File name: Pandora138s1_Milan-MIBI_20260723_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260723T234624.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260723_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260723T053025.6Z 9700.229463 91 1 48.83 2 75.72 75.77 155.11 329.79 0.00 1 0.00 1 0 25 5.453e-01 1.493e-02 1.963e-01 7.039e-03 5.691940e-01 3.764725e-03 6.608388e-03 -6.000000e+00 3.200295e-01 232.96 -2.00 3.61 -2.00 320.64 0.00e+00 3.611587e-03 1.229408e-03 4.182571e-04 -6.000000e+00 1.316571e-02 286.08 -2.00 20.00 -2.00 320.31 0.00e+00 3.965 0.001 302.00 328.00 3 4.8732e+00 1.0971e-02 5.0386e-02 -6.0000e+00 8.1237e-01 9.7123e-02 1.3665e-02 3.1568e-02 -6.0000e+00 8.8186e-01 -9.5989e-02 1.4133e-02 1.6504e-02 -6.0000e+00 5.1480e-01 3.2916e-02 7.2964e-03 5.1095e-03 -6.0000e+00 2.1410e-01 4.0754e-05 -9.6351e-04 2.0911e-04 5.9370e-05 -6.0000e+00 1.5313e-02 4.8089e-03 0.0000e+00 12 9 8 11 8 0 99.99 18.91 0.12 0.00481 -0.00243 33 7 2 8 0 1479.600 15.00 18.91 28.90 22.19 21.79 24.1 1025.16 900000 16022 -137406 -148166 900000 -112823 -135709 -105835 -97087 900000 -121051 140400 -82160 -30468 12837 -38355 1035 34506 5134 75956 -6895 18948 12173 31077 46903 10898 32237 6839 41722 25 -7989 67876 2113 -5800 482 44166 39554 3671 13431 -13852 9232 -5715 9986 6929 24323 -2312 -10447 7070 2227 2460 6521 484822 8137 10 5564 2985 3513 1364 1700 573 677 -6342 1196 3816 2089 3611 3084 -3504 -1520 7561 -647 4045 -2128 1981 -792 -5065 -2371 -1778 -2238 -4228 -6617 -4316 -720 642 -1308 -1096 -20 426 1176 3636 1596 2426 -2310 -1439 -1190 581 1303 -698 1509 1312 756 -1790 -1864 -1394 -2622 -554 -2369 -479 -374 2238 -148 972 -764 -262 94 358 597 -686 908 -1 221 322 -40 868 -492 427 -74 1048 530 698 379 217 -308 215 -463 -884 193 328 -289 -544 -20 -289 594 900000 110 -3528 -4271 900000 -2107 -3233 -2119 -2004 900000 -3533 963 -2132 -618 218 -1222 26 708 149 1237 -244 538 374 860 1196 404 1016 270 1166 1 -406 2030 129 -419 33 1959 1943 283 1124 -1777 1086 -833 1324 983 2988 -370 -1837 1079 365 421 1166 3326 1718 3 1375 786 948 379 461 155 187 -1993 391 1355 801 1349 1118 -1364 -617 3176 -327 2072 -1161 1002 -384 -2324 -980 -716 -961 -2123 -3920 -2816 -498 465 -1022 -911 -18 380 1051 3112 1312 1856 -1746 -1074 -950 513 1286 -789 1819 1611 894 -2010 -1940 -1424 -2861 -627 -2844 -597 -495 3157 -230 1577 -1260 -420 142 520 861 -1031 1416 -1 366 521 -64 1328 -733 613 -103 1458 799 1151 677 407 -601 433 -991 -1990 438 759 -675 -1248 -44 -610 1208 SS 20260723T053740.2Z 9700.234493 95 1 49.47 2 74.49 76.98 155.70 333.35 0.00 1 0.00 1 0 25 1.327e-01 5.840e-03 4.952e-02 2.040e-03 5.359921e-01 1.064034e-03 6.266534e-03 -6.000000e+00 7.776854e-02 232.96 -2.00 3.61 -2.00 320.06 0.00e+00 2.262493e-03 3.028489e-04 3.226402e-04 -6.000000e+00 3.066213e-03 286.08 -2.00 20.00 -2.00 319.74 0.00e+00 3.670 0.001 302.00 328.00 3 3.3120e+00 3.0073e-03 4.6803e-02 -6.0000e+00 1.9712e-01 1.1073e-02 3.5915e-03 2.9358e-02 -6.0000e+00 2.1372e-01 -1.5978e-02 3.4852e-03 1.5102e-02 -6.0000e+00 1.2517e-01 -1.0021e-03 1.8471e-03 4.5692e-03 -6.0000e+00 5.1633e-02 2.7507e-04 -4.8784e-04 5.8628e-05 4.9025e-05 -6.0000e+00 3.6416e-03 1.8019e-03 0.0000e+00 10 0 0 10 0 0 99.97 18.91 0.14 0.00180 -0.00186 84 18 4 8 0 588.900 15.00 18.91 29.22 22.19 21.79 24.2 1027.48 -26939 -35466 -44536 -55353 -34916 -64794 -53604 -44385 -54069 -1250 -37913 -1589 -34897 -14161 -13600 220 -6171 -885 367 8455 4910 -2901 5973 -958 2895 -4502 -6672 -5916 -5279 -2867 -8687 8125 -4461 -7062 -4771 3596 687 -589 640 -3837 227 -2005 -993 643 2703 1408 -628 1836 1517 323 1075 -3236 865 2350 3089 841 349 -437 135 -157 855 -673 1984 2226 1238 912 890 -686 420 1549 445 1305 -731 583 -438 -1500 -1148 -810 -695 -1718 -1717 -1580 -1257 -1160 -963 -371 139 464 455 1252 754 1184 76 46 135 117 592 710 232 -176 -303 -737 -201 207 -987 -1506 -872 -726 -334 487 526 293 147 263 -79 460 219 28 189 -337 -571 43 381 53 189 -73 123 1062 438 118 85 -268 -124 7 -2 -223 -123 430 -255 -190 26 -153 66 -238 -406 -613 -853 -417 -978 -770 -651 -982 -15 -683 -22 -769 -318 -374 6 -211 -32 14 319 201 -128 251 -46 144 -254 -400 -347 -299 -162 -576 539 -377 -671 -438 300 62 -62 80 -597 39 -373 -193 128 534 287 -133 385 328 74 261 -904 251 729 1005 288 124 -158 48 -55 303 -258 821 1018 597 436 414 -325 207 843 270 828 -478 365 -260 -827 -587 -404 -364 -1022 -1156 -1188 -1013 -983 -860 -347 136 466 462 1240 713 1052 65 39 120 116 644 852 301 -230 -384 -881 -225 227 -1154 -1854 -1102 -958 -464 719 828 479 242 420 -121 680 321 42 298 -552 -951 70 607 82 286 -107 176 1525 671 194 148 -488 -233 13 -3 -466 -262 927 -555 -406 54 -308 129 SS 20260723T061044.1Z 9700.257455 112 1 20.17 2 68.79 82.54 157.48 351.17 0.00 1 0.00 1 0 17 6.764e-02 8.203e-03 3.523e-02 4.130e-03 4.037628e-01 2.118540e-03 4.847788e-03 -6.000000e+00 3.964157e-02 232.96 -2.00 3.61 -2.00 318.80 0.00e+00 8.483907e-04 4.170323e-04 1.525228e-04 -6.000000e+00 1.562939e-03 286.08 -2.00 20.00 -2.00 318.48 0.00e+00 2.738 0.000 302.00 328.00 3 4.8495e+00 5.7796e-03 3.4978e-02 -6.0000e+00 1.0048e-01 1.2992e-02 6.5142e-03 2.1836e-02 -6.0000e+00 1.0894e-01 6.2809e-03 4.8143e-03 1.0827e-02 -6.0000e+00 6.3806e-02 -9.9488e-03 2.5701e-03 3.1061e-03 -6.0000e+00 2.6320e-02 1.6632e-04 -5.0127e-05 1.1930e-04 3.2668e-05 -6.0000e+00 1.8562e-03 1.6582e-03 0.0000e+00 12 9 1 12 1 1 46.13 18.91 0.24 0.00166 0.00128 7 4 1 8 0 2521.210 15.00 18.91 30.81 22.19 21.79 24.3 1036.77 -31886 10709 -36539 -24548 -3549 -32663 -24688 -19413 2302 -6705 -2938 -16166 4295 -2725 10660 2171 -4001 -2355 -4017 11366 -4197 3189 754 6682 5861 -661 657 -4756 5323 -3692 2086 7823 432 -5709 -3786 -1741 -3807 838 -668 -1200 174 -711 191 670 1824 585 -2602 -1848 -389 -1217 1617 7534 992 272 2006 -253 -287 108 -1268 121 -324 1636 2182 2951 338 -29 1367 -1737 1924 76 626 917 -709 -369 -125 -1473 -1628 -733 -481 -1271 -2229 -1565 -1839 -1496 -1638 -571 1138 320 819 843 783 1002 1104 -268 522 -250 379 720 149 391 -434 -848 -552 -88 -1137 -875 -802 -1014 -81 350 591 487 277 244 -361 659 480 -163 594 -90 -641 -7 258 -185 162 273 192 1051 398 26 424 -197 -392 -87 -338 181 -88 446 -581 309 -208 -452 108 -1164 306 -1752 -1047 -115 -1314 -962 -801 87 -301 -132 -848 213 -170 693 176 -376 -233 -431 1108 -490 350 86 770 730 -91 92 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