File name: Pandora197s1_Nagoya_20221108_L2Fit_fout2c42d20221101p1-8.txt File generation date: 20260324T105649.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c42p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v42d20221101.txt Level 1 file used: Pandora197s1_Nagoya_20221108_L1_smca1c42d20221101p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20221108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0291 305.1703 305.3116 305.4528 305.5940 305.7352 305.8764 306.0176 306.1587 306.2999 306.4410 306.5822 306.7233 306.8644 307.0055 307.1466 307.2876 307.4287 307.5698 307.7108 307.8518 307.9929 308.1339 308.2749 308.4158 308.5568 308.6978 308.8387 308.9797 309.1206 309.2615 309.4024 309.5433 309.6842 309.8251 309.9659 310.1068 310.2476 310.3884 310.5292 310.6700 310.8108 310.9516 311.0924 311.2331 311.3739 311.5146 311.6553 311.7960 311.9367 312.0774 312.2181 312.3588 312.4994 312.6401 312.7807 312.9213 313.0619 313.2025 313.3431 313.4837 313.6242 313.7648 313.9053 314.0458 314.1864 314.3269 314.4674 314.6078 314.7483 314.8888 315.0292 315.1696 315.3101 315.4505 315.5909 315.7313 315.8716 316.0120 316.1524 316.2927 316.4330 316.5734 316.7137 316.8540 316.9943 317.1345 317.2748 317.4150 317.5553 317.6955 317.8357 317.9759 318.1161 318.2563 318.3965 318.5366 318.6768 318.8169 318.9570 319.0971 319.2372 319.3773 319.5174 319.6575 319.7975 319.9376 320.0776 320.2176 320.3576 320.4976 320.6376 320.7776 320.9175 321.0575 321.1974 321.3374 321.4773 321.6172 321.7571 321.8970 322.0368 322.1767 322.3165 322.4564 322.5962 322.7360 322.8758 323.0156 323.1554 323.2951 323.4349 323.5746 323.7143 323.8541 323.9938 324.1335 324.2731 324.4128 324.5525 324.6921 324.8318 324.9714 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221107T221028.1Z 8346.923937 274 1 49.26 2 81.30 117.30 105.56 299.56 0.00 1 0.00 1 0 25 2.903e-01 2.081e-02 1.653e-01 1.053e-02 6.282568e-01 5.749489e-03 7.465752e-03 -6.000000e+00 1.642422e-01 224.97 -2.00 3.39 -2.00 321.53 0.00e+00 1.901826e-03 2.696999e-03 5.341562e-03 -6.000000e+00 7.350625e-03 285.16 -2.00 20.00 -2.00 320.97 0.00e+00 6.240 0.004 302.00 328.00 3 1.3674e+00 2.0003e-02 7.4457e-02 -6.0000e+00 4.0540e-01 5.0064e-01 2.5518e-02 4.9182e-02 -6.0000e+00 4.3947e-01 -8.1381e-01 2.0453e-02 2.0768e-02 -6.0000e+00 2.6261e-01 3.4118e-01 9.8806e-03 5.0566e-03 -6.0000e+00 1.1467e-01 1.6216e-04 -7.2199e-04 3.0921e-04 8.9343e-05 -6.0000e+00 7.6109e-03 3.6703e-02 1.3280e-04 12 8 8 10 0 0 15.47 16.57 1.04 0.03670 0.03128 51 11 1 5 0 965.710 21.79 15.00 16.57 17.45 27.0 936.34 -81330 -74291 -77783 -89318 -50477 -88477 -63578 -36002 -37018 -123493 -106923 -98595 -69915 -27769 8424 18264 16013 48127 68176 4397 29643 -29178 22673 41183 -2733 -12792 26458 -34817 -16225 -9895 -9676 12635 12832 36190 15565 -2825 -10700 -857 23363 25375 33200 35241 40214 25006 21818 22973 8133 13254 1620 30020 18827 21131 12645 19492 12222 25777 18947 16785 8668 13429 6046 13847 12938 13147 5314 3506 2633 7833 4036 5130 4267 6883 2860 6388 -4427 1252 -8386 -9362 -2579 -7814 -2233 -2646 -1839 -4157 -3198 476 266 1149 1772 1162 -378 -7028 -4511 -6149 -3589 -3526 796 1202 -415 -1015 -3030 -3593 -4000 -3077 -2698 -1089 -2221 -426 62 926 856 1405 1858 -76 561 -634 -1214 -508 -665 -14 582 2106 2440 2047 2756 986 93 -180 555 316 81 -588 275 -88 479 -43 484 512 -318 -1168 -466 -1000 900000 -2852 -2668 -2927 -3437 -1122 -2889 -1661 -773 -863 -7028 -5087 -4599 -2935 -933 236 528 508 1167 1399 172 885 -1497 698 1114 -120 -633 864 -1949 -711 -425 -478 578 658 1519 741 -155 -689 -58 1504 1870 2478 2696 3001 2170 1934 2015 827 1298 183 2958 2280 2754 1934 2980 2095 3968 3169 2808 1503 2164 1080 2515 2682 3022 1358 874 648 1889 1127 1627 1484 2402 1012 2039 -1422 339 -2349 -2719 -797 -3023 -951 -1284 -961 -2351 -1920 293 173 756 1149 724 -223 -4140 -2514 -3672 -2379 -2717 681 1168 -439 -1062 -2991 -3201 -3350 -2662 -2525 -1059 -2323 -472 76 1265 1289 2194 2865 -115 793 -880 -1741 -767 -1074 -23 943 3233 3626 2954 3812 1336 125 -262 913 585 163 -1258 614 -212 1222 -115 1310 1405 -868 -3058 -1138 -2318 900000 SS 20221107T222338.2Z 8346.933081 279 1 49.14 2 78.93 119.43 107.76 301.81 0.00 1 0.00 1 0 25 2.798e-01 1.391e-02 5.376e-02 3.364e-03 5.269566e-01 1.758431e-03 6.606532e-03 -6.000000e+00 1.582894e-01 224.97 -2.00 3.39 -2.00 320.90 0.00e+00 4.596900e-03 7.418196e-04 4.582685e-03 -6.000000e+00 7.084865e-03 285.16 -2.00 20.00 -2.00 320.30 0.00e+00 5.024 0.002 302.00 328.00 3 1.1005e+00 5.6920e-03 5.9516e-02 -6.0000e+00 3.9070e-01 1.5240e-01 7.2305e-03 3.7434e-02 -6.0000e+00 4.2358e-01 -3.2970e-01 6.2689e-03 1.8177e-02 -6.0000e+00 2.5312e-01 1.4228e-01 3.1137e-03 4.7834e-03 -6.0000e+00 1.1049e-01 7.5510e-04 -5.7573e-04 9.7045e-05 9.8940e-05 -6.0000e+00 7.3381e-03 3.7227e-02 7.2133e-05 12 8 8 10 0 0 -3.37 16.56 0.86 0.03723 0.03290 126 27 1 5 0 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-1005 -371 -614 -716 -188 149 629 690 1211 717 946 1467 1804 1671 484 965 598 1357 593 2195 1850 2024 1729 2189 1184 620 767 137 1270 1296 2276 2309 1258 1574 -64 327 31 1547 975 722 1051 372 -480 -1695 -2035 -2830 -1648 -1818 -850 -818 -1564 -1221 -1108 183 729 849 1276 392 -408 -1353 -1898 -2321 -1399 -2076 235 344 83 -705 -2216 -1587 -2179 -1356 -2701 -1368 -1197 -113 1091 1962 2256 1811 1544 -178 -228 -216 -178 441 198 -310 -671 2128 2529 2007 726 -740 1088 590 -67 -705 -309 -614 -391 -656 -47 101 1166 1426 -157 -881 -1215 -1646 900000 SS 20221107T222945.1Z 8346.937327 282 1 49.32 2 77.85 120.43 108.76 302.88 0.00 1 0.00 1 0 25 2.515e-01 1.152e-02 3.714e-02 2.336e-03 4.941584e-01 1.217842e-03 5.927915e-03 -6.000000e+00 1.422881e-01 224.97 -2.00 3.39 -2.00 320.65 0.00e+00 3.825162e-03 4.775230e-04 2.837633e-03 -6.000000e+00 6.368532e-03 285.16 -2.00 20.00 -2.00 320.02 0.00e+00 4.610 0.001 302.00 328.00 3 1.0134e+00 3.7792e-03 5.2710e-02 -6.0000e+00 3.5121e-01 7.5296e-02 4.7544e-03 2.8760e-02 -6.0000e+00 3.8076e-01 -2.0758e-01 4.1404e-03 1.5226e-02 -6.0000e+00 2.2753e-01 8.9057e-02 2.0861e-03 4.7522e-03 -6.0000e+00 9.9328e-02 1.2617e-03 -3.8515e-04 6.8439e-05 6.6478e-05 -6.0000e+00 6.5956e-03 3.7063e-02 8.3249e-05 12 8 8 10 0 0 -9.21 16.57 0.84 0.03706 0.03417 171 37 1 5 0 288.330 21.79 15.00 16.57 20.01 26.8 950.84 -92756 -68366 -79866 -67600 -81367 -91543 -81996 -81995 -71632 -63675 -70574 -89615 -67180 -38160 -25122 -21958 -16614 -8605 -3068 -10515 -13495 -12681 -11855 -9499 -7379 -15805 -402 -17447 -14236 -20053 -14375 -7140 -3531 -3379 -6035 -8105 -4041 2443 1447 3483 5047 6253 6151 6777 6701 5157 6546 3959 3465 3328 5159 6019 5862 7286 5672 6043 2524 1636 1327 1458 4745 1932 5748 5271 3570 1903 1236 -223 658 1957 1613 2172 694 394 -805 -3224 -4532 -4717 -3608 -3498 -1840 -2772 -2292 -1785 -985 -253 114 1038 1115 767 -1 -968 -1857 -1977 -1616 -1285 1 618 215 -518 -810 -1640 -1056 -1193 -1559 -1152 -913 37 818 1637 1351 1033 888 -207 -375 -243 72 26 193 -735 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