File name: Pandora197s1_Nagoya_20221028_L2Fit_fout2c41d20220827p1-8.txt File generation date: 20260324T105540.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c41p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v41d20220827.txt Level 1 file used: Pandora197s1_Nagoya_20221028_L1_smca1c41d20220827p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20221028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0366 305.1778 305.3191 305.4603 305.6015 305.7427 305.8839 306.0250 306.1662 306.3074 306.4485 306.5896 306.7308 306.8719 307.0130 307.1540 307.2951 307.4362 307.5772 307.7183 307.8593 308.0003 308.1413 308.2823 308.4233 308.5643 308.7052 308.8462 308.9871 309.1281 309.2690 309.4099 309.5508 309.6917 309.8325 309.9734 310.1142 310.2551 310.3959 310.5367 310.6775 310.8183 310.9591 311.0999 311.2406 311.3814 311.5221 311.6628 311.8036 311.9443 312.0849 312.2256 312.3663 312.5069 312.6476 312.7882 312.9289 313.0695 313.2101 313.3507 313.4912 313.6318 313.7723 313.9129 314.0534 314.1939 314.3345 314.4749 314.6154 314.7559 314.8964 315.0368 315.1773 315.3177 315.4581 315.5985 315.7389 315.8793 316.0197 316.1600 316.3004 316.4407 316.5810 316.7214 316.8617 317.0020 317.1422 317.2825 317.4228 317.5630 317.7033 317.8435 317.9837 318.1239 318.2641 318.4043 318.5444 318.6846 318.8247 318.9649 319.1050 319.2451 319.3852 319.5253 319.6653 319.8054 319.9455 320.0855 320.2255 320.3655 320.5056 320.6455 320.7855 320.9255 321.0655 321.2054 321.3453 321.4853 321.6252 321.7651 321.9050 322.0449 322.1847 322.3246 322.4644 322.6043 322.7441 322.8839 323.0237 323.1635 323.3033 323.4430 323.5828 323.7225 323.8622 324.0020 324.1417 324.2814 324.4210 324.5607 324.7004 324.8400 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221027T215947.3Z 8335.916520 61 1 49.01 2 81.07 112.92 112.93 103.93 0.00 1 0.00 1 0 17 2.702e-01 1.810e-02 1.178e-01 7.683e-03 6.036853e-01 4.183363e-03 7.303484e-03 -6.000000e+00 1.533717e-01 225.81 -2.00 3.39 -2.00 321.45 0.00e+00 3.350387e-03 1.958545e-03 5.421774e-03 -6.000000e+00 6.877662e-03 286.39 -2.00 20.00 -2.00 320.86 0.00e+00 6.096 0.003 302.00 328.00 3 1.2188e+00 1.4551e-02 7.2574e-02 -6.0000e+00 3.7913e-01 4.2901e-01 1.8486e-02 4.7299e-02 -6.0000e+00 4.1066e-01 -7.1997e-01 1.4782e-02 2.0296e-02 -6.0000e+00 2.4542e-01 3.0618e-01 7.1868e-03 4.7506e-03 -6.0000e+00 1.0710e-01 2.2222e-04 -8.4348e-04 2.2692e-04 9.5782e-05 -6.0000e+00 7.0867e-03 2.5348e-02 0.0000e+00 12 8 8 10 0 0 45.50 16.27 1.00 0.02535 0.01901 69 15 1 5 0 710.110 21.58 15.00 16.27 16.96 27.0 928.66 -87072 -89286 -44310 -44907 -11041 -83630 -94462 -131330 -83534 -107084 -75902 -84859 -20805 -11045 -19316 31903 -28569 11403 3713 -156 -3299 -589 -18107 -8302 -7367 -3794 2513 -24062 -17321 -31117 -8388 3433 19536 8400 -18528 2082 -8782 12262 1430 25750 18637 17997 26313 31572 19400 15643 31057 15932 3598 13662 12871 26552 16678 14884 11848 10792 12679 7470 5809 3760 9596 10503 9197 11608 9417 2964 4404 -1085 5847 11089 7431 3579 999 -441 -2439 -3553 -2600 -3460 -6774 -4042 -3966 -2390 -2850 -2495 -1442 226 2487 210 536 -311 -892 -2294 -3355 -5477 -4603 -1894 -726 -601 83 -2059 -2017 -2649 -2252 -2166 -3257 -1809 -731 -490 -549 906 1231 802 1301 236 -869 423 -409 642 52 -683 374 1848 2964 1267 1366 168 1152 665 -44 261 -82 183 -499 -148 122 82 385 713 -330 -591 -337 -1413 900000 -2881 -3344 -1177 -1101 -165 -2392 -3088 -6708 -2845 -4740 -2430 -3179 -496 -293 -671 760 -1343 381 139 -6 -133 -22 -814 -356 -326 -165 101 -1180 -755 -1632 -406 171 931 463 -1237 109 -556 735 115 1894 1612 1642 2276 2862 1977 1664 2838 1719 450 1627 1697 3362 2511 2442 2086 1973 2308 1405 1066 690 1718 2054 2060 2817 2399 771 1102 -295 1651 3414 2583 1332 373 -156 -799 -1051 -715 -982 -2258 -1556 -1774 -1193 -1548 -1428 -876 144 1628 144 364 -204 -546 -1332 -1903 -3332 -3152 -1466 -643 -606 89 -2213 -2007 -2383 -1893 -1898 -3135 -1813 -770 -554 -688 1256 1868 1271 2029 356 -1249 583 -583 959 83 -1143 612 2869 4419 1857 1929 231 1536 958 -73 481 -164 386 -1110 -351 308 216 1032 1932 -892 -1525 -816 -3271 900000 SS 20221027T221128.4Z 8335.924634 66 1 49.24 2 78.89 114.77 110.74 105.35 0.00 1 0.00 1 0 17 2.800e-01 1.346e-02 4.416e-02 2.864e-03 5.213272e-01 1.492415e-03 6.446535e-03 -6.000000e+00 1.589183e-01 225.81 -2.00 3.39 -2.00 320.83 0.00e+00 5.107994e-03 6.181203e-04 4.103849e-03 -6.000000e+00 7.126069e-03 286.39 -2.00 20.00 -2.00 320.20 0.00e+00 5.004 0.002 302.00 328.00 3 9.7739e-01 4.7853e-03 5.8280e-02 -6.0000e+00 3.9284e-01 1.6167e-01 6.0439e-03 3.4424e-02 -6.0000e+00 4.2550e-01 -3.0812e-01 5.1751e-03 1.7290e-02 -6.0000e+00 2.5429e-01 1.2859e-01 2.5898e-03 4.9014e-03 -6.0000e+00 1.1099e-01 8.6255e-04 -7.8868e-04 8.2352e-05 9.0981e-05 -6.0000e+00 7.3422e-03 2.4588e-02 0.0000e+00 12 8 8 10 0 0 42.52 16.27 1.00 0.02459 0.01866 151 33 1 5 0 326.030 21.58 15.00 16.27 18.41 26.7 936.38 -81645 -74255 -91363 -85330 -112730 -109233 -98001 -76448 -57511 -65969 -84791 -85532 -76285 -55453 -31423 -22915 -5686 -8631 -8211 -9026 -22841 -22334 -16456 -15922 -20601 -15097 -11346 -17526 -21335 -11560 -12588 -7514 534 -824 -6303 -7763 -2821 -476 10520 6035 6465 6704 8236 10151 8268 9590 8886 5673 4663 6007 5621 8446 7975 10464 7975 6010 3864 2548 -497 1918 3726 5965 7284 7591 4676 3277 1023 26 1427 1885 3342 2782 1569 1129 -714 -3674 -5361 -6278 -4633 -3529 -1910 -1479 -2714 -2062 -1079 -309 715 341 1176 868 32 -1534 -2580 -2817 -2287 -1587 -72 425 -113 -774 -1446 -1370 -1886 -1803 -1751 -1455 -922 -137 522 1273 1496 1029 713 125 -442 -158 360 358 13 -443 -157 996 2081 1077 666 -201 425 405 -75 -54 -444 -133 -398 -28 96 -81 624 527 -136 -465 -544 -823 900000 -1741 -1678 -2575 -2145 -3291 -2912 -2438 -1688 -1153 -1507 -2346 -2584 -2576 -1900 -1037 -809 -185 -311 -313 -360 -1055 -1004 -710 -724 -1030 -740 -536 -841 -1029 -588 -749 -493 37 -60 -454 -555 -210 -41 978 689 811 887 1120 1380 1157 1347 1268 849 721 963 992 1597 1635 2241 1824 1442 965 637 -124 465 926 1602 2178 2501 1622 1096 339 9 532 805 1534 1329 745 508 -298 -1418 -1963 -2347 -1915 -1700 -1046 -909 -1821 -1452 -808 -246 591 290 988 700 24 -1091 -1770 -2005 -1817 -1441 -74 492 -140 -946 -1646 -1406 -1833 -1831 -1930 -1688 -1125 -178 735 1974 2285 1625 1107 203 -678 -233 541 569 20 -719 -252 1529 3372 1698 1014 -296 605 615 -129 -92 -825 -258 -808 -60 219 -194 1517 1305 -334 -1101 -1220 -1762 900000 SS 20221027T221729.4Z 8335.928813 69 1 49.20 2 77.77 115.75 109.61 106.08 0.00 1 0.00 1 0 17 2.358e-01 1.126e-02 3.022e-02 1.982e-03 4.808776e-01 1.041887e-03 5.876317e-03 -6.000000e+00 1.338269e-01 225.81 -2.00 3.39 -2.00 320.58 0.00e+00 4.522822e-03 3.969050e-04 2.966789e-03 -6.000000e+00 6.000838e-03 286.39 -2.00 20.00 -2.00 319.90 0.00e+00 4.583 0.001 302.00 328.00 3 8.8162e-01 3.2237e-03 5.2362e-02 -6.0000e+00 3.3082e-01 7.3740e-02 4.0084e-03 2.8518e-02 -6.0000e+00 3.5831e-01 -1.9369e-01 3.4014e-03 1.5138e-02 -6.0000e+00 2.1414e-01 8.2700e-02 1.7240e-03 4.7919e-03 -6.0000e+00 9.3467e-02 1.4903e-03 -5.9927e-04 5.8156e-05 7.1625e-05 -6.0000e+00 6.1827e-03 2.4334e-02 0.0000e+00 12 8 8 10 0 0 -12.87 16.27 0.94 0.02433 0.01983 215 47 1 5 0 228.770 21.58 15.00 16.27 19.14 26.7 940.48 -88082 -67203 -68765 -69987 -81008 -81905 -80610 -90768 -68695 -74824 -55627 -66432 -40849 -33967 -28064 -12662 -22187 -9175 -11909 -1844 -11630 -6962 -3789 -10395 -7852 -15862 -13264 -21475 -13834 -14267 -2630 -2555 -2136 -2862 -12500 -12016 -10616 851 4247 5645 5343 5107 6585 3487 5390 3337 7360 3902 5578 4729 6032 5916 3815 5468 3884 4422 2694 2345 1723 914 4061 2623 5636 4475 3857 1700 860 507 1509 1693 1260 1519 -15 525 -1012 -3093 -3838 -4455 -3604 -3281 -2136 -2141 -2060 -1843 -616 -30 387 1258 1045 692 -433 -1123 -2295 -1628 -1744 -990 462 988 -193 -1091 -978 -1490 -1093 -1202 -1655 -1072 -1012 201 757 1184 1022 1111 1041 63 5 -595 98 -73 104 -532 -45 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