File name: Pandora138s1_Milan-MIBI_20260627_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260627T234638.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260627_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260627T051508.3Z 9674.218846 147 1 49.73 2 75.45 71.38 130.38 271.60 0.00 1 0.00 1 0 17 1.675e-01 1.127e-02 9.129e-02 3.238e-03 5.147339e-01 1.689941e-03 6.034637e-03 -6.000000e+00 9.828856e-02 233.08 -2.00 3.61 -2.00 320.18 0.00e+00 5.669214e-03 4.920881e-04 3.177663e-04 -6.000000e+00 3.871136e-03 284.26 -2.00 20.00 -2.00 319.87 0.00e+00 3.898 0.001 302.00 328.00 3 3.9687e+00 4.7950e-03 4.7816e-02 -6.0000e+00 2.4921e-01 2.3169e-02 5.7286e-03 2.8331e-02 -6.0000e+00 2.7013e-01 -5.8556e-02 5.6004e-03 1.4553e-02 -6.0000e+00 1.5820e-01 1.8454e-02 2.9646e-03 4.4133e-03 -6.0000e+00 6.5278e-02 1.1951e-04 -6.6160e-04 9.4295e-05 4.8210e-05 -6.0000e+00 4.5978e-03 -2.1545e-03 0.0000e+00 12 8 8 10 0 0 -12.12 19.03 0.23 -0.00215 -0.00713 39 9 4 8 0 1275.100 15.00 19.03 35.77 22.19 21.88 24.5 1072.25 -76189 69362 -100758 -34623 -41450 -41740 -55206 -59082 -12045 12017 -31390 -23858 12976 -18424 15802 -5815 14143 -9816 2427 28650 -2992 8432 -156 20879 -4023 536 -3575 8035 10035 -6820 -1687 8577 16545 -7988 1293 8307 3912 -1569 5532 -4844 -782 2465 -1896 6149 1628 7221 685 4476 3574 3249 3491 -28515 5210 932 4016 -530 2483 -1877 -311 -1250 1451 246 2568 6245 909 2590 1572 167 1381 2508 863 948 12 840 276 -1702 -649 -1700 -377 -636 -2604 -1669 -2020 -124 -1285 19 -265 150 -16 1266 1015 1172 -859 -322 739 -637 1127 232 894 152 152 -175 -646 64 -1250 -1113 -1535 -106 -648 579 256 240 186 -277 -353 -189 568 -202 353 -183 -225 11 -22 370 -144 460 -112 1324 342 68 30 554 57 -39 8 -446 -149 468 -406 -150 47 -168 -37 -1180 329 -2621 -499 -592 -566 -870 -1054 -153 132 -539 -402 183 -438 339 -184 418 -397 95 935 -137 350 -7 824 -209 28 -200 401 481 -394 -104 559 1146 -760 112 650 339 -162 638 -724 -128 420 -357 1113 315 1353 140 895 740 701 803 -9563 1409 281 1238 -175 825 -651 -105 -421 487 89 1011 2651 427 1181 694 75 643 1289 498 577 7 504 157 -905 -317 -810 -188 -360 -1706 -1203 -1587 -101 -1114 17 -254 147 -16 1230 941 1019 -720 -265 639 -613 1193 274 1136 197 190 -206 -715 70 -1439 -1344 -1940 -139 -899 850 402 391 304 -443 -543 -280 829 -303 552 -299 -375 17 -36 579 -219 677 -161 1889 526 112 53 1013 108 -77 17 -947 -322 1025 -901 -326 99 -345 -73 SS 20260627T052311.5Z 9674.224438 151 1 49.56 2 74.11 72.69 131.74 273.02 0.00 1 0.00 1 0 17 1.069e-01 6.513e-03 4.420e-02 2.291e-03 4.807471e-01 1.191966e-03 5.663399e-03 -6.000000e+00 6.273172e-02 233.08 -2.00 3.61 -2.00 319.86 0.00e+00 1.358279e-03 3.173521e-04 2.625279e-04 -6.000000e+00 2.470588e-03 284.26 -2.00 20.00 -2.00 319.54 0.00e+00 3.589 0.001 302.00 328.00 3 3.7172e+00 3.3408e-03 4.4204e-02 -6.0000e+00 1.5906e-01 -2.7196e-02 3.9138e-03 2.6321e-02 -6.0000e+00 1.7240e-01 -4.8244e-03 3.5667e-03 1.3355e-02 -6.0000e+00 1.0097e-01 -4.2793e-03 1.9010e-03 3.9753e-03 -6.0000e+00 4.1664e-02 2.1892e-04 -3.8747e-04 6.7057e-05 4.3707e-05 -6.0000e+00 2.9344e-03 -2.4366e-03 0.0000e+00 11 8 0 10 0 0 10.97 19.03 0.24 -0.00244 -0.00535 62 14 4 8 0 799.370 15.00 19.03 36.31 22.19 21.88 24.6 1076.09 -24567 -23910 -42660 -52534 3268 -54960 -23388 -55814 -14509 -14502 -31278 -5719 -22035 -13819 -3542 -129 -7046 5104 -12746 10193 -6861 -1609 6694 1169 1433 -5573 4457 -5358 4268 -8110 -6898 6407 2405 123 -5698 4552 -3698 -1435 -1131 -1387 -2192 746 -68 -516 2381 -338 -677 -369 492 -515 1000 11845 965 1529 1437 905 518 -143 -526 108 634 -1813 1499 1747 353 508 434 -1404 979 1696 -80 248 -666 321 -286 -691 -1154 -1326 -1002 -785 -1903 -1991 -2018 -967 -983 -680 636 224 907 851 1201 1059 -170 498 486 42 684 755 573 -204 -341 -780 -584 167 -1014 -1098 -714 -766 82 324 395 168 201 280 -171 408 200 461 348 -111 -536 -84 -2 -48 477 -93 161 794 351 91 -37 -293 -90 37 -350 -222 -256 497 -13 14 -224 -78 136 -294 -340 -806 -1110 40 -1038 -371 -1247 -245 -271 -724 -108 -573 -407 -115 -5 -318 222 -717 484 -404 -91 356 71 93 -414 311 -406 280 -606 -565 528 235 12 -603 456 -393 -173 -164 -245 -449 160 -15 -122 555 -82 -167 -92 123 -135 277 3255 297 506 507 333 198 -56 -202 40 241 -758 674 871 189 265 216 -707 508 992 -50 164 -450 208 -174 -411 -627 -693 -548 -491 -1294 -1540 -1721 -866 -876 -651 636 234 954 876 1153 941 -153 435 452 41 761 894 747 -273 -434 -918 -670 187 -1159 -1342 -912 -1038 111 476 634 270 322 455 -261 583 282 672 540 -184 -909 -138 -3 -74 703 -141 233 1142 518 148 -62 -522 -166 71 -682 -459 -547 1076 -26 29 -458 -153 270 SS 20260627T053007.8Z 9674.229257 154 1 49.38 2 72.95 73.83 132.90 274.28 0.00 1 0.00 1 0 17 7.396e-02 5.535e-03 2.487e-02 1.822e-03 4.511212e-01 9.419337e-04 5.358703e-03 -6.000000e+00 4.339192e-02 233.08 -2.00 3.61 -2.00 319.51 0.00e+00 1.636205e-03 2.254240e-04 2.146661e-04 -6.000000e+00 1.708919e-03 284.26 -2.00 20.00 -2.00 319.19 0.00e+00 3.359 0.001 302.00 328.00 3 3.5629e+00 2.6177e-03 4.1373e-02 -6.0000e+00 1.1002e-01 -1.4871e-02 3.0054e-03 2.4583e-02 -6.0000e+00 1.1925e-01 -1.3814e-02 2.5215e-03 1.2355e-02 -6.0000e+00 6.9840e-02 -5.2235e-04 1.3519e-03 3.6317e-03 -6.0000e+00 2.8819e-02 3.2655e-04 -4.9327e-04 5.3120e-05 3.8816e-05 -6.0000e+00 2.0297e-03 -2.4412e-03 0.0000e+00 10 0 0 10 0 0 8.60 19.04 0.18 -0.00244 -0.00615 76 17 4 8 0 649.650 15.00 19.04 36.80 22.29 21.88 24.6 1079.11 -22692 -20862 -32939 -26829 -23041 -34484 -22329 -31384 -9388 -14634 -18735 -16593 -14252 -6655 -7003 -4054 -3577 -2645 -4257 7003 -1166 3406 893 80 -1307 -3474 223 -2749 -1881 -5362 -2021 1816 1244 -934 -1542 427 -953 -1305 -134 -1887 -2118 -1430 -638 1343 1806 911 -505 886 390 -540 1312 593 1336 1822 1319 536 834 -396 153 -363 799 631 1830 2599 317 147 985 -514 1205 1399 102 328 -438 -41 59 -740 -467 -655 -838 -1309 -1706 -1494 -1690 -1333 -917 -482 48 45 498 989 856 940 258 471 290 -15 463 678 83 -343 -338 -718 -283 307 -1003 -1133 -821 -467 -68 532 271 217 -10 375 -80 421 448 -27 310 -192 -448 -180 124 -37 376 116 44 1043 517 61 53 -195 -232 31 47 -173 20 565 -186 -171 -154 -304 -69 -439 -428 -835 -646 -540 -774 -508 -791 -237 -390 -542 -490 -477 -252 -322 -214 -210 -167 -294 457 -86 242 66 6 -114 -328 21 -262 -169 -498 -199 197 153 -129 -211 55 -132 -192 -24 -407 -525 -379 -176 376 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