File name: Pandora197s1_Nagoya_20221010_L2Fit_fout2c41d20220827p1-8.txt File generation date: 20260324T105239.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c41p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v41d20220827.txt Level 1 file used: Pandora197s1_Nagoya_20221010_L1_smca1c41d20220827p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20221010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0366 305.1778 305.3191 305.4603 305.6015 305.7427 305.8839 306.0250 306.1662 306.3074 306.4485 306.5896 306.7308 306.8719 307.0130 307.1540 307.2951 307.4362 307.5772 307.7183 307.8593 308.0003 308.1413 308.2823 308.4233 308.5643 308.7052 308.8462 308.9871 309.1281 309.2690 309.4099 309.5508 309.6917 309.8325 309.9734 310.1142 310.2551 310.3959 310.5367 310.6775 310.8183 310.9591 311.0999 311.2406 311.3814 311.5221 311.6628 311.8036 311.9443 312.0849 312.2256 312.3663 312.5069 312.6476 312.7882 312.9289 313.0695 313.2101 313.3507 313.4912 313.6318 313.7723 313.9129 314.0534 314.1939 314.3345 314.4749 314.6154 314.7559 314.8964 315.0368 315.1773 315.3177 315.4581 315.5985 315.7389 315.8793 316.0197 316.1600 316.3004 316.4407 316.5810 316.7214 316.8617 317.0020 317.1422 317.2825 317.4228 317.5630 317.7033 317.8435 317.9837 318.1239 318.2641 318.4043 318.5444 318.6846 318.8247 318.9649 319.1050 319.2451 319.3852 319.5253 319.6653 319.8054 319.9455 320.0855 320.2255 320.3655 320.5056 320.6455 320.7855 320.9255 321.0655 321.2054 321.3453 321.4853 321.6252 321.7651 321.9050 322.0449 322.1847 322.3246 322.4644 322.6043 322.7441 322.8839 323.0237 323.1635 323.3033 323.4430 323.5828 323.7225 323.8622 324.0020 324.1417 324.2814 324.4210 324.5607 324.7004 324.8400 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221009T231513.3Z 8317.968904 303 1 49.01 2 63.55 120.40 117.03 297.51 0.00 1 0.00 1 0 17 2.197e-02 7.318e-03 3.016e-03 7.008e-04 2.569903e-01 3.490166e-04 2.973778e-03 -6.000000e+00 1.234391e-02 227.25 -2.00 3.39 -2.00 318.15 0.00e+00 1.103356e-03 6.312539e-05 2.058268e-04 -6.000000e+00 5.605008e-04 288.33 -2.00 20.00 -2.00 317.27 0.00e+00 2.232 0.000 302.00 328.00 3 1.6588e+00 9.4178e-04 2.5412e-02 -6.0000e+00 3.0578e-02 -2.0841e-02 1.0751e-03 1.2847e-02 -6.0000e+00 3.3255e-02 4.1652e-03 6.7045e-04 6.3052e-03 -6.0000e+00 1.9888e-02 -3.1116e-03 3.3798e-04 1.8990e-03 -6.0000e+00 8.4498e-03 8.4396e-03 -1.0441e-04 2.0381e-05 1.9853e-05 -6.0000e+00 5.7448e-04 4.8498e-03 0.0000e+00 11 8 0 10 0 0 99.99 14.35 1.08 0.00485 0.00407 632 137 1 5 0 77.530 19.85 15.00 14.35 23.42 27.3 957.49 -5450 -5455 -4244 -7835 -9090 -9292 -5895 -5424 -5552 -5417 -7951 -5031 -4174 -1166 -541 339 271 1496 1041 1600 458 241 1923 1813 340 -473 -735 -1372 -2675 -433 1186 1059 929 -1120 -3346 -2305 -992 -696 -240 -86 -99 -210 231 105 659 468 209 149 -419 597 1382 1080 1268 1139 1209 884 189 -141 231 527 1477 1773 2097 1920 -234 -579 -511 0 837 241 266 301 272 183 -667 -1230 -1497 -1881 -1163 -1854 -1712 -1835 -2467 -1376 -611 -51 164 709 1141 635 327 -234 -26 -67 -180 -155 683 1067 -79 -872 -813 -582 -702 -249 -1118 -909 -658 -67 611 693 973 693 665 236 87 135 160 112 -243 -889 -1049 237 1088 627 418 -306 573 848 129 -513 -450 3 -137 123 114 -68 373 599 73 -398 -342 -303 -465 -395 -440 -350 -636 -658 -696 -447 -459 -528 -546 -811 -504 -465 -146 -78 53 45 254 185 294 87 45 362 360 72 -106 -165 -293 -537 -84 239 232 222 -284 -809 -533 -246 -201 -83 -35 -44 -98 111 51 318 227 100 69 -193 273 662 559 694 658 720 539 118 -88 141 319 916 1183 1522 1493 -185 -422 -344 0 582 192 232 274 247 160 -546 -907 -1000 -1203 -780 -1420 -1476 -1749 -2519 -1324 -627 -55 189 839 1345 723 344 -248 -25 -64 -182 -174 770 1330 -106 -1142 -991 -648 -822 -277 -1368 -1170 -884 -94 895 1086 1600 1148 1054 347 118 173 206 151 -358 -1400 -1681 369 1633 904 574 -402 711 1071 177 -760 -698 4 -221 208 204 -128 715 1173 143 -765 -634 -540 -820 SS 20221010T011734.8Z 8318.053875 374 1 49.62 2 45.95 151.17 134.55 326.77 0.00 1 0.00 1 0 17 1.135e-02 7.492e-03 2.857e-04 1.524e-04 1.709887e-01 7.607494e-05 2.012078e-03 -6.000000e+00 6.374693e-03 227.24 -2.00 3.39 -2.00 315.96 0.00e+00 6.342543e-04 8.198445e-06 2.635176e-05 -6.000000e+00 2.894392e-04 288.32 -2.00 20.00 -2.00 315.19 0.00e+00 1.436 0.000 302.00 328.00 3 1.0818e-01 1.9691e-04 1.6495e-02 -6.0000e+00 1.5791e-02 -2.4831e-02 2.2025e-04 8.5396e-03 -6.0000e+00 1.7173e-02 8.2985e-03 1.2683e-04 4.1664e-03 -6.0000e+00 1.0271e-02 -4.3878e-03 5.8470e-05 1.2233e-03 -6.0000e+00 4.3639e-03 9.9621e-02 -1.4352e-04 4.2623e-06 1.3513e-05 -6.0000e+00 2.9666e-04 4.5136e-03 0.0000e+00 11 8 0 10 0 0 99.08 14.35 1.32 0.00451 0.00344 2148 465 1 5 0 22.510 19.85 15.00 14.35 23.31 27.5 956.28 -1164 -2026 -1863 -4165 -4940 -3051 -724 -768 -1447 -2222 -2817 -1549 -200 12 430 322 361 1172 1233 1830 785 803 2168 1999 580 41 -53 -521 -785 782 2228 1155 1234 -1277 -2786 -1519 -476 -110 -236 -13 -405 -547 -337 -334 253 -142 -182 -199 -519 225 1213 666 782 1065 810 903 286 21 107 511 1278 1412 1625 1440 -385 -900 -554 -48 750 120 160 270 133 250 -538 -927 -1278 -1475 -1094 -1802 -1834 -1943 -2355 -1317 -550 -115 33 557 1054 601 240 -54 193 239 -35 -103 662 1034 -99 -797 -631 -349 -496 -266 -1059 -878 -664 -114 548 762 842 682 705 348 217 280 235 162 -189 -880 -1033 184 1009 646 508 -136 725 999 286 -402 -425 -43 -29 125 91 -90 310 483 -5 -463 -440 -446 -641 -262 -501 -469 -1005 -1048 -590 -142 -168 -355 -578 -717 -384 -53 4 144 117 135 443 480 729 323 325 870 840 259 17 -22 -227 -314 296 858 476 544 -592 -1213 -627 -211 -56 -132 -9 -286 -403 -254 -253 190 -106 -133 -140 -353 150 834 490 603 856 668 755 245 18 90 424 1085 1178 1460 1367 -366 -781 -475 -39 648 109 158 278 137 249 -504 -851 -1055 -1145 -878 -1632 -1700 -1975 -2544 -1471 -655 -135 41 709 1338 736 272 -60 193 230 -36 -115 813 1286 -131 -1032 -760 -419 -573 -322 -1305 -1138 -897 -160 796 1084 1246 1006 987 484 275 334 281 205 -259 -1209 -1456 272 1444 886 661 -168 917 1273 361 -541 -595 -61 -42 185 133 -139 489 779 -9 -738 -679 -666 -948 SS 20221010T012232.9Z 8318.057325 377 1 49.37 2 45.47 152.76 135.05 328.28 0.00 1 0.00 1 0 17 1.122e-02 7.529e-03 2.812e-04 1.532e-04 1.699014e-01 7.662032e-05 1.996981e-03 -6.000000e+00 6.306056e-03 227.24 -2.00 3.39 -2.00 315.94 0.00e+00 6.091645e-04 8.179225e-06 2.605295e-05 -6.000000e+00 2.863028e-04 288.32 -2.00 20.00 -2.00 315.19 0.00e+00 1.424 0.000 302.00 328.00 3 1.8235e-01 1.9807e-04 1.6360e-02 -6.0000e+00 1.5621e-02 -2.4883e-02 2.2202e-04 8.4741e-03 -6.0000e+00 1.6988e-02 7.6736e-03 1.2721e-04 4.1356e-03 -6.0000e+00 1.0160e-02 -4.1909e-03 5.8009e-05 1.2114e-03 -6.0000e+00 4.3171e-03 9.3813e-02 -1.1741e-04 4.2804e-06 1.3496e-05 -6.0000e+00 2.9344e-04 4.0785e-03 0.0000e+00 11 8 0 10 0 0 99.59 14.36 1.31 0.00408 0.00320 1785 387 1 5 0 27.180 19.85 15.00 14.36 23.99 27.5 960.69 -977 -1976 -1772 -4232 -4758 -2864 -622 -645 -1248 -2144 -2974 -1374 -251 171 533 321 536 1225 1290 1768 801 820 2195 2023 690 43 -67 -486 -762 849 2153 1232 1302 -1337 -2705 -1472 -409 -183 -180 -71 -382 -516 -317 -324 234 -83 -209 -198 -557 240 1185 676 796 1006 793 887 337 44 105 522 1316 1438 1635 1473 -440 -881 -520 -62 756 131 145 265 150 219 -533 -967 -1250 -1465 -1083 -1810 -1812 -1963 -2378 -1284 -560 -168 1 542 1025 554 256 -35 228 242 -24 -99 653 1013 -113 -803 -634 -292 -474 -230 -1061 -896 -646 -114 558 747 825 634 701 384 218 305 257 168 -170 -874 -1058 178 1011 675 523 -96 762 1003 291 -409 -417 -1 -15 167 79 -80 299 512 10 -465 -426 -414 -590 -228 -507 -463 -1062 -1047 -574 -127 -146 -317 -578 -787 -353 -69 53 185 121 207 479 519 663 309 343 912 799 289 19 -29 -219 -315 332 857 524 592 -640 -1215 -627 -186 -88 -103 -47 -278 -359 -226 -232 166 -59 -158 -144 -390 165 839 512 632 764 617 700 271 35 82 408 1054 1233 1511 1438 -430 -786 -420 -53 615 122 147 280 159 224 -512 -837 -1060 -1167 -892 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