1664 -133 1038 -122 -339 475 -334 5401 828 1423 79 1044 1499 -462 336 2003 828 -32 -329 279 731 -964 -1457 438 -1822 -613 -1598 -960 -803 373 -1216 -486 702 -38 532 1752 1525 -348 -1720 -909 -857 -1170 574 483 1031 -187 -572 -253 -885 916 -1629 -2057 -1714 -1567 -317 751 545 514 -292 -560 -293 1135 925 -504 154 -327 -661 1364 422 1078 106 641 1260 1187 203 67 641 267 89 -195 -295 -427 -880 1533 -348 -487 -39 -1536 333 SS 20260621T050036.1Z 9668.208751 87 1 49.32 2 77.56 69.11 133.32 3.16 0.00 1 0.00 1 0 17 4.005e-01 8.400e-03 1.313e-01 2.937e-03 6.629247e-01 1.564429e-03 7.515368e-03 -6.000000e+00 2.349172e-01 233.03 -2.00 3.61 -2.00 320.96 0.00e+00 5.792510e-03 5.630148e-04 5.862648e-04 -6.000000e+00 9.253840e-03 283.71 -2.00 20.00 -2.00 320.64 0.00e+00 4.508 0.002 302.00 328.00 3 2.9637e+00 4.6437e-03 5.7870e-02 -6.0000e+00 5.9556e-01 4.7397e-02 6.1792e-03 3.7102e-02 -6.0000e+00 6.4557e-01 -1.3428e-01 7.0286e-03 2.0042e-02 -6.0000e+00 3.7809e-01 5.4388e-02 3.5572e-03 6.4287e-03 -6.0000e+00 1.5603e-01 1.5775e-04 -7.4696e-04 8.3239e-05 7.1144e-05 -6.0000e+00 1.0991e-02 -2.2798e-03 0.0000e+00 11 8 0 10 0 0 20.17 19.03 0.19 -0.00228 -0.00789 83 18 4 8 0 594.240 15.00 19.03 32.88 22.19 21.88 24.4 1056.16 -31298 -128617 -167111 -121388 -109917 -158178 -164948 -153578 -94503 -46116 -140522 -77099 -107973 -106734 -32088 -46542 1866 -44290 -18581 -11431 -26947 -12929 -26596 5259 -12011 -5415 -17062 -2712 -19061 -9595 -24041 20810 -1339 -978 -5901 -7836 7741 -12436 4094 -6921 3080 1747 2428 12009 4826 6369 -2682 5361 -1791 2055 3971 12948 5725 2006 5477 -207 1995 -1075 1186 -1932 2554 -1156 3287 5284 1923 4249 1089 -1001 450 4563 455 1975 -285 148 -216 -3205 -813 -1564 -1457 -2720 -1804 -2038 -1554 -1185 -1435 -197 151 902 524 2411 1119 1037 -1287 -531 -178 -797 343 42 258 1 -68 -833 -520 -72 -1353 -1252 -1247 -543 -299 466 170 516 38 160 46 77 439 -53 334 -342 -285 225 379 332 505 36 -221 1354 151 190 77 86 -96 78 -98 -235 -153 447 -156 -170 -148 -212 -31 -90 -1216 -2394 -1252 -945 -1895 -2191 -2200 -839 -277 -2086 -729 -1732 -2029 -414 -867 25 -969 -383 -236 -618 -285 -623 105 -306 -137 -458 -69 -511 -272 -845 626 -54 -44 -281 -367 331 -751 254 -582 271 170 250 1179 522 698 -305 635 -219 258 538 1808 950 378 1071 -45 435 -244 258 -426 549 -279 861 1549 635 1368 355 -339 161 1801 195 888 -132 65 -89 -1323 -300 -574 -580 -1194 -928 -1212 -1027 -833 -1078 -146 118 725 427 1888 898 775 -935 -384 -140 -678 335 48 303 1 -79 -951 -534 -71 -1445 -1424 -1492 -644 -385 662 253 825 63 255 70 118 666 -84 523 -568 -476 362 586 530 770 53 -316 1932 243 323 145 165 -193 166 -224 -536 -360 1063 -375 -396 -344 -465 -65 SS 20260621T050600.3Z 9668.212504 89 1 49.22 2 76.67 70.00 133.28 4.94 0.00 1 0.00 1 0 17 2.866e-01 7.975e-03 8.451e-02 2.190e-03 6.262001e-01 1.159694e-03 7.172029e-03 -6.000000e+00 1.681305e-01 233.03 -2.00 3.61 -2.00 320.71 0.00e+00 4.697261e-03 3.927357e-04 4.975015e-04 -6.000000e+00 6.623108e-03 283.71 -2.00 20.00 -2.00 320.39 0.00e+00 4.229 0.001 302.00 328.00 3 2.7662e+00 3.3809e-03 5.4375e-02 -6.0000e+00 4.2624e-01 1.8034e-02 4.3400e-03 3.4788e-02 -6.0000e+00 4.6204e-01 -8.2886e-02 4.7854e-03 1.8490e-02 -6.0000e+00 2.7060e-01 2.9568e-02 2.4586e-03 5.8245e-03 -6.0000e+00 1.1167e-01 2.5986e-04 -6.3254e-04 6.2324e-05 6.4870e-05 -6.0000e+00 7.8662e-03 -2.1744e-03 0.0000e+00 11 8 0 10 0 0 -33.80 19.04 0.12 -0.00217 -0.00693 114 25 4 8 0 431.720 15.00 19.04 33.25 22.29 21.88 24.4 1059.39 -59741 -127731 -93799 -138919 -35302 -87303 -107371 -69332 -104908 -23730 -109284 -50171 -72639 -52680 -14242 -19157 -2619 -32587 14678 -14801 329 -20204 -7185 -12362 -3861 2049 -13581 -1244 -9268 -8189 -16526 16022 333 -409 -5889 3254 2984 -3569 8336 -6972 3932 -2160 1666 2170 4755 5683 1853 4755 3809 4709 4736 -20258 1713 3521 3027 1442 2405 -180 930 -1848 3165 -215 2830 3821 2558 2407 1871 941 1537 3261 -160 1647 -589 907 -469 -1552 -404 -1649 -261 -1712 -1410 -1777 -1568 -1838 -1324 -448 342 455 498 1935 660 935 -830 -102 -253 -323 274 574 130 266 95 -594 -333 347 -1335 -1543 -1065 -607 -334 384 170 363 -74 155 -119 42 205 166 193 -137 -461 90 464 137 245 210 -18 1359 380 206 -122 -62 -45 151 -59 -249 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