File name: Pandora138s1_Milan-MIBI_20260717_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260717T234605.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260717_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260717T061125.5Z 9694.257934 115 1 49.12 2 67.86 81.82 102.67 62.43 0.00 1 0.00 1 0 17 1.686e-02 5.506e-03 3.249e-03 6.241e-04 3.594341e-01 3.204780e-04 4.360334e-03 -6.000000e+00 9.890086e-03 233.19 -2.00 3.61 -2.00 318.06 0.00e+00 7.906770e-04 5.069443e-05 1.030941e-04 -6.000000e+00 3.895666e-04 285.97 -2.00 20.00 -2.00 317.73 0.00e+00 2.630 0.000 302.00 328.00 3 2.4150e+00 8.6163e-04 3.2577e-02 -6.0000e+00 2.5083e-02 1.2826e-02 9.6184e-04 1.9411e-02 -6.0000e+00 2.7190e-02 -5.3490e-03 6.3299e-04 9.5243e-03 -6.0000e+00 1.5922e-02 -2.8974e-03 3.2797e-04 2.6867e-03 -6.0000e+00 6.5652e-03 2.2560e-03 -2.4445e-04 1.7913e-05 2.8739e-05 -6.0000e+00 4.6269e-04 1.0384e-03 0.0000e+00 10 0 0 10 0 0 99.48 18.93 0.14 0.00104 -0.00080 227 50 4 8 0 216.360 15.00 18.93 26.14 22.19 21.79 24.0 1009.56 -3785 -2893 -4111 -5068 -7140 -6782 -6029 -3903 -3252 -3620 -6001 -4566 -2411 -1470 521 -520 -507 1146 747 2042 774 1547 1156 1247 324 -90 -725 -1539 -1034 -920 263 1129 1341 -988 -2817 -2212 -1735 -1398 -676 -659 -1084 -646 -494 -505 134 190 -253 -234 -395 -178 1051 882 949 1163 911 970 747 51 125 331 901 1665 1622 2029 491 -225 109 -220 1077 829 120 264 -249 256 -165 -627 -383 -884 -311 -940 -1121 -1269 -1959 -1335 -907 -666 -135 84 348 414 467 542 306 558 445 -4 435 777 -69 -409 -452 -735 -295 229 -937 -1184 -752 -506 -36 404 369 267 307 283 152 440 286 240 162 -108 -531 -41 186 295 424 188 87 1043 452 103 54 -242 -47 130 -42 -101 -137 440 -127 -189 -215 -407 -180 -203 -177 -273 -337 -440 -388 -355 -249 -233 -284 -495 -380 -221 -157 64 -68 -73 171 119 336 134 266 202 231 65 -19 -158 -327 -205 -179 54 255 334 -271 -767 -571 -473 -403 -232 -252 -471 -298 -237 -249 66 94 -125 -114 -193 -87 540 460 531 692 572 626 464 32 77 215 592 1086 1161 1485 379 -167 80 -158 793 650 100 234 -224 222 -143 -493 -288 -631 -227 -733 -998 -1199 -1925 -1374 -989 -740 -159 97 407 495 522 584 305 562 445 -5 515 980 -91 -545 -600 -903 -350 269 -1146 -1549 -978 -692 -52 595 560 420 476 434 216 610 389 339 233 -166 -809 -64 283 433 616 261 122 1426 634 150 85 -381 -76 217 -71 -181 -245 800 -235 -341 -388 -707 -315 SS 20260717T062353.1Z 9694.266587 123 1 0.64 2 65.69 83.92 100.82 64.80 0.00 1 0.00 1 0 17 3.399e-02 8.574e-03 2.378e-02 6.035e-03 3.307707e-01 3.103730e-03 4.012555e-03 -6.000000e+00 1.994359e-02 233.19 -2.00 3.61 -2.00 317.62 0.00e+00 9.027168e-04 4.343497e-04 8.278553e-05 -6.000000e+00 7.854218e-04 285.97 -2.00 20.00 -2.00 317.29 0.00e+00 2.412 0.000 302.00 328.00 3 2.4678e+00 8.3010e-03 2.9886e-02 -6.0000e+00 5.0581e-02 2.1883e-02 9.2401e-03 1.7797e-02 -6.0000e+00 5.4826e-02 -7.8272e-03 5.7808e-03 8.6985e-03 -6.0000e+00 3.2105e-02 -1.9314e-03 2.9127e-03 2.4367e-03 -6.0000e+00 1.3241e-02 2.7301e-03 -4.1163e-04 1.7319e-04 2.6574e-05 -6.0000e+00 9.3284e-04 -2.4548e-04 0.0000e+00 12 9 1 12 1 1 999.00 18.95 0.17 -0.00025 -0.00334 2 51 2 8 0 211.800 15.00 18.95 26.76 22.19 21.88 24.1 1014.29 -8577 12999 -3112 11829 -19600 -1386 -12465 -10213 -6192 -5460 -269 -8344 5465 -2336 10883 -2133 4328 -1196 1281 120 2378 2656 1627 2805 -4341 3329 -4031 202 887 -1257 -1697 -469 3387 -2534 -2100 -1899 -456 -3002 -2340 657 -2331 -407 -1047 426 -642 3468 -319 497 -589 -1015 1573 -630 1148 1696 2797 613 471 -583 1598 380 1460 818 2245 2429 -2030 -46 45 -158 1396 836 568 -440 -602 -24 1159 -779 567 -1705 -572 -714 -368 -2136 -2615 -1013 -1770 -311 -252 -254 868 771 65 -225 -524 -702 717 249 731 900 292 -887 -231 -65 -458 690 -1279 -372 -1149 -253 -252 1080 234 286 736 202 315 448 86 -160 708 225 -373 -366 1115 179 -492 387 157 869 -123 386 -227 -668 -654 -280 342 -468 340 539 -55 -161 54 -288 -333 -679 965 -285 938 -1890 -106 -1087 -954 -621 -588 -28 -959 613 -323 1542 -379 783 -238 261 26 514 573 358 641 -1111 832 -1093 52 214 -302 -429 -127 960 -801 -645 -560 -139 -1043 -930 292 -1162 -209 -557 229 -348 1837 -173 266 -315 -545 865 -371 701 1080 1824 413 323 -405 1086 258 996 585 1688 1926 -1694 -37 35 -118 1061 689 502 -409 -565 -22 1017 -651 439 -1291 -436 -587 -328 -2065 -2675 -1061 -1933 -352 -295 -305 1046 917 74 -246 -548 -713 738 273 858 1129 385 -1186 -299 -80 -543 812 -1592 -479 -1530 -345 -354 1568 354 443 1127 301 449 614 117 -222 1013 336 -570 -555 1660 262 -704 537 212 1165 -171 563 -344 -1042 -1036 -451 567 -805 592 951 -98 -283 93 -488 -554 SS 20260717T063558.8Z 9694.274986 128 1 49.21 2 63.58 85.99 99.00 67.05 0.00 1 0.00 1 0 17 1.146e-02 5.568e-03 7.153e-04 2.157e-04 3.078245e-01 1.110364e-04 3.754867e-03 -6.000000e+00 6.726214e-03 233.19 -2.00 3.61 -2.00 317.33 0.00e+00 5.502479e-04 1.441907e-05 6.909431e-05 -6.000000e+00 2.649195e-04 285.97 -2.00 20.00 -2.00 317.00 0.00e+00 2.234 0.000 302.00 328.00 3 7.6726e-01 2.9589e-04 2.7736e-02 -6.0000e+00 1.7059e-02 1.3886e-02 3.2902e-04 1.6563e-02 -6.0000e+00 1.8491e-02 -4.9210e-03 2.0043e-04 8.0849e-03 -6.0000e+00 1.0828e-02 -2.6655e-03 9.8804e-05 2.2572e-03 -6.0000e+00 4.4653e-03 1.8424e-02 -1.8638e-04 6.2039e-06 2.4887e-05 -6.0000e+00 3.1465e-04 4.0880e-04 0.0000e+00 10 0 0 10 0 0 15.72 18.95 0.16 0.00041 -0.00099 1707 375 2 8 0 28.810 15.00 18.95 28.20 22.19 21.88 24.8 1026.51 -1295 -1428 -1508 -3079 -4773 -3682 -3941 -1913 -1977 -2100 -3945 -2787 -1508 -1147 590 94 344 814 997 1529 1130 558 1637 1171 435 338 -564 -973 -951 -63 821 849 1419 -845 -2555 -2087 -1960 -1235 -403 -511 -908 -650 -363 -486 176 79 -429 -248 -524 -156 846 793 918 1228 725 822 874 122 352 400 931 1336 1626 1740 318 -275 10 -280 986 773 -37 338 -172 225 -212 -428 -321 -778 -176 -785 -1037 -1196 -1955 -1437 -882 -677 -189 10 290 311 331 378 168 586 524 35 392 790 -14 -408 -414 -733 -253 193 -807 -1149 -738 -514 -54 428 375 280 227 303 120 426 286 280 294 -72 -472 35 204 232 546 263 139 1119 427 109 -14 -234 -28 92 -39 -143 -112 389 -131 -196 -193 -445 -286 -120 -152 -170 -347 -493 -349 -385 -202 -235 -272 -529 -373 -220 -178 104 19 74 183 236 374 287 143 418 317 116 94 -163 -272 -268 -17 232 241 438 -285 -849 -656 -652 -467 -167 -254 -476 -361 -209 -286 103 46 -251 -142 -297 -88 496 470 580 821 510 592 605 86 258 288 680 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