File name: Pandora138s1_Milan-MIBI_20260728_L2Fit_fout2c22d20250714p1-8.txt File generation date: 20260728T235643.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v22d20250714.txt Level 1 file used: Pandora138s1_Milan-MIBI_20260728_L1_smca1c22d20250714p1-8.txt Full location name: University Milano Bicocca, building U9 Short location name: Milan-MIBI Country of location: Italy Location latitude [deg]: 45.5090 Location longitude [deg]: 9.2080 Location altitude [m]: 150 Local noon date: 20260728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.0035 305.1446 305.2856 305.4266 305.5676 305.7086 305.8496 305.9905 306.1315 306.2724 306.4134 306.5543 306.6952 306.8361 306.9770 307.1178 307.2587 307.3996 307.5404 307.6812 307.8221 307.9629 308.1037 308.2444 308.3852 308.5260 308.6667 308.8075 308.9482 309.0889 309.2296 309.3703 309.5110 309.6517 309.7923 309.9330 310.0736 310.2143 310.3549 310.4955 310.6361 310.7767 310.9172 311.0578 311.1983 311.3389 311.4794 311.6199 311.7604 311.9009 312.0414 312.1819 312.3223 312.4628 312.6032 312.7436 312.8840 313.0244 313.1648 313.3052 313.4456 313.5859 313.7263 313.8666 314.0069 314.1472 314.2875 314.4278 314.5681 314.7084 314.8486 314.9888 315.1291 315.2693 315.4095 315.5497 315.6899 315.8301 315.9702 316.1104 316.2505 316.3906 316.5308 316.6709 316.8109 316.9510 317.0911 317.2312 317.3712 317.5112 317.6513 317.7913 317.9313 318.0713 318.2112 318.3512 318.4912 318.6311 318.7710 318.9110 319.0509 319.1908 319.3307 319.4705 319.6104 319.7502 319.8901 320.0299 320.1697 320.3095 320.4493 320.5891 320.7289 320.8686 321.0084 321.1481 321.2878 321.4276 321.5673 321.7069 321.8466 321.9863 322.1259 322.2656 322.4052 322.5448 322.6845 322.8240 322.9636 323.1032 323.2428 323.3823 323.5219 323.6614 323.8009 323.9404 324.0799 324.2194 324.3588 324.4983 324.6378 324.7772 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260728T045942.5Z 9705.208131 147 1 50.00 2 81.65 71.38 114.23 256.96 0.00 1 0.00 1 0 25 9.378e-01 3.132e-02 3.572e-01 1.211e-02 7.892893e-01 6.860995e-03 8.867353e-03 -6.000000e+00 5.507979e-01 232.76 -2.00 3.61 -2.00 321.75 0.00e+00 1.028489e-02 2.765537e-03 9.051187e-04 -6.000000e+00 2.329495e-02 286.17 -2.00 20.00 -2.00 321.39 0.00e+00 6.462 0.005 302.00 328.00 3 3.1256e+00 2.1580e-02 7.7783e-02 -6.0000e+00 1.3972e+00 8.6314e-01 2.7394e-02 4.4213e-02 -6.0000e+00 1.5190e+00 -1.1483e+00 2.7086e-02 2.3312e-02 -6.0000e+00 8.8794e-01 4.5953e-01 1.3623e-02 7.5479e-03 -6.0000e+00 3.6736e-01 1.6423e-05 -1.9035e-03 3.5419e-04 1.0550e-04 -6.0000e+00 2.6538e-02 1.6429e-03 0.0000e+00 12 8 8 10 0 0 72.15 19.02 0.65 0.00164 -0.01266 20 4 4 8 0 2499.780 15.00 19.02 31.22 22.29 21.88 24.4 1038.83 17377 369395 -82192 -38007 900000 -123889 -139233 -115758 -138284 33256 -104390 900000 29378 -110618 900000 271827 38629 20524 182751 900000 -34328 119370 144069 900000 60211 62762 326743 542034 161363 33412 87818 900000 54850 9512 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-2771 -4583 -7015 -4220 1470 2667 -2019 744 -193 1177 109 5166 1371 1978 -3886 -6354 -2545 -1276 -29 -2410 3710 916 2179 -3801 -6481 205 -3556 335 -4922 -1287 -5966 2685 -1800 2099 -1730 -3246 883 -172 1751 -2076 2475 1439 2541 2315 2898 3055 -994 5035 -386 3164 166 2739 359 3238 -1731 1837 -80 -2858 1883 -1247 -1115 -2980 872 -1901 -303 SS 20260728T051757.7Z 9705.220807 154 1 49.27 2 78.59 74.47 117.22 259.85 0.00 1 0.00 1 0 25 3.871e-01 7.918e-03 1.161e-01 2.541e-03 6.510806e-01 1.359729e-03 7.388889e-03 -6.000000e+00 2.267626e-01 232.76 -2.00 3.61 -2.00 320.98 0.00e+00 5.479726e-03 4.923460e-04 5.788819e-04 -6.000000e+00 8.945799e-03 286.17 -2.00 20.00 -2.00 320.66 0.00e+00 4.883 0.002 302.00 328.00 3 2.3615e+00 4.0344e-03 6.0294e-02 -6.0000e+00 5.7449e-01 3.1002e-02 5.3980e-03 3.6479e-02 -6.0000e+00 6.2295e-01 -9.2751e-02 6.2069e-03 1.9672e-02 -6.0000e+00 3.6491e-01 3.5599e-02 3.1293e-03 6.3133e-03 -6.0000e+00 1.5061e-01 2.0714e-04 -6.9795e-04 7.3100e-05 7.3680e-05 -6.0000e+00 1.0624e-02 8.1929e-04 0.0000e+00 11 8 0 10 0 0 64.18 19.02 0.19 0.00082 -0.00443 113 25 4 8 0 436.000 15.00 19.02 31.83 22.29 21.88 24.4 1042.17 -163751 -36841 -162871 -159537 -81386 -179604 -93857 -158564 -75703 -113368 -88080 -70533 -59384 -63087 -22489 -10830 -27144 508 -46737 21672 -42886 15769 -21365 1730 -5007 -28800 16424 -40249 6489 -37542 -13913 14741 6337 -2900 -9209 8920 -7539 4182 -8933 317 -3655 2085 -1659 4329 7047 4500 2816 -1062 5043 -863 4800 -8557 6993 4574 5895 2308 843 3236 -564 3260 475 2017 1656 4473 2978 2101 2534 -408 2369 2377 1320 903 -171 580 -82 -2427 -2377 367 -2576 -606 -3045 -1607 -2380 -1378 -1104 -795 523 -395 974 1583 1660 365 29 -1204 -715 -379 483 755 -37 601 -210 -150 -1302 427 -1336 -1411 -831 -1133 19 352 493 296 572 -1 -220 27 230 -23 -140 -100 -291 257 296 368 55 151 171 972 226 104 193 -248 88 -62 -53 -213 -32 624 -318 -261 -84 -207 52 -1476 -128 -2055 -2013 -484 -2468 -628 -2036 -525 -1264 -808 -594 -559 -813 -251 -134 -464 7 -1106 306 -1101 250 -457 35 -105 -811 338 -1324 145 -1252 -433 418 231 -131 -442 346 -369 211 -624 25 -312 184 -162 417 678 458 301 -122 574 -111 643 -1477 1142 838 1146 485 186 705 -125 685 105 476 445 1333 978 694 816 -138 839 892 565 413 -80 258 -34 -925 -901 134 -1050 -264 -1605 -963 -1602 -980 -776 -598 411 -326 801 1265 1243 277 21 -887 -533 -326 477 803 -44 729 -245 -160 -1360 427 -1449 -1524 -939 -1375 25 508 744 481 941 -1 -337 39 330 -35 -223 -168 -492 418 465 559 85 227 247 1418 346 180 348 -481 180 -134 -116 -495 -76 1504 -780 -618 -188 -463 111 SS 20260728T052557.6Z 9705.226361 158 1 49.33 2 77.24 75.82 118.54 261.12 0.00 1 0.00 1 0 25 2.447e-01 5.884e-03 5.594e-02 1.635e-03 5.963049e-01 8.608502e-04 6.842929e-03 -6.000000e+00 1.433426e-01 232.76 -2.00 3.61 -2.00 320.57 0.00e+00 3.487064e-03 2.840667e-04 4.545493e-04 -6.000000e+00 5.654422e-03 286.17 -2.00 20.00 -2.00 320.26 0.00e+00 4.403 0.002 302.00 328.00 3 2.1147e+00 2.5098e-03 5.4554e-02 -6.0000e+00 3.6315e-01 -4.4308e-03 3.1710e-03 3.3024e-02 -6.0000e+00 3.9378e-01 -3.3354e-02 3.4123e-03 1.7446e-02 -6.0000e+00 2.3067e-01 9.1605e-03 1.7616e-03 5.4651e-03 -6.0000e+00 9.5209e-02 4.4053e-04 -4.2750e-04 4.6995e-05 5.9355e-05 -6.0000e+00 6.7151e-03 2.6239e-04 0.0000e+00 10 0 0 10 0 0 35.82 19.02 0.18 0.00026 -0.00295 180 40 4 8 0 274.010 15.00 19.02 32.33 22.29 21.88 24.5 1045.72 -77921 -55009 -106469 -87247 -95539 -69488 -95208 -68142 -78302 -71893 -55025 -61875 -36488 -53972 -21745 -26801 -14366 -22224 -9500 -3057 -13925 -640 -4639 -3235 -11513 -6534 -15139 -14310 -6079 -9858 -4371 7394 430 -6087 -4377 -5250 1026 -5521 51 -3044 -1326 -2036 -2671 2551 1798 1365 -878 1509 1181 1282 3526 6508 2485 1305 2511 -5 1592 -786 -375 -472 1428 2488 1520 3074 1318 1928 875 -232 1063 1449 728 795 104 42 -97 -1361 -1021 -1835 -1374 -1564 -1847 -1232 -2036 -1285 -991 -354 267 338 424 1044 957 494 81 -133 360 -311 431 626 120 -80 -254 -688 -499 290 -1349 -1249 -905 -650 -24 490 456 376 212 263 143 229 283 89 9 -308 -592 47 384 238 220 22 -91 1070 220 70 -109 8 -26 113 -147 -318 -75 394 -154 -223 58 -217 78 -534 -368 -1342 -932 -1036 -554 -1033 -630 -912 -871 -597 -780 -436 -990 -368 -586 -321 -599 -248 -80 -390 -17 -135 -101 -382 -220 -580 -539 -205 -360 -175 314 23 -387 -272 -319 63 -419 4 -335 -152 -256 -359 339 246 192 -130 224 183 209 616 1238 542 314 641 -1 443 -227 -106 -131 397 740 515 1070 502 722 322 -87 423 658 375 437 58 23 -48 -620 -424 -753 -603 -805 -1119 -790 -1461 -975 -800 -305 242 318 404 964 830 399 62 -102 298 -296 440 733 146 -100 -303 -803 -528 298 -1506 -1485 -1127 -808 -32 720 697 614 350 421 216 349 426 140 14 -512 -994 76 601 382 337 33 -131 1530 350 118 -201 14 -51 232 -308 -706 -171 912 -342 -508 124 -444 160 SS 20260728T053246.4Z 9705.231093 161 1 49.24 2 76.08 76.97 119.66 262.22 0.00 1 0.00 1 0 25 1.727e-01 5.643e-03 3.523e-02 1.219e-03 5.538674e-01 6.356464e-04 6.430475e-03 -6.000000e+00 1.011454e-01 232.76 -2.00 3.61 -2.00 320.22 0.00e+00 2.768973e-03 1.903762e-04 3.618340e-04 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