File name: Pandora197s1_Nagoya_20220721_L2Fit_fout2c401d20220701p1-8.txt File generation date: 20260324T103938.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c401p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v401d20220701.txt Level 1 file used: Pandora197s1_Nagoya_20220721_L1_smca1c401d20220701p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20220721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New initial field cal based on Session 4 ref@May29 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0298 305.1710 305.3123 305.4535 305.5947 305.7359 305.8771 306.0183 306.1595 306.3006 306.4418 306.5829 306.7240 306.8651 307.0063 307.1473 307.2884 307.4295 307.5706 307.7116 307.8526 307.9937 308.1347 308.2757 308.4167 308.5577 308.6986 308.8396 308.9805 309.1215 309.2624 309.4033 309.5442 309.6851 309.8260 309.9668 310.1077 310.2485 310.3894 310.5302 310.6710 310.8118 310.9526 311.0933 311.2341 311.3749 311.5156 311.6563 311.7970 311.9377 312.0784 312.2191 312.3598 312.5005 312.6411 312.7817 312.9224 313.0630 313.2036 313.3442 313.4848 313.6253 313.7659 313.9064 314.0470 314.1875 314.3280 314.4685 314.6090 314.7495 314.8899 315.0304 315.1708 315.3113 315.4517 315.5921 315.7325 315.8729 316.0132 316.1536 316.2940 316.4343 316.5746 316.7149 316.8552 316.9955 317.1358 317.2761 317.4163 317.5566 317.6968 317.8370 317.9773 318.1175 318.2576 318.3978 318.5380 318.6781 318.8183 318.9584 319.0985 319.2386 319.3787 319.5188 319.6589 319.7989 319.9390 320.0790 320.2191 320.3591 320.4991 320.6391 320.7790 320.9190 321.0590 321.1989 321.3389 321.4788 321.6187 321.7586 321.8985 322.0383 322.1782 322.3181 322.4579 322.5977 322.7375 322.8773 323.0171 323.1569 323.2967 323.4365 323.5762 323.7159 323.8557 323.9954 324.1351 324.2748 324.4144 324.5541 324.6937 324.8334 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220720T204448.4Z 8236.864448 214 1 49.30 2 81.02 71.15 25.29 173.20 0.00 1 0.00 1 0 25 4.540e-01 2.945e-02 4.357e-01 2.845e-02 6.909046e-01 1.648847e-02 1.504303e-02 -6.000000e+00 2.776862e-01 232.15 -2.00 3.39 -2.00 321.74 0.00e+00 5.348813e-03 9.515736e-03 3.283295e-02 -6.000000e+00 1.416645e-02 292.07 -2.00 20.00 -2.00 321.18 0.00e+00 6.065 0.003 302.00 328.00 3 3.0377e+00 6.6587e-02 2.0121e-01 -6.0000e+00 7.0092e-01 4.2041e-01 9.0450e-02 2.6240e-01 -6.0000e+00 7.6478e-01 -6.8937e-01 7.3466e-02 7.0095e-02 -6.0000e+00 4.4607e-01 2.8585e-01 3.3576e-02 2.3484e-02 -6.0000e+00 1.8876e-01 3.2793e-05 1.3866e-02 8.5317e-04 1.5418e-04 -6.0000e+00 1.2910e-02 -1.0545e-01 0.0000e+00 12 8 8 10 0 0 -68.91 15.92 1.39 -0.10545 -0.00125 16 3 1 5 0 3080.650 19.85 14.97 15.92 31.07 24.9 1022.74 900000 900000 -130596 15265 900000 -99053 900000 -67832 900000 13874 -210927 900000 41987 900000 -98682 900000 76139 900000 20855 -4969 133860 -71392 60842 900000 209414 900000 900000 -69949 -110247 -95807 -23117 -33892 17916 900000 900000 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3125 -2732 974 5307 -726 2041 1464 -1900 1021 -868 -4193 -496 -148 726 451 2282 1283 -2503 -2442 -3327 2802 1716 -1265 2851 -984 1293 -3466 -5072 1566 -1442 -2642 -5632 -2006 -3582 -1973 1947 -2499 46 -2790 2723 116 -1345 -286 367 4381 -893 489 -3887 2086 4931 5699 2872 2617 2974 -701 811 3067 -2284 -2865 -2161 3195 -826 -664 4507 2037 -4244 -1139 1816 -311 -4150 SS 20220720T213459.9Z 8236.899304 238 1 45.73 2 71.15 77.72 26.39 201.20 0.00 1 0.00 1 0 25 3.585e-02 6.378e-03 1.528e-02 1.183e-03 3.881938e-01 6.011979e-04 4.452035e-03 -6.000000e+00 2.083243e-02 232.15 -2.00 3.39 -2.00 319.49 0.00e+00 1.680670e-03 1.732316e-04 2.698872e-03 -6.000000e+00 9.348911e-04 292.07 -2.00 20.00 -2.00 318.65 0.00e+00 3.057 0.000 302.00 328.00 3 2.0416e+00 1.7473e-03 3.6702e-02 -6.0000e+00 5.2178e-02 -4.2392e-02 2.0824e-03 2.2310e-02 -6.0000e+00 5.6203e-02 3.9048e-03 1.5829e-03 1.1722e-02 -6.0000e+00 3.3532e-02 -7.0101e-03 8.2272e-04 3.6654e-03 -6.0000e+00 1.4515e-02 2.1833e-03 1.4529e-02 3.4336e-05 4.9546e-05 -6.0000e+00 9.4186e-04 -1.0624e-01 0.0000e+00 12 1 1 12 1 1 99.58 15.93 0.88 -0.10624 0.00293 144 34 1 5 0 314.110 19.85 15.00 15.93 32.48 25.0 1031.12 900000 -12932 -6992 -8673 -16556 -8610 -11622 -10917 -13164 -8596 -8159 -14150 -6721 -5990 -2862 -3343 223 -3939 603 -678 2713 -615 616 -1899 -1981 -3086 -3847 -2099 -4666 -1892 -736 -712 1160 -2133 -5007 -4291 -2989 -2267 -1656 -621 -2007 -1132 194 -337 506 579 115 -116 -1045 -195 1169 1151 1236 1222 1220 619 380 -70 -344 578 1263 1934 2102 2615 649 231 -73 103 1217 596 731 553 407 356 -223 -565 -1167 -1767 -1158 -1699 -1424 -1483 -2168 -1328 -658 -34 313 474 1242 709 569 190 73 140 93 8 753 797 92 -672 -858 -558 -554 -458 -1057 -977 -875 -468 283 460 648 473 541 -51 -156 222 253 114 -315 -1113 -1156 178 997 595 595 -186 666 898 149 -218 -217 1 -209 123 64 -33 364 581 5 -286 -242 -383 -447 900000 -282 -153 -188 -384 -175 -257 -272 -381 -257 -246 -472 -243 -259 -144 -194 14 -267 42 -50 199 -46 47 -160 -179 -297 -379 -195 -420 -167 -71 -78 139 -281 -643 -530 -397 -352 -312 -138 -504 -299 53 -94 141 163 33 -33 -299 -57 361 390 450 475 496 261 165 -31 -147 243 544 900 1084 1464 378 127 -38 53 670 379 513 406 299 251 -146 -333 -632 -934 -654 -1114 -1065 -1242 -1789 -1144 -605 -34 323 504 1312 725 540 166 66 124 82 8 835 991 123 -892 -1066 -628 -587 -503 -1271 -1241 -1165 -655 420 680 1023 765 850 -76 -233 315 361 172 -468 -1765 -1849 275 1616 930 888 -266 907 1256 231 -338 -358 2 -368 227 127 -69 770 1251 10 -602 -486 -737 -847 SS 20220720T214038.9Z 8236.903228 241 1 49.48 2 70.02 78.45 26.81 204.11 0.00 1 0.00 1 0 25 2.869e-02 6.250e-03 2.127e-02 1.754e-03 3.666496e-01 8.962412e-04 4.300082e-03 -6.000000e+00 1.667405e-02 232.15 -2.00 3.39 -2.00 319.40 0.00e+00 1.616092e-03 2.485003e-04 2.651243e-03 -6.000000e+00 7.482712e-04 292.07 -2.00 20.00 -2.00 318.53 0.00e+00 2.894 0.000 302.00 328.00 3 2.8546e+00 2.5998e-03 3.4889e-02 -6.0000e+00 4.1763e-02 -4.7028e-02 3.0756e-03 2.1504e-02 -6.0000e+00 4.4984e-02 1.0871e-02 2.2595e-03 1.0912e-02 -6.0000e+00 2.6838e-02 -9.3453e-03 1.1732e-03 3.1905e-03 -6.0000e+00 1.1618e-02 1.1618e-03 1.4638e-02 5.1336e-05 4.3326e-05 -6.0000e+00 7.5384e-04 -1.0637e-01 0.0000e+00 10 0 0 10 0 0 99.84 15.94 0.80 -0.10637 0.00362 92 20 1 5 0 537.530 19.85 15.01 15.94 33.22 24.9 1036.08 900000 -10997 -550 -234 -10599 -8471 -9200 -7715 -13312 -7327 -7453 -3251 -8171 -4004 -1960 -9948 258 -4143 415 -300 -895 478 1961 677 -3115 1266 -579 1505 -328 -4686 -1049 589 1290 -3289 -2677 -4450 -2033 -1593 -1417 -683 -1882 -1442 -1014 -58 -487 944 -562 27 -306 86 1686 347 1189 935 750 956 126 -398 -215 438 1542 2085 2348 2165 543 439 -56 -207 856 715 606 588 551 454 55 -516 -1600 -1365 -1166 -1289 -1671 -1492 -2070 -1050 -391 -90 381 321 1179 733 387 -101 38 231 -155 -17 675 1045 -99 -883 -529 -625 -295 -470 -1180 -972 -793 -541 384 668 742 639 313 -84 -217 376 131 120 -163 -1063 -962 72 967 454 617 -227 708 800 133 -337 -384 46 -169 105 98 64 373 507 98 -341 -126 -302 -413 900000 -279 -13 -5 -247 -183 -212 -198 -410 -229 -235 -102 -312 -194 -111 -634 18 -315 32 -24 -76 40 165 62 -315 129 -61 148 -31 -466 -110 68 166 -470 -359 -589 -286 -263 -284 -162 -501 -405 -295 -17 -145 280 -169 8 -91 26 539 123 447 376 315 413 56 -179 -94 190 682 996 1238 1244 322 244 -29 -108 476 457 428 434 406 321 36 -306 -875 -720 -658 -838 -1244 -1238 -1858 -982 -390 -87 389 338 1234 741 400 -96 34 201 -147 -18 729 1261 -129 -1139 -635 -684 -333 -503 -1386 -1203 -1028 -737 554 1041 1234 1085 516 -131 -311 508 179 173 -254 -1761 -1608 116 1507 682 884 -312 923 1072 196 -543 -656 81 -306 200 199 124 746 1033 200 -679 -261 -601 -810 SS 20220720T214507.4Z 8236.906335 244 1 49.11 2 69.12 79.02 27.18 206.35 0.00 1 0.00 1 0 25 2.522e-02 6.213e-03 6.688e-03 7.212e-04 3.535557e-01 3.646825e-04 3.848307e-03 -6.000000e+00 1.465974e-02 232.15 -2.00 3.39 -2.00 319.07 0.00e+00 1.309109e-03 9.184987e-05 1.722144e-03 -6.000000e+00 6.578606e-04 292.07 -2.00 20.00 -2.00 318.20 0.00e+00 2.778 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