File name: Pandora197s1_Nagoya_20220930_L2Fit_fout2c41d20220827p1-8.txt File generation date: 20260324T105125.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c41p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v41d20220827.txt Level 1 file used: Pandora197s1_Nagoya_20220930_L1_smca1c41d20220827p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20220930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0366 305.1778 305.3191 305.4603 305.6015 305.7427 305.8839 306.0250 306.1662 306.3074 306.4485 306.5896 306.7308 306.8719 307.0130 307.1540 307.2951 307.4362 307.5772 307.7183 307.8593 308.0003 308.1413 308.2823 308.4233 308.5643 308.7052 308.8462 308.9871 309.1281 309.2690 309.4099 309.5508 309.6917 309.8325 309.9734 310.1142 310.2551 310.3959 310.5367 310.6775 310.8183 310.9591 311.0999 311.2406 311.3814 311.5221 311.6628 311.8036 311.9443 312.0849 312.2256 312.3663 312.5069 312.6476 312.7882 312.9289 313.0695 313.2101 313.3507 313.4912 313.6318 313.7723 313.9129 314.0534 314.1939 314.3345 314.4749 314.6154 314.7559 314.8964 315.0368 315.1773 315.3177 315.4581 315.5985 315.7389 315.8793 316.0197 316.1600 316.3004 316.4407 316.5810 316.7214 316.8617 317.0020 317.1422 317.2825 317.4228 317.5630 317.7033 317.8435 317.9837 318.1239 318.2641 318.4043 318.5444 318.6846 318.8247 318.9649 319.1050 319.2451 319.3852 319.5253 319.6653 319.8054 319.9455 320.0855 320.2255 320.3655 320.5056 320.6455 320.7855 320.9255 321.0655 321.2054 321.3453 321.4853 321.6252 321.7651 321.9050 322.0449 322.1847 322.3246 322.4644 322.6043 322.7441 322.8839 323.0237 323.1635 323.3033 323.4430 323.5828 323.7225 323.8622 324.0020 324.1417 324.2814 324.4210 324.5607 324.7004 324.8400 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220929T214519.8Z 8307.906479 65 1 49.04 2 78.76 101.43 128.06 90.09 0.00 1 0.00 1 0 25 3.123e-01 1.911e-02 1.400e-01 8.445e-03 5.607401e-01 4.434192e-03 7.020870e-03 -6.000000e+00 1.760417e-01 228.12 -2.00 3.39 -2.00 321.25 0.00e+00 7.158293e-03 2.056711e-03 5.466303e-03 -6.000000e+00 8.003568e-03 289.36 -2.00 20.00 -2.00 320.56 0.00e+00 4.953 0.002 302.00 328.00 3 2.5176e+00 1.5395e-02 6.1348e-02 -6.0000e+00 4.3682e-01 2.8030e-01 1.9552e-02 4.1650e-02 -6.0000e+00 4.7470e-01 -4.8992e-01 1.5490e-02 1.9536e-02 -6.0000e+00 2.8387e-01 2.1078e-01 7.5253e-03 4.8718e-03 -6.0000e+00 1.2049e-01 1.8177e-04 -8.8114e-04 2.4540e-04 1.1446e-04 -6.0000e+00 8.1700e-03 5.9381e-03 0.0000e+00 12 8 8 10 0 0 -7.77 14.35 1.43 0.00594 -0.00068 34 7 1 5 0 1442.210 19.85 15.00 14.35 28.22 27.1 979.95 -103153 -84435 -7477 -65440 -63173 -144638 -142003 -80037 -107102 -53234 -95852 -102695 -50118 -57952 26360 -60853 44393 -378 29137 -16192 29917 11693 15998 2394 -29220 25605 258 -13124 -303 -40132 733 -4531 -609 -4266 30366 -9461 20084 -143 -7002 7385 23145 15115 16345 12800 25893 17965 14795 21175 18659 3470 17881 4663 13664 14923 19912 9877 6411 8244 7324 3817 809 16808 7484 12188 5232 6760 2887 319 5720 3793 3743 1972 1840 1276 1406 133 -6898 -4463 -5805 -4079 -3145 -1513 -692 -2503 -2634 -604 -835 -1615 322 1162 279 -3501 -1659 -3171 -4076 -2992 -508 75 -365 -848 -2413 -1414 -1741 -2478 -2528 -2096 -2151 -70 798 1205 1453 1407 886 106 -1107 258 -1080 502 781 -1043 -142 1223 2693 1935 1574 -319 1867 2327 19 -441 -654 -492 -596 956 -114 -11 739 477 360 -694 -388 -1033 -1073 -3044 -2376 -112 -1666 -1372 -6497 -6273 -2037 -3849 -1156 -3158 -3844 -1351 -2126 513 -3326 931 -13 807 -727 851 385 503 90 -1553 805 10 -580 -11 -2344 33 -251 -37 -284 1341 -595 1007 -10 -640 686 2027 1516 1689 1399 2501 1910 1803 2459 2274 514 2504 822 2374 2741 3624 2034 1389 1731 1502 799 181 3516 1942 3363 1607 1960 839 96 1795 1396 1514 843 776 511 513 44 -2267 -1437 -2113 -1727 -1533 -822 -405 -1575 -1776 -427 -623 -1250 245 841 189 -2289 -1014 -2019 -2931 -2459 -470 79 -415 -961 -2587 -1351 -1548 -2285 -2534 -2213 -2402 -82 1014 1700 2241 2263 1416 162 -1614 357 -1539 744 1234 -1752 -235 1930 4056 2833 2221 -441 2442 3196 31 -783 -1259 -994 -1259 2109 -272 -27 1869 1229 922 -1724 -906 -2294 -2343 SS 20220929T215130.3Z 8307.910768 68 1 49.48 2 77.53 102.37 126.87 90.96 0.00 1 0.00 1 0 25 2.822e-01 1.303e-02 7.108e-02 4.325e-03 5.256611e-01 2.229448e-03 6.491089e-03 -6.000000e+00 1.590784e-01 228.12 -2.00 3.39 -2.00 320.86 0.00e+00 5.616375e-03 9.505986e-04 4.284785e-03 -6.000000e+00 7.232181e-03 289.36 -2.00 20.00 -2.00 320.15 0.00e+00 4.499 0.001 302.00 328.00 3 2.1254e+00 7.3229e-03 5.4726e-02 -6.0000e+00 3.9473e-01 1.5246e-01 9.2776e-03 3.5442e-02 -6.0000e+00 4.2896e-01 -2.7888e-01 7.7028e-03 1.7141e-02 -6.0000e+00 2.5652e-01 1.1367e-01 3.8152e-03 4.4888e-03 -6.0000e+00 1.0888e-01 4.3183e-04 -6.7913e-04 1.2329e-04 9.2277e-05 -6.0000e+00 7.3825e-03 5.7652e-03 0.0000e+00 12 8 8 10 0 0 28.96 14.35 1.09 0.00577 0.00066 63 14 1 5 0 785.350 19.85 15.00 14.35 28.73 27.1 982.70 -67145 -118059 -71711 -80382 -89005 -95775 -85357 -100581 -101877 -62840 -89277 -73922 -87414 -35808 -27035 18939 -17306 -24733 -8435 -31998 -11397 -13545 -14274 -9785 -8356 -5557 -17929 -15568 -21566 -11361 -511 -5017 1031 4785 -12526 -9909 -1397 -16535 10537 9544 12622 10354 7539 11777 4649 6531 2486 1515 3498 8979 11753 9058 7044 6471 6297 2098 3175 2373 3894 2342 2235 6374 6177 6488 2984 3733 3284 2382 2172 1223 3457 1026 1364 -952 1179 -3495 -3072 -4911 -4052 -2827 -3020 -939 -2412 -1027 -1323 264 131 -69 1154 -359 -355 -1812 -1622 -2449 -2323 -1162 -234 911 -903 -1086 -1737 -638 -1519 -957 -1959 -1857 -600 -309 745 812 1283 1090 1079 161 33 -246 -409 458 -180 -367 -368 1320 1980 714 582 -870 484 840 204 -391 -103 125 -289 -56 -501 -106 468 796 -87 -360 -330 -546 -521 -1133 -3848 -1567 -1849 -1980 -2130 -1768 -2661 -3008 -1325 -2465 -1871 -3084 -947 -809 421 -611 -1015 -314 -1571 -463 -551 -591 -409 -362 -243 -894 -728 -1034 -514 -24 -287 63 331 -972 -723 -101 -1632 960 1039 1480 1319 1033 1585 679 953 382 238 552 1401 1948 1704 1462 1449 1477 527 806 603 946 571 566 1702 1863 2168 1069 1267 1078 798 799 523 1590 503 658 -446 494 -1374 -1113 -1811 -1643 -1333 -1653 -569 -1609 -712 -987 207 109 -59 973 -296 -271 -1302 -1102 -1713 -1806 -1026 -235 1028 -1117 -1330 -1993 -653 -1460 -944 -2120 -2121 -714 -392 1017 1229 2106 1859 1810 259 50 -357 -603 706 -299 -580 -579 2175 3142 1106 866 -1259 667 1214 333 -711 -202 256 -562 -115 -1107 -243 1096 1892 -207 -825 -715 -1126 -1059 SS 20220929T215654.3Z 8307.914518 71 1 49.08 2 76.45 103.21 125.83 91.70 0.00 1 0.00 1 0 25 2.525e-01 1.202e-02 4.187e-02 2.874e-03 4.957438e-01 1.467090e-03 5.860624e-03 -6.000000e+00 1.423550e-01 228.12 -2.00 3.39 -2.00 320.62 0.00e+00 4.441194e-03 5.764050e-04 2.870526e-03 -6.000000e+00 6.471387e-03 289.36 -2.00 20.00 -2.00 319.87 0.00e+00 4.166 0.001 302.00 328.00 3 1.8735e+00 4.6228e-03 4.9146e-02 -6.0000e+00 3.5324e-01 1.0772e-01 5.7822e-03 2.8656e-02 -6.0000e+00 3.8385e-01 -2.1070e-01 4.7488e-03 1.4653e-02 -6.0000e+00 2.2955e-01 8.4357e-02 2.3841e-03 4.3324e-03 -6.0000e+00 9.7442e-02 7.8832e-04 -5.0520e-04 8.2476e-05 6.1487e-05 -6.0000e+00 6.6055e-03 5.1833e-03 0.0000e+00 12 8 8 10 0 0 16.98 14.35 1.16 0.00518 0.00139 97 21 1 5 0 505.870 19.85 15.00 14.35 29.19 27.1 985.37 -84993 -64695 -72468 -92645 -89673 -90819 -72175 -76491 -90770 -67050 -76492 -78630 -56550 -52229 -23189 -13324 -17305 -15995 -1547 -8111 -8307 -4248 -1448 -6867 -7513 -2395 -7897 -17182 -15129 -16179 -10067 -7053 533 -2052 -4432 -7047 -6797 -1478 1943 3891 5802 4872 7145 6251 8844 7115 4366 3344 2826 4444 7113 5545 7040 5077 5003 3642 2012 1843 938 1486 1871 4530 5248 5080 3118 1354 947 930 1676 1934 1129 1745 1659 -53 -582 -2859 -4077 -4920 -2676 -2652 -2277 -1994 -2552 -1447 -1061 18 424 782 1025 1175 -461 -1151 -1990 -1936 -1628 -1175 118 800 -97 -852 -1612 -1150 -1226 -1433 -1762 -1408 -819 -42 435 988 1272 1081 755 290 -250 323 27 27 -296 -787 -434 790 2083 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